The failure mechanism of a nickel electrode in a nickel-hydrogen cell

Studies on a number of types of nickel electrodes after cycle failure in a Ni/H2 cell showed that the failure is due to the loss of high rate discharge capability rather than an absolute capacity loss. The failure mechanism is speculated to be a combination of migration of the active material away from the current collecting nickel sinter, increased porosity of the active material caused by cycling, and an electrical isolation process of the active material during discharge

Long Life Nickel Electrodes for a Nickel-hydrogen Cell: Cycle Life Tests

In order to develop a long life nickel electrode for a Ni/H2 cell, cycle life tests of nickel electrodes were carried out in Hi/H2 boiler plate cells. A 19 test cell matrix was made of various nickel electrode designs including three levels each of plaque mechanical strength, median pore size of the plaque, and active material loading. Test cells were cycled to the end of their life (0.5v) in a 45-minute low earth orbit cycle regime at 80% depth-of-discharge. The results show that the active material loading level affects the cycle life the most with the optimum loading at 1.6 g/cc void. Mechanical strength did not affect the cycle life noticeably in the bend strength range of 400 to 700 psi. The best plaque type appears to be one which is made of INCO nickel powder type 287 and has a median pore size of 13 micron

KOH concentration effect on the cycle life of nickel-hydrogen cells. Part 4: Results of failure analyses

KOH concentration effects on cycle life of a Ni/H2 cell have been studied by carrying out a cycle life test of ten Ni/H2 boiler plate cells which contain electrolytes of various KOH concentrations. Failure analyses of these cells were carried out after completion of the life test which accumulated up to 40,000 cycles at an 80 percent depth of discharge over a period of 3.7 years. These failure analyses included studies on changes of electrical characteristics of test cells and component analyses after disassembly of the cell. The component analyses included visual inspections, dimensional changes, capacity measurements of nickel electrodes, scanning electron microscopy, BET surface area measurements, and chemical analyses. Results have indicated that failure mode and change in the nickel electrode varied as the concentration was varied, especially, when the concentration was changed from 31 percent or higher to 26 percent or lower

A prediction model of the depth-of-discharge effect on the cycle life of a storage cell

Cycle life requirements are very high for batteries used in aerospace applications in low Earth orbit. The data base required to establish confidence in a particular cell design is thus both extensive and expensive. Reliable accelerated cycle life testing and performance decay modeling represent attractive alternatives to real-time tests of cycle life. In light of certain long-term cycle life test results, this paper examines a very simple performance decay model developed earlier. Application of that model to available data demonstrates a rigid relationship between a battery's expected cycle life and the depth of discharge of cycling. Further, modeling analysis of the data suggests that a significantly improved cycle life can be obtained with advanced components, materials, and designs; and that cycle life can be reliably predicted from the results of accelerated testing

Hadronic B Decays to Charmless VT Final States

Charmless hadronic decays of B mesons to a vector meson (V) and a tensor meson (T) are analyzed in the frameworks of both flavor SU(3) symmetry and generalized factorization. We also make comments on B decays to two tensor mesons in the final states. Certain ways to test validity of the generalized factorization are proposed, using $B \to VT$ decays. We calculate the branching ratios and CP asymmetries using the full effective Hamiltonian including all the penguin operators and the form factors obtained in the non-relativistic quark model of Isgur, Scora, Grinstein and Wise.Comment: 27 pages, no figures, LaTe

Determinations of upper critical field in continuous Ginzburg-Landau model

Novel procedures to determine the upper critical field $B_{c2}$ have been proposed within a continuous Ginzburg-Landau model. Unlike conventional methods, where $B_{c2}$ is obtained through the determination of the smallest eigenvalue of an appropriate eigen equation, the square of the magnetic field is treated as eigenvalue problems so that the upper critical field can be directly deduced. The calculated $B_{c2}$ from the two procedures are consistent with each other and in reasonably good agreement with existing theories and experiments. The profile of the order parameter associated with $B_{c2}$ is found to be Gaussian-like, further validating the methodology proposed. The convergences of the two procedures are also studied.Comment: Revtex4, 8 pages, 4 figures, references modified, figures and table embedde