Analytical expression for the convolution of a Fano line profile with a Gaussian

Asymmetric Fano line profiles are frequently encountered, e.g., in the photoionization spectra of atoms and ions. For the fitting of spectral line profiles to experimental spectra the line profiles have to be convolved with the experimental window function. The latter is often taken to be a Gaussian. It is shown that the convolution can be represented by a rather simple analytic expression involving the Faddeeva function for the evaluation of which efficient and accurate numerical algorithms are available.Comment: Refined version, old figure removed, new figure, new references, expanded discussion, accepted for publication by the Journal of Quantitative Spectroscopy and Radiative Transfe

Interference effects in the photorecombination of argonlike Sc3+ ions: Storage-ring experiment and theory

Absolute total electron-ion recombination rate coefficients of argonlike Sc3+(3s2 3p6) ions have been measured for relative energies between electrons and ions ranging from 0 to 45 eV. This energy range comprises all dielectronic recombination resonances attached to 3p -> 3d and 3p -> 4s excitations. A broad resonance with an experimental width of 0.89 +- 0.07 eV due to the 3p5 3d2 2F intermediate state is found at 12.31 +- 0.03 eV with a small experimental evidence for an asymmetric line shape. From R-Matrix and perturbative calculations we infer that the asymmetric line shape may not only be due to quantum mechanical interference between direct and resonant recombination channels as predicted by Gorczyca et al. [Phys. Rev. A 56, 4742 (1997)], but may partly also be due to the interaction with an adjacent overlapping DR resonance of the same symmetry. The overall agreement between theory and experiment is poor. Differences between our experimental and our theoretical resonance positions are as large as 1.4 eV. This illustrates the difficulty to accurately describe the structure of an atomic system with an open 3d-shell with state-of-the-art theoretical methods. Furthermore, we find that a relativistic theoretical treatment of the system under study is mandatory since the existence of experimentally observed strong 3p5 3d2 2D and 3p5 3d 4s 2D resonances can only be explained when calculations beyond LS-coupling are carried out.Comment: 11 pages, 7 figures, 3 tables, Phys. Rev. A (in print), see also: http://www.strz.uni-giessen.de/~k

Dielectronic recombination data for astrophysical applications: Plasma rate-coefficients for Fe^q+ (q=7-10, 13-22) and Ni^25+ ions from storage-ring experiments

This review summarizes the present status of an ongoing experimental effort to provide reliable rate coefficients for dielectronic recombination of highly charged iron ions for the modeling of astrophysical and other plasmas. The experimental work has been carried out over more than a decade at the heavy-ion storage-ring TSR of the Max-Planck-Institute for Nuclear Physics in Heidelberg, Germany. The experimental and data reduction procedures are outlined. The role of previously disregarded processes such as fine-structure core excitations and trielectronic recombination is highlighted. Plasma rate coefficients for dielectronic recombination of Fe^q+ ions (q=7-10, 13-22) and Ni^25+ are presented graphically and in a simple parameterized form allowing for easy use in plasma modeling codes. It is concluded that storage-ring experiments are presently the only source for reliable low-temperature dielectronic recombination rate-coefficients of complex ions.Comment: submitted for publication in the International Review of Atomic and Molecular Physics, 8 figures, 3 tables, 68 reference

Enhanced dielectronic recombination of lithium-like Ti19+ ions in external ExB fields

Dielectronic recombination(DR) of lithium-like Ti19+(1s2 2s) ions via 2s->2p core excitations has been measured at the Heidelberg heavy ion storage ring TSR. We find that not only external electric fields (0 <= Ey <= 280 V/cm) but also crossed magnetic fields (30 mT <= Bz <= 80 mT) influence the DR via high-n (2p_j nl)-Rydberg resonances. This result confirms our previous finding for isoelectronic Cl14+ ions [Bartsch T et al, PRL 82, 3779 (1999)] that experimentally established the sensitivity of DR to ExB fields. In the present investigation the larger 2p_{1/2}-2p_{3/2} fine structure splitting of Ti19+ allowed us to study separately the influence of external fields via the two series of Rydberg DR resonances attached to the 2s -> 2p_{1/2} and 2s -> 2p_{3/2} excitations of the Li-like core, extracting initial slopes and saturation fields of the enhancement. We find that for Ey > 80 V/cm the field induced enhancement is about 1.8 times stronger for the 2p_{3/2} series than for the 2p_{1/2} series.Comment: 10 pages, 3 figures, to be published in Journal of Physics B, see also http://www.strz.uni-giessen.de/~k

Near--K-edge double and triple detachment of the F- negative ion: observation of direct two-electron ejection by a single photon

Double and triple detachment of the F-(1s2 2s2 2p6) negative ion by a single photon have been investigated in the photon energy range 660 to 1000 eV. The experimental data provide unambiguous evidence for the dominant role of direct photo-double-detachment with a subsequent single-Auger process in the reaction channel leading to F2+ product ions. Absolute cross sections were determined for the direct removal of a (1s+2p) pair of electrons from F- by the absorption of a single photon