Generalized convective quasi-equilibrium principle

A generalization of Arakawa and Schubert's convective quasi-equilibrium principle is presented for a closure formulation of mass-flux convection parameterization. The original principle is based on the budget of the cloud work function. This principle is generalized by considering the budget for a vertical integral of an arbitrary convection-related quantity. The closure formulation includes Arakawa and Schubert's quasi-equilibrium, as well as both CAPE and moisture closures as special cases. The formulation also includes new possibilities for considering vertical integrals that are dependent on convective-scale variables, such as the moisture within convection. The generalized convective quasi-equilibrium is defined by a balance between large-scale forcing and convective response for a given vertically-integrated quantity. The latter takes the form of a convolution of a kernel matrix and a mass-flux spectrum, as in the original convective quasi-equilibrium. The kernel reduces to a scalar when either a bulk formulation is adopted, or only large-scale variables are considered within the vertical integral. Various physical implications of the generalized closure are discussed. These include the possibility that precipitation might be considered as a potentially-significant contribution to the large-scale forcing. Two dicta are proposed as guiding physical principles for the specifying a suitable vertically-integrated quantity

Bells and whistles of convection parameterization

The present workshop constitutes the 5th in the annual series on “Concepts for Convective Parameterizations in Large-Scale Models”. The purpose of the workshop series has been to discuss the fundamental theoretical issues of convection parameterization with a small number of European scientists. The workshop series has been funded by European Cooperation in the Field of Scientific and Technical Research (COST) Action ES0905. The theme of the workshop for the year 2012 was decided from a main conclusion of the previous workshop, which focused on the convective organization problem, seeking a means for implementing such effects into convection parameterizations (Yano et al. 2012). As it turned out, in order to discuss this implementation issue in any concrete manner, we have first to know very well the bells and whistles of convection parameterizations. This was the purpose of the 5th workshop. The title of the workshop is rather metaphorically tagged as “Bulk or Spectrum?”, because this is a typical decision we have to face at the outset of any parameterization development. The following report discusses selected issues of bells and whistles addressed during the meeting

A Remarkably Stable and Simple Monocyclic Thiepin. Synthesis and Properties of 2, 7-Di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin

A simple monocyclic 8n electron thiepin, 2,7-di-tert-butyl-4- -ethoxycarbonyl-5-methylthiepin (13) stabilized by two bulky tert- -butyl groups at 2- and 7-positions, was synthesized from 2,6-di- -tert-butyl-4-methylthiopyrylium tetrafluoroborate (11). In spite of of its monocyclic thiepin structure, the compound 13 showed remarkable thermal stability and had a half-life of 7.1 h at 130 °C. Judging from the 1H-NMR spectrum, the thiepin 13 is considered to be an atropic molecule. Synthetic details of 11 and 13, and the chemical and physical properties of 13 are also described

A Remarkably Stable and Simple Monocyclic Thiepin. Synthesis and Properties of 2, 7-Di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin

A simple monocyclic 8n electron thiepin, 2,7-di-tert-butyl-4- -ethoxycarbonyl-5-methylthiepin (13) stabilized by two bulky tert- -butyl groups at 2- and 7-positions, was synthesized from 2,6-di- -tert-butyl-4-methylthiopyrylium tetrafluoroborate (11). In spite of of its monocyclic thiepin structure, the compound 13 showed remarkable thermal stability and had a half-life of 7.1 h at 130 °C. Judging from the 1H-NMR spectrum, the thiepin 13 is considered to be an atropic molecule. Synthetic details of 11 and 13, and the chemical and physical properties of 13 are also described

Geometry and stability of dynamical systems

We reconsider both the global and local stability of solutions of continuously evolving dynamical systems from a geometric perspective. We clarify that an unambiguous definition of stability generally requires the choice of additional geometric structure that is not intrinsic to the dynamical system itself. While global Lyapunov stability is based on the choice of seminorms on the vector bundle of perturbations, we propose a definition of local stability based on the choice of a linear connection. We show how this definition reproduces known stability criteria for second order dynamical systems. In contrast to the general case, the special geometry of Lagrangian systems provides completely intrinsic notions of global and local stability. We demonstrate that these do not suffer from the limitations occurring in the analysis of the Maupertuis-Jacobi geodesics associated to natural Lagrangian systems.Comment: 22 pages, 2 figure

Deformation Quantization of Almost Kahler Models and Lagrange-Finsler Spaces

Finsler and Lagrange spaces can be equivalently represented as almost Kahler manifolds enabled with a metric compatible canonical distinguished connection structure generalizing the Levi Civita connection. The goal of this paper is to perform a natural Fedosov-type deformation quantization of such geometries. All constructions are canonically derived for regular Lagrangians and/or fundamental Finsler functions on tangent bundles.Comment: the latex 2e variant of the manuscript accepted for JMP, 11pt, 23 page

On the geometric quantization of twisted Poisson manifolds

We study the geometric quantization process for twisted Poisson manifolds. First, we introduce the notion of Lichnerowicz-twisted Poisson cohomology for twisted Poisson manifolds and we use it in order to characterize their prequantization bundles and to establish their prequantization condition. Next, we introduce a polarization and we discuss the quantization problem. In each step, several examples are presented

Hidden symmetries and Killing tensors on curved spaces

Higher order symmetries corresponding to Killing tensors are investigated. The intimate relation between Killing-Yano tensors and non-standard supersymmetries is pointed out. In the Dirac theory on curved spaces, Killing-Yano tensors generate Dirac type operators involved in interesting algebraic structures as dynamical algebras or even infinite dimensional algebras or superalgebras. The general results are applied to space-times which appear in modern studies. One presents the infinite dimensional superalgebra of Dirac type operators on the 4-dimensional Euclidean Taub-NUT space that can be seen as a twisted loop algebra. The existence of the conformal Killing-Yano tensors is investigated for some spaces with mixed Sasakian structures.Comment: 12 pages; talk presented at Group 27 Colloquium, Yerevan, Armenia, August 200

A covariant formalism for Chern-Simons gravity

Chern--Simons type Lagrangians in $d=3$ dimensions are analyzed from the point of view of their covariance and globality. We use the transgression formula to find out a new fully covariant and global Lagrangian for Chern--Simons gravity: the price for establishing globality is hidden in a bimetric (or biconnection) structure. Such a formulation allows to calculate from a global and simpler viewpoint the energy-momentum complex and the superpotential both for Yang--Mills and gravitational examples.Comment: 12 pages,LaTeX, to appear in Journal of Physics