271 research outputs found
Phonon renormalisation in doped bilayer graphene
We report phonon renormalisation in bilayer graphene as a function of doping.
The Raman G peak stiffens and sharpens for both electron and hole doping, as a
result of the non-adiabatic Kohn anomaly at the point. The bilayer has
two conduction and valence subbands, with splitting dependent on the interlayer
coupling. This results in a change of slope in the variation of G peak position
with doping, which allows a direct measurement of the interlayer coupling
strength.Comment: 5 figure
Raman Fingerprint of Charged Impurities in Graphene
We report strong variations in the Raman spectra for different single-layer
graphene samples obtained by micromechanical cleavage, which reveals the
presence of excess charges, even in the absence of intentional doping. Doping
concentrations up to ~10^13 cm-2 are estimated from the G peak shift and width,
and the variation of both position and relative intensity of the second order
2D peak. Asymmetric G peaks indicate charge inhomogeneity on the scale of less
than 1 micron.Comment: 3 pages, 5 figure
Vibration Induced Non-adiabatic Geometric Phase and Energy Uncertainty of Fermions in Graphene
We investigate geometric phase of fermion states under relative vibrations of
two sublattices in graphene by solving time-dependent Sch\"{o}dinger equation
using Floquet scheme. In a period of vibration the fermions acquire different
geometric phases depending on their momenta. There are two regions in the
momentum space: the adiabatic region where the geometric phase can be
approximated by the Berry phase and the chaotic region where the geometric
phase drastically fluctuates in changing parameters. The energy of fermions due
to vibrations shows spikes in the chaotic region. The results suggest a
possible dephasing mechanism which may cause classical-like transport
properties in graphene.Comment: 9 pages, 5 figure
High-performance lead-acid batteries enabled by Pb and PbO2 nanostructured electrodes: Effect of operating temperature
Lead-acid batteries are now widely used for energy storage, as result of an established and reliable technology. In the last decade, several studies have been carried out to improve the performance of this type of batteries, with the main objective to replace the conventional plates with innovative electrodes with improved stability, increased capacity and a larger active surface. Such studies ultimately aim to improve the kinetics of electrochemical conversion reactions at the electrode-solution interface and to guarantee a good electrical continuity during the repeated charge/discharge cycles. To achieve these objectives, our contribution focuses on the employment of nanostructured electrodes. In particular, we have obtained nanostructured electrodes in Pb and PbO2 through electrosynthesis in a template consisting of a nanoporous polycarbonate membrane. These electrodes are characterized by a wider active surface area, which allows for a better use of the active material, and for a consequent increased specific energy compared to traditional batteries. In this research, the performance of lead-acid batteries with nanostructured electrodes was studied at 10 C at temperatures of 25, −20 and 40 °C in order to evaluate the efficiency and the effect of temperature on electrode morphology. The batteries were assembled using both nanostructured electrodes and an AGM-type separator used in commercial batteries
Rayleigh Imaging of Graphene and Graphene Layers
We investigate graphene and graphene layers on different substrates by
monochromatic and white-light confocal Rayleigh scattering microscopy. The
image contrast depends sensitively on the dielectric properties of the sample
as well as the substrate geometry and can be described quantitatively using the
complex refractive index of bulk graphite. For few layers (<6) the
monochromatic contrast increases linearly with thickness: the samples behave as
a superposition of single sheets which act as independent two dimensional
electron gases. Thus, Rayleigh imaging is a general, simple and quick tool to
identify graphene layers, that is readily combined with Raman scattering, which
provides structural identification.Comment: 8 pages, 9 figure
Effect of Holstein phonons on the optical conductivity of gapped graphene
We study the optical conductivity of a doped graphene when a sublattice
symmetry breaking is occurred in the presence of the electron-phonon
interaction. Our study is based on the Kubo formula that is established upon
the retarded self-energy. We report new features of both the real and imaginary
parts of the quasiparticle self-energy in the presence of a gap opening. We
find an analytical expression for the renormalized Fermi velocity of massive
Dirac Fermions over broad ranges of electron densities, gap values and the
electron-phonon coupling constants. Finally we conclude that the inclusion of
the renormalized Fermi energy and the band gap effects are indeed crucial to
get reasonable feature for the optical conductivity.Comment: 12 pages, 4 figures. To appear in Eur. Phys. J.
Raman spectra of epitaxial graphene on SiC and of epitaxial graphene transferred to SiO2
Raman spectra were measured for mono-, bi- and trilayer graphene grown on SiC
by solid state graphitization, whereby the number of layers was pre-assigned by
angle-resolved ultraviolet photoemission spectroscopy. It was found that the
only unambiguous fingerprint in Raman spectroscopy to identify the number of
layers for graphene on SiC(0001) is the linewidth of the 2D (or D*) peak. The
Raman spectra of epitaxial graphene show significant differences as compared to
micromechanically cleaved graphene obtained from highly oriented pyrolytic
graphite crystals. The G peak is found to be blue-shifted. The 2D peak does not
exhibit any obvious shoulder structures but it is much broader and almost
resembles a single-peak even for multilayers. Flakes of epitaxial graphene were
transferred from SiC onto SiO2 for further Raman studies. A comparison of the
Raman data obtained for graphene on SiC with data for epitaxial graphene
transferred to SiO2 reveals that the G peak blue-shift is clearly due to the
SiC substrate. The broadened 2D peak however stems from the graphene structure
itself and not from the substrate.Comment: 27 pages, 8 figure
Anomalous Lattice Vibrations of Single and Few-Layer MoS2
Molybdenum disulfide (MoS2) of single and few-layer thickness was exfoliated
on SiO2/Si substrate and characterized by Raman spectroscopy. The number of
S-Mo-S layers of the samples was independently determined by contact-mode
atomic-force microscopy. Two Raman modes, E12g and A1g, exhibited sensitive
thickness dependence, with the frequency of the former decreasing and that of
the latter increasing with thickness. The results provide a convenient and
reliable means for determining layer thickness with atomic-level precision. The
opposite direction of the frequency shifts, which cannot be explained solely by
van der Waals interlayer coupling, is attributed to Coulombic interactions and
possible stacking-induced changes of the intralayer bonding. This work
exemplifies the evolution of structural parameters in layered materials in
changing from the 3-dimensional to the 2-dimensional regime.Comment: 14 pages, 4 figure
Electrochemically Top Gated Graphene: Monitoring Dopants by Raman Scattering
We demonstrate electrochemical top gating of graphene by using a solid
polymer electrolyte. This allows to reach much higher electron and hole doping
than standard back gating. In-situ Raman measurements monitor the doping. The G
peak stiffens and sharpens for both electron and hole doping, while the 2D peak
shows a different response to holes and electrons. Its position increases for
hole doping, while it softens for high electron doping. The variation of G peak
position is a signature of the non-adiabatic Kohn anomaly at . On the
other hand, for visible excitation, the variation of the 2D peak position is
ruled by charge transfer. The intensity ratio of G and 2D peaks shows a strong
dependence on doping, making it a sensitive parameter to monitor charges.Comment: 7 pages, 8 figure
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