315 research outputs found
Superparamagnetic-like ac susceptibility behavior in a "partially disordered antiferromagnetic" compound, CaCoRhO
We report the results of dc and ac magnetization measurements as a function
of temperature (1.8 - 300 K) for the spin chain compound, CaCoRhO,
which has been recently reported to exhibit a partially disordered
antiferromagnetic (PDAF) structure in the range 30 - 90 K and spin-glass
freezing below 30 K. We observe an unexpectedly large frequency dependence of
ac susceptibility in the T range 30 - 90 K, typical of superparamagnets. In
addition, we find that there is no difference in the isothermal remanent
magnetization behavior for the two regimes below 90 K. These findings call for
more investigations to understand the magnetism of this compound.Comment: 4 pages, 3 figure
Sublattice Asymmetric Reductions of Spin Values on Stacked Triangular Lattice Antiferromagnet CsCoBr
We study the reductions of spin values of the ground state on a stacked
triangular antiferromagnet using the spin-wave approach. We find that the spin
reductions have sublattice asymmetry due to the cancellation of the molecular
field. The sublattice asymmetry qualitatively analyzes the NMR results of
CsCoBr.Comment: 5pages, 5figure
Tuning the spin Hamiltonian of NENP by external pressure: a neutron scattering study
We report an inelastic neutron scattering study of antiferromagnetic spin
dynamics in the Haldane chain compound Ni(C2H8N2)2NO2ClO4 (NENP) under external
hydrostatic pressure P = 2.5 GPa. At ambient pressure, the magnetic excitations
in NENP are dominated by a long-lived triplet mode with a gap which is split by
orthorhombic crystalline anisotropy into a lower doublet centered at
1.2meV and a singlet at 2.5meV.
With pressure we observe appreciable shifts in these levels, which move to
1.45 meV and
2.2meV. The dispersion of these modes in the crystalline c-direction
perpendicular to the chain was measured here for the first time, and can be
accounted for by an interchain exchange J'_c approximately 3e-4*J which changes
only slightly with pressure. Since the average gap value 1.64
meV remains almost unchanged with P, we conclude that in NENP the application
of external pressure does not affect the intrachain coupling J appreciably, but
does produce a significant decrease of the single-ion anisotropy constant from
D/J = 0.16(2) at ambient pressure to D/J = 0.09(7) at P = 2.5 GPa.Comment: LaTeX file nenp_p.tex, 10 pages, 1 table, 5 figures. Submitted to
Phys. Rev.
Second Low Temperature Phase Transition in Frustrated UNi_4B
Hexagonal UNi_4B is magnetically frustrated, yet it orders
antiferromagnetically at T_N = 20 K. However, one third of the U-spins remain
paramagnetic below this temperature. In order to track these spins to lower
temperature, we measured the specific heat C of \unib between 100 mK and 2 K,
and in applied fields up to 9 T. For zero field there is a sharp kink in C at
330 mK, which we interpret as an indication of a second phase
transition involving paramagnetic U. The rise in between 7 K and
330 mK and the absence of a large entropy liberated at may be due to a
combination of Kondo screening effects and frustration that strongly modifies
the low T transition.Comment: 4 pages, 4 figure
Study of Structural and Magnetic Properties of Iron-Rich Mixed Rare-Earth NdDyFe (17-y-x)CoxSiy Compounds
A series of NdDyFe(17-y-x)CoxSiy solid solutions with = 2 and 3 and = 0.5 1.0 and 1.5 were prepared by induction melting stoichiometric amounts of high-purity elements. The postannealed samples consist of two phases belonging to the space groups R3 m and P63 mmc . The lattice parameters and the unit cell volumes were calculated from the refinements of the magnetic and structural unit cells using the FULLPROF version of the Rietveld program. For a fixed content of Co, the maximum Curie temperatures (305 C to 405 C) were observed in samples with = 1 and having two phases, a disordered rhombohedral (DR) structure and a disordered hexagonal (DH) structure. An increase in the Curie temperature of 70 C per atom of cobalt is observed in NdDyFe(17-y-x)CoxSiy with y = 1 and x\u3c 3, suggesting that with a suitable choice of rare earths this DR phase may be a promising candidate for high-energy product permanent magnets. The magnetization versus temperature (M versus T) plots of the solid solutions, which consist of two phases, exhibit only a single magnetic ordering transition temperature
Large Scale Growth and Magnetic Properties of Fe and Fe₃O₄ Nanowires
Fe and Fe3O4 nanowires have been synthesized by thermal decomposition of Fe(CO)5, followed by heat treatments. The Fe wires are formed through the aggregation of nanoparticles generated by decomposition of Fe(CO)5. A core-shell structure with an iron oxide shell and Fe core is observed for the as-prepared Fe wires. Annealing in air leads to the formation of Fe2O3/Fe3O4 wires, which after heat treatment in a N2/alcohol atmosphere form Fe3O4 wires with a sharp Verwey [Nature (London) 144, 327 (1939)] transition at 125 K. The Fe3O4 wires have coercivities of 261 and 735 Oe along the wire axis at RT and 5 K, respectively. The large increase of coercivity at 5 K as compared to RT is due to the increase of anisotropy resulting from the Verwey transition
The Effect of Cu-Doping on the Magnetic and Transport Properties of La₀.₇Sr₀.₃MnO₃
The effects of Cu-doping on the structural, magnetic, and transport properties of La0.7Sr0.3Mn1xCuxO3 (0\u3c=x\u3c=0.20) have been studied using neutron diffraction, magnetization, and magnetoresistance (MR) measurements. All samples show the rhombohedral structure with the R[overline 3]c space-group from 10 K to room temperature (RT). Neutron diffraction data suggest that some of the Cu ions have a Cu3+ state in these compounds. The substitution of Mn by Cu affects the MnO bond length and Mn-O-Mn bond angle resulting from the minimization of the distortion of the MnO6 octahedron. Resistivity measurements show that a metal to insulator transition occurs for the x\u3e=0.15 samples. The x=0.15 sample shows the highest MR([approximate]80%), which might result from the co-existence of Cu3-Cu2+ and the dilution effect of Cu-doping on the double exchange interactio
Structure, magnetic and transport properties of Ti-substituted La0.7Sr0.3MnO3
Ti-substituted perovskites, La0.7Sr0.3Mn1-xTixO3, with x between 0 to 0.20,
were investigated by neutron diffraction, magnetization, electric resistivity,
and magnetoresistance (MR) measurements. All samples show a rhombohedral
structure (space group R3c) from 10 K to room temperature. At room temperature,
the cell parameters a, c and the unit cell volume increase with increasing Ti
content. However, at 10 K, the cell parameter a has a maximum value for x =
0.10, and decreases for x greater than 0.10, while the unit cell volume remains
nearly constant for x greater than 0.10. The average (Mn,Ti)-O bond length
increases up to x=0.15, and the (Mn,Ti)-O-(Mn,Ti) bond angle decreases with
increasing Ti content to its minimum value at x=0.15 at room temperature. Below
the Curie temperature T_C, the resistance exhibits metallic behavior for the x
_ 0.05 samples. A metal (semiconductor) to insulator transition is observed for
the x_ 0.10 samples. A peak in resistivity appears below T_C for all samples,
and shifts to a lower temperature as x increases. The substitution of Mn by Ti
decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth
W, and increases the electron-phonon coupling. Therefore, the TC shifts to a
lower temperature and the resistivity increases with increasing Ti content. A
field-induced shift of the resistivity maximum occurs at x less than or equal
to 0.10. The maximum MR effect is about 70% for La0.7Sr0.3Mn0.8Ti0.2O3. The
separation of TC and the resistivity maximum temperature Tmax enhances the MR
effect in these compounds due to the weak coupling between the magnetic
ordering and the resistivity as compared with La0.7Sr0.3MnO3.Comment: zip fil
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