Neutron Scattering and magnetization studies of Ba2_2Cu2.95_{2.95}Co0.05_{0.05}O4_4Cl2_2: A decorated two-dimensional antiferromagnet

Ba$_2$Cu$_3$O$_4$Cl$_2$ has two inter-penetrating square Cu sublattices, one with square root 2 times the in-plane spacing of the other. Isotropic magnetic interactions between the two sublattices are completely frustrated. Quantum fluctuations resolve the intrinsic degeneracy in the ordering direction of the more weakly coupled sublattice in favor of collinear ordering. We present neutron scattering and magnetization studies of the magnetic structure when the Cu ions are substituted with Co. The Co spins create new magnetic interactions between the two sublattices. The ordering behavior of both Cu sublattices is retained largely unmodified. Between the phase transitions of the two sublattices spin-glass behavior is observed. Magnetization results show a strong enhancement to the ferromagnetic aspect of the magnetic structure. The combination of glassy behavior and large moments strongly suggest that the Co moments induce the formation of local canted states.Comment: 4 figure

Vita contemplativa: a life in part

Life, art and science are irremediably intertwined: how, where and with whom one shares the brief moments of existence necessarily affect what one thinks, how one writes, and what one will address. Being a scholar is a vocation, as Weber knew only too well, in which science, ethics and art blend; sometimes seamlessly, sometimes not. None who live an intellectual and public life are immune to the normal glosses of the sociology of knowledge and this paper provides glimpses, through a personal lens, of what such a gloss might see. It is a glimpse of a life still living and lived; an artist still at work, an agenda still being developed, frozen like a snapshot of an instant - and just as representative. Can a snapshot capture an essence? Sometimes. Whether this does is left to others to judge. Copyright © 2005 SAGE Publications

Scalable Peer-to-Peer Streaming for Live Entertainment Content

We present a system for streaming live entertainment content over the Internet originating from a single source to a scalable number of consumers without resorting to centralized or provider-provisioned resources. The system creates a peer-to-peer overlay network, which attempts to optimize use of existing capacity to ensure quality of service, delivering low startup delay and lag in playout of the live content. There are three main aspects of our solution: first, a swarming mechanism that constructs an overlay topology for minimizing propagation delays from the source to end consumers; second, a distributed overlay anycast system that uses a location-based search algorithm for peers to quickly find the closest peers in a given stream; and finally, a novel incentive mechanism that encourages peers to donate capacity even when the user is not actively consuming content

Observations of rotationally resolved C3 in translucent sight lines

The rotationally resolved spectrum of the A ^1Pi_u <- X ^1Sigma^+_g 000-000 transition of C3, centered at 4051.6A, has been observed along 10 translucent lines of sight. To interpret these spectra, a new method for the determination of column densities and analysis of excitation profiles involving the simulation and fitting of observed spectra has been developed. The populations of lower rotational levels (J<14) in C3 are best fit by thermal distributions that are consistent with the kinetic temperatures determined from the excitation profile of C2. Just as in the case of C2, higher rotational levels (J>14) of C3 show increased nonthermal population distributions in clouds which have been determined to have total gas densities below ~500 cm-3.Comment: 12 pages, 4 figures, accepted for publication in The Astrophysical Journa

Foaming, emulsifying and rheological properties of extracts from a co-product of the Quorn fermentation process

Julien Lonchamp - ORCID: 0000-0001-7954-4745 https://orcid.org/0000-0001-7954-4745Item also deposited in University of Edinburgh repository, available at: https://www.research.ed.ac.uk/portal/en/publications/foaming-emulsifying-and-rheological-properties-of-extracts-from-a-coproduct-of-the-quorn-fermentation-process(c1316b1e-0940-4329-8b28-f010f4156548).htmlThis study assessed the functional profile (foaming, emulsifying and rheological properties), proteomic and metabolomic composition of a naturally foaming and currently unexploited co-product (centrate) from the Quorn fermentation process. Due to the low environmental footprint of this process the centrate is a potential source of sustainable functional ingredients for the food industry. A range of fractions were isolated from the centrate via successive ultrafiltration steps. The retentate 100 (R100) fraction, which was obtained following a 100 kDa ultrafiltration, displayed good foaming, emulsifying and rheological properties. R100 solutions and oil-in-water emulsions displayed high viscosity, while R100 solutions and hydrogels showed high viscoelasticity. R100 foams displayed high stability while oil-in-water R100 emulsions showed small and stable oil droplet size distributions. Large mycelial aggregates were reported in R100 solutions and gels, correlating with their high viscosity and viscoelasticity. A dense mycelial network was observed in R100 foams and contributing to their stability. In parallel tensiometry measurements highlighted the presence of interfacially active molecules in R100 which formed a rigid film stabilising the oil/water interface. A number of functional metabolites and proteins were identified in the centrate, including a cerato-platanin protein, cell membrane constituents (phospholipids, sterols, glycosphingolipids, sphingomyelins), cell wall constituents (chitin, chitosan, proteins), guanine and guanine-based nucleosides and nucleotides. This study highlighted the potential of functional extracts from the Quorn fermentation process as novel ingredients for the preparation of sustainable food products and the complex and specific nature of the centrate’s functional profile, with contributions reported for both mycelial structures and interfacially active molecules.This work was supported by the Engineering and Physical Sciences Research Council (Grant number EP/J501682/1 Foaming and Fat Replacer Ingredients).https://doi.org/10.1007/s00217-019-03287-z245pubpu