283 research outputs found
Dilution effect in correlated electron system with orbital degeneracy
Theory of dilution effect in orbital ordered system is presented. The
orbital model without spin degree of freedom and the spin-orbital coupled model
in a three-dimensional simple-cubic lattice are analyzed by the Monte-Carlo
simulation and the cluster expansion method. In the orbital model without
spin degree of freedom, reduction of the orbital ordering temperature due to
dilution is steeper than that in the dilute magnet. This is attributed to a
modification of the orbital wave-function around vacant sites. In the
spin-orbital coupled model, it is found that magnetic structure is changed from
the A-type antiferromagnetic order into the ferromagnetic one. Orbital
dependent exchange interaction and a sign change of this interaction around
vacant sites bring about this novel phenomena. Present results explain the
recent experiments in transition-metal compounds with orbital dilution.Comment: 12 pages, 16 figure
Photoinduced magnetic bound state in itinerant correlated electron system with spin-state degree of freedom
Photo-excited state in correlated electron system with spin-state degree of
freedom is studied. We start from the two-orbital extended Hubbard model where
energy difference between the two orbitals is introduced. Photo-excited
metastable state is examined based on the effective model Hamiltonian derived
by the two-orbital Hubbard model. Spin-state change is induced by
photo-irradiation in the low-spin band insulator near the phase boundary.
High-spin state is stabilized by creating a ferromagnetic bound state with
photo-doped hole carriers. An optical absorption occurs between the bonding and
antibonding orbitals inside of the bound state. Time-evolution for
photo-excited states is simulated in the time-dependent mean-field scheme.
Pair-annihilations of the photo-doped electron and hole generate the high-spin
state in a low-spin band insulator. We propose that this process is directly
observed by the time-resolved photoemission experiments.Comment: 15 pages, 16 figure
Spin-state transition and phase separation in multi-orbital Hubbard model
We study spin-state transition and phase separation involving this transition
based on the milti-orbital Hubbard model. Multiple spin states are realized by
changing the energy separation between the two orbitals and the on-site Hund
coupling. By utilizing the variational Monte-Carlo simulation, we analyze the
electronic and magnetic structures in hole doped and undoped states. Electronic
phase separation occurs between the low-spin band insulating state and the
high-spin ferromagnetic metallic one. Difference of the band widths in the two
orbitals is of prime importance for the spin-state transition and the phase
separation.Comment: 5 pages, 5 figure
Dilution Effects in Two-dimensional Quantum Orbital System
We study dilution effects in a Mott insulating state with quantum orbital
degree of freedom, termed the two-dimensional orbital compass model. This is a
quantum and two-dimensional version of the orbital model where the interactions
along different bond directions cause frustration between different orbital
configurations. A long-range correlation of a kind of orbital at each row or
column, termed the directional order, is studied by means of the quantum
Monte-Carlo method. It is shown that decrease of the ordering temperature due
to dilution is much stronger than that in spin models. Quantum effect enhances
the effective dimensionality in the system and makes the directional order
robust against dilution. We discuss an essential mechanism of the dilute
orbital systems.Comment: 5pages, 4 figure
Numerical study of t2g orbital system with ferromagnetic polarization
Finite temperature orbital state in a ferromagnetic Mott insulator with
triply-degenerate orbital is investigated numerically. We employ the
quantum Monte Carlo simulation with the loop algorithm. Indications for
conventional staggered-type orbital order are not remarkable down to the lowest
temperature to which the present simulation can get access. Physical parameters
monitoring the off-diagonal orbital order, which is characterized by a linear
combination of the orbital-wave functions with equal
weights, are not conspicuous. It is found that a orbital gap-like behavior
appears in the uniform orbital susceptibility. This is supported by a threshold
behavior in the staggered correlation function in a calculation with the
additional Ising-type interaction. Some rigorous remarks for the long-range
orbital order are also presented.Comment: 5 pages, 3 figure
Tcnq-based Porous Coordination Polymers Synthesis and Sorption Properties Study in Magnetic Field
Porous coordination polymers (PCPs) were synthesized with used TCNQ anion that acts as cross linker connecting and bipyridine to form a 3D framework. In these study, we use zinc and manganese metal ion as centre of complex coordination. Green crystal of Zn(TCNQ-TCNQ)bpy.1.5 benzene and Mn(TCNQ-TCNQ)bpy.1.5 benzene was successfully synthesized in no under magnetic field (0T) and under magnetic field 6T. XRD patterns of Zn(TCNQ-TCNQ)bpy.1.5 benzene 0T and 6T shown not significant different pattern that indicate no different crytal formed. XRD patterns of Mn(TCNQ-TCNQ)bpy.1.5 benzene also shown not significant different but we found five different intensity ratio peaks that possibility it was a little bit changing of crystal structure. To investigate the pores properties, adsorption isotherm was performe for oxygen gas in 77 K and the guest of benzene were removed at 413 K for 3 hours under low pressure. Zn(TCNQ-TCNQ)bpy}1.5benzene 0T and 6T oxygen adsorption isotherms shows the unique sorption isotherms by gate pressure profile. On other hand, Mn(TCNQ-TCNQ)bpy}1.5 benzene 0T and 6T shows type 1 adsorption isotherms for micropores materials. Adsorption isotherm was also determined in magnetic field 6T for all crystal, and shows shift of gate pressure for Zn compounds and enhance the amount of oxygen adsorbed for all kind of compounds
Asymptotic Learning Curve and Renormalizable Condition in Statistical Learning Theory
Bayes statistics and statistical physics have the common mathematical
structure, where the log likelihood function corresponds to the random
Hamiltonian. Recently, it was discovered that the asymptotic learning curves in
Bayes estimation are subject to a universal law, even if the log likelihood
function can not be approximated by any quadratic form. However, it is left
unknown what mathematical property ensures such a universal law. In this paper,
we define a renormalizable condition of the statistical estimation problem, and
show that, under such a condition, the asymptotic learning curves are ensured
to be subject to the universal law, even if the true distribution is
unrealizable and singular for a statistical model. Also we study a
nonrenormalizable case, in which the learning curves have the different
asymptotic behaviors from the universal law
Theory of Orbital Ordering, Fluctuation and Resonant X-ray Scattering in Manganites
A theory of resonant x-ray scattering in perovskite manganites is developed
by applying the group theory to the correlation functions of the pseudospin
operators for the orbital degree of freedom. It is shown that static and
dynamical informations of the orbital state are directly obtained from the
elastic, diffuse and inelastic scatterings due to the tensor character of the
scattering factor. We propose that the interaction and its anisotropy between
orbitals are directly identified by the intensity contour of the diffuse
scattering in the momentum space.Comment: 4 pages, 1 figur
Temperature dependence of the resistivity in the double-exchange model
The resistivity around the ferromagnetic transition temperature in the double
exchange model is studied by the Schwinger boson approach. The spatial spin
correlation responsible for scattering of conduction electrons are taken into
account by adopting the memory function formalism. Although the correlation
shows a peak lower than the transition temperature, the resistivity in the
ferromagnetic state monotonically increases with increasing temperature due to
a variation of the electronic state of the conduction electron. In the
paramagnetic state, the resistivity is dominated by the short range correlation
of scattering and is almost independent of the temperature. It is attributed to
a cancellation between the nearest-neighbor spin correlation, the fermion
bandwidth, and the fermion kinetic energy. This result implies the importance
of the temperature dependence of the electronic states of the conduction
electron as well as the localized spin states in both ferromagnetic and
paramagnetic phases.Comment: RevTex, 4 pages, 4 PostScript figures, To appear in Phys. Rev.
Polarization Dependence of Anomalous X-ray Scattering in Orbital Ordered Manganites
In order to determine types of the orbital ordering in manganites, we study
theoretically the polarization dependence of the anomalous X-ray scattering
which is caused by the anisotropy of the scattering factor. The general
formulae of the scattering intensity in the experimental optical system is
derived and the atomic scattering factor is calculated in the microscopic
electronic model. By using the results, the X-ray scattering intensity in
several types of the orbital ordering is numerically calculated as a function
of azimuthal and analyzer angles.Comment: 9 pages, 7 figure
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