1,213 research outputs found
Particle-stabilized oscillating diver: a self-assembled responsive capsule
We report the experimental discovery of a self-assembled capsule, with
density set by interfacial glass beads and an internal bubble, that
automatically performs regular oscillations up and down a vial in response to a
temperature gradient. Similar composites featuring interfacial particles and
multiple internal compartments could be the solution to a variety of
application challenges.Comment: 7 pages, 3 figure
Opportunities and limitations of transition voltage spectroscopy: a theoretical analysis
In molecular charge transport, transition voltage spectroscopy (TVS) holds
the promise that molecular energy levels can be explored at bias voltages lower
than required for resonant tunneling. We investigate the theoretical basis of
this novel tool, using a generic model. In particular, we study the length
dependence of the conducting frontier orbital and of the 'transition voltage'
as a function of length. We show that this dependence is influenced by the
amount of screening of the electrons in the molecule, which determines the
voltage drop to be located at the contacts or across the entire molecule. We
observe that the transition voltage depends significantly on the length, but
that the ratio between the transition voltage and the conducting frontier
orbital is approximately constant only in strongly screening (conjugated)
molecules. Uncertainty about the screening within a molecule thus limits the
predictive power of TVS. We furthermore argue that the relative length
independence of the transition voltage for non-conjugated chains is due to
strong localization of the frontier orbitals on the end groups ensuring binding
of the rods to the metallic contacts. Finally, we investigate the
characteristics of TVS in asymmetric molecular junctions. If a single level
dominates the transport properties, TVS can provide a good estimate for both
the level position and the degree of junction asymmetry. If more levels are
involved the applicability of TVS becomes limited.Comment: 8 pages, 12 figure
Interference enhanced thermoelectricity in quinoid type structures
Quantum interference (QI) effects in molecular junctions may be used to
obtain large thermoelectric responses. We study the electrical conductance G
and the thermoelec- tric response of a series of molecules featuring a quinoid
core using density functional theory (DFT), as well as a semi-empirical
interacting model Hamiltonian describing the {\pi}-system of the molecule which
we treat in the GW approximation. Molecules with a quinoid type structure are
shown to have two distinct destructive QI features close to the frontier
orbital energies. These manifest themselves as two dips in the transmission,
that remain separated, even when either electron donating or withdraw- ing side
groups are added. We find that the position of the dips in the transmission and
the frontier molecular levels can be chemically controlled by varying the
electron donating or withdrawing character of the side groups as well as the
conjugation length inside the molecule. This feature results in a very high
thermoelectric power factor S^2G and figure of merit ZT, where S is the Seebeck
coefficient, making quinoid type molecules potential candidates for efficient
thermoelectric devices.Comment: 22 pages, 11 figure
Electric-field control of interfering transport pathways in a single-molecule anthraquinone transistor
It is understood that molecular conjugation plays an important role in charge
transport through single-molecule junctions. Here, we investigate electron
transport through an anthraquinone based single-molecule three-terminal device.
With the use of an electric-field induced by a gate electrode, the molecule is
reduced resulting into a ten-fold increase in the off-resonant differential
conductance. Theoretical calculations link the change in differential
conductance to a reduction-induced change in conjugation, thereby lifting
destructive interference of transport pathways.Comment: Nano Letters (2015
Spatially Resolved Excitation of Rydberg Atoms and Surface Effects on an Atom Chip
We demonstrate spatially resolved, coherent excitation of Rydberg atoms on an
atom chip. Electromagnetically induced transparency (EIT) is used to
investigate the properties of the Rydberg atoms near the gold coated chip
surface. We measure distance dependent shifts (~10 MHz) of the Rydberg energy
levels caused by a spatially inhomogeneous electric field. The measured field
strength and distance dependence is in agreement with a simple model for the
electric field produced by a localized patch of Rb adsorbates deposited on the
chip surface during experiments. The EIT resonances remain narrow (< 4 MHz) and
the observed widths are independent of atom-surface distance down to ~20 \mum,
indicating relatively long lifetime of the Rydberg states. Our results open the
way to studies of dipolar physics, collective excitations, quantum metrology
and quantum information processing involving interacting Rydberg excited atoms
on atom chips
Electrical control of spin dynamics in finite one-dimensional systems
We investigate the possibility of the electrical control of spin transfer in
monoatomic chains incorporating spin-impurities. Our theoretical framework is
the mixed quantum-classical (Ehrenfest) description of the spin dynamics, in
the spirit of the s-d-model, where the itinerant electrons are described by a
tight-binding model while localized spins are treated classically. Our main
focus is on the dynamical exchange interaction between two well-separated
spins. This can be quantified by the transfer of excitations in the form of
transverse spin oscillations. We systematically study the effect of an
electrostatic gate bias V_g on the interconnecting channel and we map out the
long-range dynamical spin transfer as a function of V_g. We identify regions of
V_g giving rise to significant amplification of the spin transmission at low
frequencies and relate this to the electronic structure of the channel.Comment: 9 pages, 11 figure
Conditional phase shift from a quantum dot in a pillar microcavity
Large conditional phase shifts from coupled atom-cavity systems are a key
requirement for building a spin photon interface. This in turn would allow the
realisation of hybrid quantum information schemes using spin and photonic
qubits. Here we perform high resolution reflection spectroscopy of a quantum
dot resonantly coupled to a pillar microcavity. We show both the change in
reflectivity as the quantum dot is tuned through the cavity resonance, and
measure the conditional phase shift induced by the quantum dot using an ultra
stable interferometer. These techniques could be extended to the study of
charged quantum dots, where it would be possible to realise a spin photon
interface
Two phase transitions in the fully frustrated model
The fully frustrated model on a square lattice is studied by means of
Monte Carlo simulations. A Kosterlitz-Thouless transition is found at , followed by an ordinary Ising transition at a slightly
higher temperature, . The non-Ising exponents reported by
others, are explained as a failure of finite size scaling due to the screening
length associated with the nearby Kosterlitz-Thouless transition.Comment: REVTEX file, 8 pages, 5 figures in uuencoded postscrip
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