4 research outputs found
Crystal structure of mixed fluorites Ca(1-x)Sr(x)F(2) and Sr(1-x)Ba(x)F(2) and luminescence of Eu(2+) in the crystals
Within the framework of the virtual crystal method implemented in the shell
model and pair potential approximation the crystal structure of mixed fluorites
Ca(1-x)Sr(x)F(2) and Sr(1-x)Ba(x)F(2) has been calculated. The impurity center
Eu(2+) and the distance Eu(2+)-F in this crystals have been also calculated.
The low level position of excited 4f65d configuration of the Eu(2+) ion has
been expressed using phenomenological dependence on distance E(2+)-F. The
dependences of Stokes shift and Huang-Rhys factor on concentration x have been
received for yellow luminescence in Sr(1-x)Ba(x)F(2):Eu(2+). The value x, for
which the eg -level of Eu(2+) ion will be in conduction band in
Sr(1-x)Ba(x)F(2):Eu(2+) has been calculated.Comment: 8 pages, 3 figures. The manuscript is sent to journal 'Physics of the
solid state'. The results will be submitted on inernational conference
SCINTMAT'2002 in oral session (june,20-22,2002,Ekaterinburg,Russia).
Corresponding author e-mail: [email protected]