204 research outputs found
Phase Transition in a One-Dimensional Extended Peierls-Hubbard Model with a Pulse of Oscillating Electric Field: I. Threshold Behavior in Ionic-to-Neutral Transition
Photoinduced dynamics of charge density and lattice displacements is
calculated by solving the time-dependent Schr\"odinger equation for a
one-dimensional extended Peierls-Hubbard model with alternating potentials for
the mixed-stack organic charge-transfer complex, TTF-CA. A pulse of oscillating
electric field is incorporated into the Peierls phase of the transfer integral.
The frequency, the amplitude, and the duration of the pulse are varied to study
the nonlinear and cooperative character of the photoinduced transition. When
the dimerized ionic phase is photoexcited, the threshold behavior is clearly
observed by plotting the final ionicity as a function of the increment of the
total energy. Above the threshold photoexcitation, the electronic state reaches
the neutral one with equidistant molecules after the electric field is turned
off. The transition is initiated by nucleation of a metastable neutral domain,
for which an electric field with frequency below the linear absorption peak is
more effective than that at the peak. When the pulse is strong and short, the
charge transfer takes place on the same time scale with the disappearance of
dimerization. As the pulse becomes weak and long, the dimerization-induced
polarization is disordered to restore the inversion symmetry on average before
the charge transfer takes place to bring the system neutral. Thus, a
paraelectric ionic phase is transiently realized by a weak electric field. It
is shown that infrared light also induces the ionic-to-neutral transition,
which is characterized by the threshold behavior.Comment: 24 pages, 11 figure
Novel mechanism of photoinduced reversible phase transitions in molecule-based magnets
A novel microscopic mechanism of bi-directional structural changes is
proposed for the photo-induced magnetic phase transition in Co-Fe Prussian blue
analogues on the basis of ab initio quantum chemical cluster calculations. It
is shown that the local potential energies of various spin states of Co are
sensitive to the number of nearest neighbor Fe vacancies. As a result, the
forward and backward structural changes are most readily initiated by
excitation of different local regions by different photons. This mechanism
suggests an effective strategy to realize photoinduced reversible phase
transitions in a general system consisting of two local components.Comment: 4 pages, LaTex, 3 figures, to appear in Phys. Rev. Let
Direct evidence of electronic ferroelectricity in YbFe2O4 using neutron diffraction and nonlinear spectroscopy
We report the first observation of room temperature spontaneous electric polarization in an electronic ferroelectric material, a YbFe2O4 single crystal. The observation was based on second harmonic generation (SHG), a nonlinear optical process. Tensor analysis of the SHG signal revealed that this material has a polar charge superstructure with Cm symmetry. This result settles the long-term discussion on the uncertainty about electronic ferroelectric properties, including the charge order structure. We present a complete picture of the polar charge ordering of this material via consistent results from two different characterization methods. The SHG signal shows the same temperature dependence as the superlattice signal observed in neutron diffraction experiments. These results prove ferroelectric coupling to electron ordering in YbFe2O4, which results in electronic ferroelectricity which is enabled by the real space ordering of iron cations with different valences. The existence of electronic ferroelectricity holds promise for future electronics technologies where devices run a thousand times faster than frequency of the present CPU (a few gigahertz) embedded in smartphones, etc
Charge-Transfer Excitations in One-Dimensional Dimerized Mott Insulators
We investigate the optical properties of one-dimensional (1D) dimerized Mott
insulators using the 1D dimerized extended Hubbard model. Numerical
calculations and a perturbative analysis from the decoupled-dimer limit clarify
that there are three relevant classes of charge-transfer (CT) states generated
by photoexcitation: interdimer CT unbound states, interdimer CT exciton states,
and intradimer CT exciton states. This classification is applied to
understanding the optical properties of an organic molecular material,
1,3,5-trithia-2,4,6-triazapentalenyl (TTTA), which is known for its
photoinduced transition from the dimerized spin-singlet phase to the regular
paramagnetic phase. We conclude that the lowest photoexcited state of TTTA is
the interdimer CT exciton state and the second lowest state is the intradimer
CT exciton state.Comment: 6 pages, 6 figures, to be published in J. Phys. Soc. Jp
Effects of Lattice and Molecular Phonons on Photoinduced Neutral-to-Ionic Transition Dynamics in Tetrathiafulvalene--Chloranil
For electronic states and photoinduced charge dynamics near the neutral-ionic
transition in the mixed-stack charge-transfer complex
tetrathiafulvalene--chloranil (TTF-CA), we review the effects of Peierls
coupling to lattice phonons modulating transfer integrals and Holstein
couplings to molecular vibrations modulating site energies. The former
stabilizes the ionic phase and reduces discontinuities in the phase transition,
while the latter stabilizes the neutral phase and enhances the discontinuities.
To reproduce the experimentally observed ionicity, optical conductivity and
photoinduced charge dynamics, both couplings are quantitatively important. In
particular, strong Holstein couplings to form the highly-stabilized neutral
phase are necessary for the ionic phase to be a Mott insulator with large
ionicity. A comparison with the observed photoinduced charge dynamics indicates
the presence of strings of lattice dimerization in the neutral phase above the
transition temperature.Comment: 9 pages, 7 figures, accepted for publication in J. Phys. Soc. Jp
Electronic and Lattice Dynamics in The Photoinduced Ionic-to-Neutral Phase Transition in a One-Dimensional Extended Peierls-Hubbard Model
Real-time dynamics of charge density and lattice displacements is studied
during photoinduced ionic-to-neutral phase transitions by using a
one-dimensional extended Peierls-Hubbard model with alternating potentials for
the one-dimensional mixed-stack charge-transfer complex, TTF-CA. The
time-dependent Schr\"odinger equation and the classical equation of motion are
solved for the electronic and lattice parts, respectively. We show how neutral
domains grow in the ionic background. As the photoexcitation becomes intense,
more neutral domains are created. Above threshold intensity, the neutral phase
is finally achieved. After the photoexcitation, ionic domains with wrong
polarization also appear. They quickly reduce the averaged staggered lattice
displacement, compared with the averaged ionicity. As the degree of initial
lattice disorder increases, more solitons appear between these ionic domains
with different polarizations, which obstruct the growth of neutral domains and
slow down the transition.Comment: 9 pages, 10 figures, submitted to J. Phys. Soc. Jp
Effect of sodium n-butyrate on induction of prostaglandin synthase activity in cloned mastocytoma P-815 2-E-6 cells
Photoinduced metallic properties of one-dimensional strongly correlated electron systems
We study photoinduced optical responses of one-dimensional strongly
correlated electron systems. The optical conductivity spectra are calculated
for the ground state and a photoexcited state in the one-dimensional Hubbard
model at half filling by using the exact diagonalization method. It is found
that, in the Mott insulator phase, the photoexcited state has large spectral
weights including the Drude weight below the optical gap. As a consequence, the
spectral weight above the optical gap is largely reduced. These results imply
that a metallic state is induced by photoexcitation. Comparison between the
photoexcited and hole-doped states shows that the photoexcitation is similar to
chemical doping.Comment: 4 pages, 4 figures, submitted to J. Phys. Soc. Jp
High-Temperature Hall Effect in Ga(1-x)Mn(x)As
The temperature dependence of the Hall coefficient of a series of
ferromagnetic Ga(1-x)Mn(x)As samples is measured in the temperature range 80K <
T < 500K. We model the Hall coefficient assuming a magnetic susceptibility
given by the Curie-Weiss law, a spontaneous Hall coefficient proportional to
rho_xx^2(T), and including a constant diamagnetic contribution in the
susceptibility. For all low resistivity samples this model provides excellent
fits to the measured data up to T=380K and allows extraction of the hole
concentration (p). The calculated p are compared to alternative methods of
determining hole densities in these materials: pulsed high magnetic field (up
to 55 Tesla) technique at low temperatures (less than the Curie temperature),
and electrochemical capacitance- voltage profiling. We find that the Anomalous
Hall Effect (AHE) contribution to rho_xy is substantial even well above the
Curie temperature. Measurements of the Hall effect in this temperature regime
can be used as a testing ground for theoretical descriptions of transport in
these materials. We find that our data are consistent with recently published
theories of the AHE, but they are inconsistent with theoretical models
previously used to describe the AHE in conventional magnetic materials.Comment: 6 pages, 5 figures, 1 table. Accepted to Phys.Rev.
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