Influence of temperature on the chemical compositions and microstructural changes of ash formed from palm kernel shell

This study investigated the characteristics of raw palm kernel shell (raw PKS) and the influence of temperature variation on palm kernel shell ash (PKSA). The PKSA was obtained under different temperature regimes of 900, 1000, and 1100�C. The characterization of the samples was carried out using X-ray Fluorescence (XRF), Fourier Transform Infrared (FTIR), X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) with attached Energy Dispersive X-ray (EDX) facilities. The results showed that moisture and ash contents and the density of raw PKS were 6.56%, 8.86%, and 745 kg/m3 , respectively. The colour of the pulverized PKS was dark brown, as observed by visual examination based on standard colour gradation. This colour transformed into various shades of brown when PKS was subjected to different temperature regimes to form PKSA. The XRF analysis showed that silica is the main constituent of the raw PKS and PKSA samples. Silica content in the PKSA increased with the rise in the heating temperature. The FTIR and EDX spectra confirmed the predominance of silicon compounds with functional groups associated with silanol and siloxane. Also, XRD analysis revealed that the silica contents in the samples are quartz, while SEM examinations indicated that temperature increases during processing influenced the microstructure through the reduction of pore concentration in the samples. The silica obtained from the PKSA would find applications in metal matrix composites as partial reinforcing material

Solar-eclipse-induced perturbations at mid-latitude during the 21 August 2017 event

A study of the response of some ionospheric parameters and their relationship in describing the behaviour of ionospheric mechanisms during the solar eclipse of 21 August 2017 is presented. Mid-latitude stations located along the eclipse path and with data available from the Global Ionospheric radio Observatory (GIRO) database were selected. The percentage of obscuration at these stations ranges between 63&thinsp;% and 100&thinsp;%. A decrease in electron density during the eclipse is attributed to a reduction in solar radiation and natural gas heating. The maximum magnitude of the eclipse consistently coincided with a hmF2 increase and with a lagged maximum decrease in NmF2 at the stations investigated. The results revealed that the horizontal neutral wind flow is as a consequence of the changes in the thermospheric and diffusion processes. The unusual increase and decrease in the shape and thickness parameters during the eclipse period relative to the control days points to the perturbation caused by the solar eclipse. The relationships of the bottomside ionosphere and the F2 layer parameters with respect to the scale height are shown in the present work as viable parameters for probing the topside ionosphere during the eclipse. Furthermore, this study shows that in addition to traditional ways of analysing the thermospheric composition and neutral wind flow, proper relation of standardized NmF2 and hmF2 can be conveniently used to describe the mechanisms.</p

Relationship between F2 layer critical frequency and solar activity indices during different solar epochs

73-81This paper aims at investigating the relationship between F2 layer critical frequency (foF2) and solar activity indices viz. smoothed twelve-month running mean of the sunspot number (R12) and the solar radio flux of 10.7cm wavelength (F10.7) during three different solar epochs. Data from Ouagadougou, an African low latitude station (latitude 12.4°N, longitude 1.5°W, dip 5.7), and the National Geophysical Data Centre were used for this study. Distinct characteristics were observed during different solar epochs and during each season. Sunspot number and solar radio flux agreed better during the year of moderate solar activity than during the year of low solar activity. The average correlation coefficients between foF2 and F10.7 obtained for high, moderate and low solar activity were 0.17, 0.67, and 0.44, respectively; while correlation coefficients between foF2 and R12 obtained were 0.05, 0.66, and 0.49, respectively. Irrespective of solar epochs and the trend of the indices, a trough in foF2 value was observed towards the end of June solstice. Relationship between foF2 and the solar activity indices agreed reasonably for the three solar epochs during December solstice. A strong solar activity dependence of foF2 around equinoxes than solstices was also observed. Factors that could cause the F2 layer variation were discussed

Pattern of Ionization Gradient, Solar Quiet Magnetic Element, and F2-Layer Bottomside Thickness Parameter at African Equatorial Location

The study of ionization gradient (dN/dh) profile in the description of ionospheric dynamics is not common. This is the first attempt at finding the dependence of ionization gradient, solar quiet component (Sq (BH)), and bottomside thickness parameter (B0) in the African equatorial sector. Digisonde and Magnetic Data Acquisition System data collocated at an equatorial location were employed. Result was presented for sunrise (00 LT), midday (12 LT), sunset (18 LT), and midnight (00 LT) hours. The ionization gradient peak height remains unchanged at midday across all months. A percentage correlation of 93% existed in the inverse and direct linear relationship of dN/dh‐B0 at sunrise, and of Sq (BH)‐B0 at midday, respectively. Significant relationship between dN/dh and Sq (BH) was at sunset; for other hours, the relationship is poor. The multiple linear relationship of dN/dh‐Sq (BH)‐B0 parameters revealed that the dependence of dN/dh on Sq (BH) and B0 is highest at midday, and a model equation was presented. The dependence of dN/dh on the solar activity index (F10.7) holds at all the selected hours, and distinct only at midday and midnight for the Sq (BH)‐F10.7 and B0‐F10.7 patterns. Both the peak ionization gradient and the height it occurs maximizes/minimizes at 18 LT/06 LT. The importance of the F region dynamo at heights above 150 km was reported

Experimental Study on the Properties of Fired Sand–Clay Ceramic Products for Masonry Applications

This study reports the effect of fine sand addition on the properties of fired clay bricks. Fine sand was sieved to −75 μm and incorporated at varied weight proportions (5, 10, 15, 20, 25, 30, 35, and 40 wt.%) to clay in the preparation of fired bricks. The samples produced were oven dried at 110°C for 12 h, and fired at a temperature of 1,200°C in an electric furnace. The samples were examined for physical, thermal, and mechanical properties. Result of the tests showed a reduction in porosity, water absorption, weight loss, and firing shrinkage with increasing sand addition, although the bulk density increased as the percentage weight content of sand increased. Thermal properties such as thermal conductivity, thermal diffusivity, and thermal emissivity increased with fine sand addition while reduction in coefficient of thermal expansion and specific heat capacity was observed. Also, the thermal shock resistance improved with increase in fine sand addition up to 25 wt.%, before further decline was observed. The hardness and impact value were enhanced with increasing additives. It is noted that samples immersed in rainwater were found to experience depreciation in hardness, resistance to impact, compressive and flexural strengths as the number of days of immersion increased. It was concluded that bricks produced are good for building in temperate region in which much flooding is not experienced