Collective dissolution of microbubbles

© 2018 American Physical Society. A microscopic bubble of soluble gas always dissolves in finite time in an undersaturated fluid. This diffusive process is driven by the difference between the gas concentration near the bubble, whose value is governed by the internal pressure through Henry's law, and the concentration in the far field. The presence of neighboring bubbles can significantly slow down this process by increasing the effective background concentration and reducing the diffusing flux of dissolved gas experienced by each bubble. We develop theoretical modeling of such diffusive shielding process in the case of small microbubbles whose internal pressure is dominated by Laplace pressure. We first use an exact semianalytical solution to capture the case of two bubbles and analyze in detail the shielding effect as a function of the distance between the bubbles and their size ratio. While we also solve exactly for the Stokes flow around the bubble, we show that hydrodynamic effects are mostly negligible except in the case of almost-touching bubbles. In order to tackle the case of multiple bubbles, we then derive and validate two analytical approximate yet generic frameworks, first using the method of reflections and then by proposing a self-consistent continuum description. Using both modeling frameworks, we examine the dissolution of regular one-, two-, and three-dimensional bubble lattices. Bubbles located at the edge of the lattices dissolve first, while innermost bubbles benefit from the diffusive shielding effect, leading to the inward propagation of a dissolution front within the lattice. We show that diffusive shielding leads to severalfold increases in the dissolution time, which grows logarithmically with the number of bubbles in one-dimensional lattices and algebraically in two and three dimensions, scaling respectively as its square root and 2/3 power. We further illustrate the sensitivity of the dissolution patterns to initial fluctuations in bubble size or arrangement in the case of large and dense lattices, as well as nonintuitive oscillatory effects

Integration of autohydrolysis and organosolv process for recovery of lignin from corncob

Book of Abstracts of CEB Annual Meeting 2017[Excerpt] Lignocelluloses, such as hardwood, softwood and agricultural residues, are low cost feedstocks mainly composed by cellulose, hemicellulose and lignin. Lignin is the third most abundant naturally synthesized polymer. It presents an amorphous polyphenolic structure, which can be used for the development of bio-based materials and chemicals. However, the bioconversion of renewable lignocelluloses to valueadded products requires their fractionation through pretreatment technologies [1,2]. [...]info:eu-repo/semantics/publishedVersio

Viscous growth and rebound of a bubble near a rigid surface

Motivated by the dynamics of microbubbles near catalytic surfaces in bubble-powered microrockets, we consider theoretically the growth of a free spherical bubble near a flat no-slip surface in a Stokes flow. The flow at the bubble surface is characterised by a constant slip length allowing us to tune the hydrodynamic mobility of its surface and tackle in one formulation both clean and contaminated bubbles as well as rigid shells. Starting with a bubble of infinitesimal size, the fluid flow and hydrodynamic forces on the growing bubble are obtained analytically. We demonstrate that, depending on the value of the bubble slip length relative to the initial distance to the wall, the bubble will either monotonically drain the fluid separating it from the wall, which will exponentially thin, or it will bounce off the surface once before eventually draining the thin film. Clean bubbles are shown to be a singular limit which always monotonically get repelled from the surface. The bouncing events for bubbles with finite slip lengths are further analysed in detail in the lubrication limit. In particular, we identify the origin of the reversal of the hydrodynamic force direction as due to the change in the flow pattern in the film between the bubble and the surface and to the associated lubrication pressure. Last, the final drainage dynamics of the film is observed to follow a universal algebraic scaling for all finite slip lengths.ER

Self-propulsion in 2D Confinement: Phoretic and Hydrodynamic Interactions

Chemically active Janus particles generate tangential concentration gradients along their surface for self-propulsion. Although this is well studied in unbounded domains, the analysis in biologically relevant environments such as confinements is scarce. In this work, we study the motion of a Janus sphere in weak confinement. The particle is placed at an arbitrary location, with an arbitrary orientation between the two walls. Using the method of reflections, we study the effect of confining planar boundaries on the phoretic and hydrodynamic interactions, and their consequence on the Janus particle dynamics. The dynamical trajectories are analyzed using phase diagrams for different surface coverage of activity and solute-particle interactions. In addition to near wall states such as `sliding' and `hovering', we demonstrate that accounting for two planar boundaries reveals two new states: channel-spanning oscillations and damped oscillations around the centerline, which were characterized as `scattering' or `reflection' by earlier analyses on single-wall interactions. Using phase diagrams, we highlight the differences in inert-facing and active-facing Janus particles. We also compare the dynamics of Janus particles with squirmers for contrasting the chemical interactions with hydrodynamic effects. Insights from the current work suggest that biological and artificial swimmers sense their surroundings through long-ranged interactions, that can be modified by altering the surface properties.Comment: To appear in European Physical Journal

Geometric tuning of self-propulsion for Janus catalytic particles

Catalytic swimmers have attracted much attention as alternatives to biological systems for examining collective microscopic dynamics and the response to physico-chemical signals. Yet, understanding and predicting even the most fundamental characteristics of their individual propulsion still raises important challenges. While chemical asymmetry is widely recognized as the cornerstone of catalytic propulsion, different experimental studies have reported that particles with identical chemical properties may propel in opposite directions. Here, we show that, beyond its chemical properties, the detailed shape of a catalytic swimmer plays an essential role in determining its direction of motion, demonstrating the compatibility of the classical theoretical framework with experimental observations.This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme under grant agreements 714027 (S.M.) and 682754 (E.L.)

B-FERL: Blockchain based Framework for Securing Smart Vehicles

The ubiquity of connecting technologies in smart vehicles and the incremental automation of its functionalities promise significant benefits, including a significant decline in congestion and road fatalities. However, increasing automation and connectedness broadens the attack surface and heightens the likelihood of a malicious entity successfully executing an attack. In this paper, we propose a Blockchain based Framework for sEcuring smaRt vehicLes (B-FERL). B-FERL uses permissioned blockchain technology to tailor information access to restricted entities in the connected vehicle ecosystem. It also uses a challenge-response data exchange between the vehicles and roadside units to monitor the internal state of the vehicle to identify cases of in-vehicle network compromise. In order to enable authentic and valid communication in the vehicular network, only vehicles with a verifiable record in the blockchain can exchange messages. Through qualitative arguments, we show that B-FERL is resilient to identified attacks. Also, quantitative evaluations in an emulated scenario show that B-FERL ensures a suitable response time and required storage size compatible with realistic scenarios. Finally, we demonstrate how B-FERL achieves various important functions relevant to the automotive ecosystem such as trust management, vehicular forensics and secure vehicular networks.Comment: 11 Pages, 8 Figure

Resonance-induced enhancement of the energy harvesting performance of piezoelectric flags

International audienceThe spontaneous flapping of a flag can be used to produce electrical energy from a fluid flow when coupled to a generator. In this paper, the energy harvesting performance of a flag covered by a single pair of polyvinylidene difluoride piezoelectricelectrodes is studied both experimentally and numerically. The electrodes are connected to a resistive-inductive circuit that forms a resonant circuit with the piezoelectric's intrinsic capacitance. Compared with purely resistive circuits, the resonance between the circuit and the flag's flapping motion leads to a significant increase in the harvested energy. Our experimental study also validates our fluid-solid-electric nonlinear numerical model

Phoretic flow induced by asymmetric confinement

Internal phoretic flows due to the interactions of solid boundaries with local chemical gradients may be created using chemical patterning. Alternatively, we demonstrate here that internal flows might also be induced by geometric asymmetries of chemically homogeneous surfaces. We characterise the circulatory flow created in a cavity enclosed between two eccentric cylindrical walls of uniform chemical activity. Local gradients of the diffusing solute induce a slip flow along the surface of the cylinders, leading to a circulatory bulk flow pattern which can be solved analytically in the diffusive limit. The flow strength can be controlled by adjusting the relative positions of the cylinders, and an optimal configuration is identified. These results provide a model system for tunable phoretic pumps.This work was funded in part by a David Crighton Fellowship at the University of Cambridge (ML), a Mobility Plus Fellowship from the Polish Ministry of Science and Higher Education (ML), the EU through a Marie-Curie CIG grant (EL) and the French Ministry of Defense DGA (SM).This is the author accepted manuscript. The final version is available from Cambridge University Press via http://dx.doi.org/10.1017/jfm.2016.40