494 research outputs found

    The nature of iron-oxygen vacancy defect centers in PbTiO3

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    The iron(III) center in ferroelectric PbTiO3 together with an oxygen vacancy forms a charged defect associate, oriented along the crystallographic c-axis. Its microscopic structure has been analyzed in detail comparing results from a semi-empirical Newman superposition model analysis based on finestructure data and from calculations using density functional theory. Both methods give evidence for a substitution of Fe3+ for Ti4+ as an acceptor center. The position of the iron ion in the ferroelectric phase is found to be similar to the B-site in the paraelectric phase. Partial charge compensation is locally provided by a directly coordinated oxygen vacancy. Using high-resolution synchrotron powder diffraction, it was verified that lead titanate remains tetragonal down to 12 K, exhibiting a c/a-ratio of 1.0721.Comment: 11 pages, 5 figures, accepted in Phys. Rev.

    Mapping Kenyan grassland heights across large spatial scales with combined optical and radar satellite imagery

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    Grassland monitoring can be challenging because it is time-consuming and expensive to measure grass condition at large spatial scales. Remote sensing offers a time- and cost-effective method for mapping and monitoring grassland condition at both large spatial extents and fine temporal resolutions. Combinations of remotely sensed optical and radar imagery are particularly promising because together they can measure differences in moisture, structure, and reflectance among land cover types. We combined multi-date radar (PALSAR-2 and Sentinel-1) and optical (Sentinel-2) imagery with field data and visual interpretation of aerial imagery to classify land cover in the Masai Mara National Reserve, Kenya using machine learning (Random Forests). This study area comprises a diverse array of land cover types and changes over time due to seasonal changes in precipitation, seasonal movements of large herds of resident and migratory ungulates, fires, and livestock grazing. We classified twelve land cover types with user’s and producer’s accuracies ranging from 66%–100% and an overall accuracy of 86%. These methods were able to distinguish among short, medium, and tall grass cover at user’s accuracies of 83%, 82%, and 85%, respectively. By yielding a highly accurate, fine-resolution map that distinguishes among grasses of different heights, this work not only outlines a viable method for future grassland mapping efforts but also will help inform local management decisions and research in the Masai Mara National Reserve

    Spatial distribution of micrometre‐scale porosity and permeability across the damage zone of a reverse‐reactivated normal fault in a tight sandstone : Insights from the Otway Basin, SE Australia

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    This research forms part of a PhD project supported by the Australian Research Council [Discovery Project DP160101158] and through an Australian Government Research Training Program Scholarship. Dave Healy acknowledges the support of the Natural Environment Research Council (NERC, UK) through the award NE/N003063/1 ‘Quantifying the Anisotropy of Permeability in Stressed Rock’. This study was also funded by scholarships from the Petroleum Exploration Society of Australia and the Australian Petroleum Production and Exploration Association. We thank Gordon Holm for preparing thin sections and Colin Taylor for carrying out particle size measurements and mercury injection capillary pressure analyses. Aoife McFadden and David Kelsey from Adelaide Microscopy, Braden Morgan, and Sophie Harland are acknowledged for their assistance with laboratory work. Field assistants James Hall, Rowan Hansberry, and Lachlan Furness are also gratefully acknowledged for their assistance with sample collection. Discussions with Ian Duddy on the mineralogy of the Eumeralla Formation are also greatly appreciated. This forms TRaX record 416.Peer reviewedPublisher PD

    Naturally propped fractures caused by quartz cementation preserve oil reservoirs in basement rocks

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    MB is in receipt of a postgraduate studentship from PTDF (Nigeria). Skilled technical support was provided by M. Baron and J. Still. Two reviewers made valuable criticisms that improved the paper.Peer reviewedPostprin

    Elevated blood pressures in mice lacking endothelial nitric oxide synthase

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    Nitric oxide produced in endothelial cells affects vascular tone. To investigate the role of endothelial nitric oxide synthase (eNOS) in blood pressure regulation, we have generated mice heterozygous (+/−) or homozygous (−/−) for disruption of the eNOS gene. Immunohistochemical staining with anti-eNOS antibodies showed reduced amounts of eNOS protein in +/− mice and absence of eNOS protein in −/− mutant mice. Male or female mice of all three eNOS genotypes were indistinguishable in general appearance and histology, except that −/− mice had lower body weights than +/+ or +/− mice. Blood pressures tended to be increased (by approximately 4 mmHg) in +/− mice compared with +/+, while −/− mice had a significant increase in pressure compared with +/+ mice (≈18 mmHg) or +/− mice (≈14 mmHg). Plasma renin concentration in the −/− mice was nearly twice that of +/+ mice, although kidney renin mRNA was modestly decreased in the −/− mice. Heart rates in the −/− mice were significantly lower than in +/− or +/+ mice. Appropriate genetic controls show that these phenotypes in F2 mice are due to the eNOS mutation and are not due to sequences that might differ between the two parental strains (129 and C57BL/6J) and are linked either to the eNOS locus or to an unlinked chromosomal region containing the renin locus. Thus eNOS is essential for maintenance of normal blood pressures and heart rates. Comparisons between the current eNOS mutant mice and previously generated inducible nitric oxide synthase mutants showed that homozygous mutants for the latter differ in having unaltered blood pressures and heart rates; both are susceptible to lipopolysaccharide-induced death
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