Hopping and clustering of oxygen vacancies in SrTiO3 by anelastic relaxation

The complex elastic compliance s11(w,T) of SrTiO3-d has been measured as a function of the O deficiency d < 0.01. The two main relaxation peaks in the absorption are identified with hopping of isolated O vacancies over a barrier of 0.60 eV and reorientation of pairs of vacancies involving a barrier of 1 eV. The pair binding energy is ~0.2 eV and indications for additional clustering, possibly into chains, is found already at d ~0.004. The anistropic component of the elastic dipole of an O vacancy is Deltalambda = 0.026.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let

Algebraic treatment of the confluent Natanzon potentials

Using the so(2,1) Lie algebra and the Baker, Campbell and Hausdorff formulas, the Green's function for the class of the confluent Natanzon potentials is constructed straightforwardly. The bound-state energy spectrum is then determined. Eventually, the three-dimensional harmonic potential, the three-dimensional Coulomb potential and the Morse potential may all be considered as particular cases.Comment: 9 page

An Analytical Study of Ozone Feedbacks on Kelvin and Rossby–Gravity Waves: Effects on the QBO

An equatorial beta-plane model of the middle atmosphere is used to analytically examine the effects of radiative cooling and ozone heating on the spatial and temporal evolution of the quasi-biennial oscillation (QBO). Under the assumption that the diabatic heating is weak and the background fields of wind, temperature, and ozone are slowly varying, a perturbation analysis yields expressions describing the vertical spatial modulation of Kelvin and Rossby–gravity waves in the presence of ozone. These expressions show that wave-induced changes in the diabatic heating arising from the advection of basic-state ozone reduce the local radiative damping rate by up to 15% below 35 km. In a one-dimensional model of the QBO, eddy ozone heating increases the amplitude of the zonal wind QBO by 1–2 m s−1 and increases the oscillation period by about two months. The significance of these results to the observed QBO is discussed

Effect of doping and oxygen vacancies on the octahedral tilt transitions in the BaCeO3 perovskite

We present a systematic study of the effect of Y doping and hydration level on the structural transformations of BaCeO3 based on anelastic spectroscopy experiments. The temperature of the intermediate transformation between rhombohedral and orthorhombic Imma phases rises with increasing the molar fraction x of Y roughly as (500 K)x in the hydrated state, and is depressed of more than twice that amount after complete dehydration. This is explained in terms of the effect of doping on the average (Ce/Y)-O and Ba-O bond lengths, and of lattice relaxation from O vacancies. The different behavior of the transition to the lower temperature Pnma orthorhombic phase is tentatively explained in terms of progressive flattening of the effective shape of the OH ion and ordering of the O vacancies during cooling.Comment: 8 pages, 5 figure