159 research outputs found
DEVELOPING THE METHODS OF FOOD PRESERVATIVES EXTRACTION FROM COMPLEX MATRICES FOR BIOASSAY PURPOSE
The presence of food additives in food products may be associated with the risk of their toxic effects on human body. Therefore, the study of approaches to testing their safety seems to be a particularly urgent task. The aim of this study was to determine the conditions for extracting food preservatives from the samples of preserved pureed vegetables for further bioassay of the extract obtained in the Allium test. Onion roots were used as a test object in this method. Two extraction methods of benzoic and sorbic acids added to pureed vegetables have been developed. Distilled water and acetone were used as extracting solutions. The extraction efficiency was evaluated on Shimadzu Prominence LC-20 liquid chromatograph (Japan) in the ultraviolet range, wavelength 235 nm (benzoic acid), 285 nm (sorbic acid). According to the results of studies using both water and acetone as extractants, the degree of preservatives extraction was approximately the same and quite high. In the quantitative calculation of the preservatives content in pureed vegetables, the value of the correction factor was 0.8. However, due to certain production characteristics of this product, i. e. the stage of cauliflower homogenization, obtaining an extract with acetone seems to be more acceptable for the Allium test conditions.The presence of food additives in food products may be associated with the risk of their toxic effects on human body. Therefore, the study of approaches to testing their safety seems to be a particularly urgent task. The aim of this study was to determine the conditions for extracting food preservatives from the samples of preserved pureed vegetables for further bioassay of the extract obtained in the Allium test. Onion roots were used as a test object in this method. Two extraction methods of benzoic and sorbic acids added to pureed vegetables have been developed. Distilled water and acetone were used as extracting solutions. The extraction efficiency was evaluated on Shimadzu Prominence LC-20 liquid chromatograph (Japan) in the ultraviolet range, wavelength 235 nm (benzoic acid), 285 nm (sorbic acid). According to the results of studies using both water and acetone as extractants, the degree of preservatives extraction was approximately the same and quite high. In the quantitative calculation of the preservatives content in pureed vegetables, the value of the correction factor was 0.8. However, due to certain production characteristics of this product, i. e. the stage of cauliflower homogenization, obtaining an extract with acetone seems to be more acceptable for the Allium test conditions
Novel magnetic phases in a Gd2Ti2O7 pyrochlore for a field applied along the [100] axis
We report on longitudinal and transverse magnetisation measurements performed
on single crystal samples of Gd2Ti2O7 for a magnetic field applied along the
[100] direction. The measurements reveal the presence of previously unreported
phases in fields below 10 kOe in an addition to the higher-field-induced phases
that are also seen for H//[111], [110], and [112]. The proposed H-T phase
diagram for the [100] direction looks distinctly different from all the other
directions studied previously.Comment: 4 pages, 5 figure
Electron spin resonance study of anisotropic interactions in a two-dimensional spin gap magnet PHCC
Fine details of the excitation spectrum of the two-dimensional spin-gap
magnet PHCC are revealed by electron spin resonance investigations. The values
of anisotropy parameters and the orientations of the anisotropy axes are
determined by accurate measurements of the angular, frequency-field and
temperature dependences of the resonance absorption. The properties of a
spin-gap magnet in the vicinity of critical field are discussed in terms of
sublevel splittings and g-factor anisotropy.Comment: submitted to PR
ESR study of the spin ladder with uniform Dzyaloshinskii-Moria interaction
Evolution of the ESR absorption in a strong-leg spin ladder magnet
(CHN)CuBr (abbreviated as DIMPY) is studied from 300K to
400mK. Temperature dependence of the ESR relaxation follows a staircase of
crossovers between different relaxation regimes. We ague that the main
mechanism of ESR line broadening in DIMPY is uniform Dzyaloshinskii-Moria
interaction (K) with an effective longitudinal component along
an exchange bond of Cu ions within the legs resulting from the low crystal
symmetry of DIMPY and nontrivial orbital ordering. The same
Dzyaloshinskii-Moriya interaction results in the lifting of the triplet
excitation degeneracy, revealed through the weak splitting of the ESR
absorption at low temperatures.Comment: 13 pages, submitted to PRB, Fig.3 update
Spin Dynamics of in the Field-Induced Ordered Phase
- (known as DTN) is a spin-1 material with a strong
single-ion anisotropy that is regarded as a new candidate for Bose-Einstein
condensation (BEC) of spin degrees of freedom. We present a systematic study of
the low-energy excitation spectrum of DTN in the field-induced magnetically
ordered phase by means of high-field electron spin resonance measurements at
temperatures down to 0.45 K. We argue that two gapped modes observed in the
experiment can be consistently interpreted within a four-sublattice
antiferromagnet model with a finite interaction between two tetragonal
subsystems and unbroken axial symmetry. The latter is crucial for the
interpretation of the field-induced ordering in DTN in terms of BEC.Comment: 4 pages, 3 figure
High-frequency dielectric anomalies in a highly frustrated square kagome lattice nabokoite family compounds ACu(TeO)(SO)Cl (A=Na, K, Rb, Cs)
Nabokoite family compounds ACu(TeO)(SO)Cl (A=Na, K, Cs, Rb)
are candidates for the experimental realization of highly-frustrated 2D square
kagome lattice (SKL). Their magnetic subsystem includes SKL layers decorated by
additional copper ions. All members of this family are characterized by quite
high Curie-Weiss temperatures ( K), but magnetic ordering was
reported only for Na and K compounds at a much lower temperatures below 4 K. We
report here results of the study of high-frequency ( GHz) dielectric
properties of this family of compounds. Our study revealed presence of the
strong dielectric anomaly both in the real and imaginary parts of
high-frequency dielectric permittivity for Na and K compounds approx. 100 and
26 K, correspondingly, presumably related to antiferroelectric ordering.
Additionally, much weaker anomalies were observed at approximately 5K
indicating possible interplay of magnetic and lattice degrees of freedom. We
discuss possible relation between the structure rearrangements accompanying
dielectric anomalies and a delayed magnetic ordering in the nabokoite family
compounds.Comment: 12 pages, 8 figure
Paramagnetic and antiferromagnetic resonances in the diamagnetically diluted Haldane magnet PbNi2V2O8
The impurity-induced antiferromagnetic ordering of the doped Haldane magnet
Pb(Ni{1-x}Mg{x})2V2O8 (0 < x <0.06) was studied by electron spin resonance
(ESR) on ceramic samples in the frequency range 9-110 GHz. Below the N\'{e}el
temperature a transformation of the ESR spectrum was found, indicating an
antiferromagnetic resonance mode of spin precession. The excitation gap of the
spin-wave spectrum increases with increasing Mg-concentration in the same
manner as the N\'{e}el temperature, reaching its maximum value of 80 GHz at x >
0.04. At small concentrations x < 0.02 the signals of antiferromagnetic
resonance were found to coexist with the signal of the paramagnetic resonance
indicating a microscopic separation of the magnetic phases.Comment: 10 pages, 9 figure
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