The preparation of BP single crystals by high pressure flux method

Single crystals of BP, a III-V compound semiconductor, were obtained by the high pressure flux method. Cu3P and Ni12P5 powders were used as the flux, and mixed with BP powder. Two kinds of mixtures were prepared: (1) 1.8g (BP) + 35 G (Cu3P) and (2) 1.7 g (BP) + 25 g (Ni12P5). They were compressed into pellets, heated at 1300 C for 24 h in an induction furnace under a pressure of 1 MPa using Ar-P2 gas, and slowly cooled to room temperature. In case (1), BP single crystals grew along the (III) plane, and in case (2) they grew as an aggregate of crystallites. The cathodoluminescence spectra of the synthetic BP crystals showed peaks near 680 nm (1.82 eV) for case (1), and 500 nm (2.47 eV) for case (2). By using the high pressure flux method conventional sized crystals were obtained in a relatively short time

Nonlinear optical response of wave packets on quantized potential energy surfaces

We calculated the dynamics of nuclear wave packets in coupled electron-vibration systems and their nonlinear optical responses. We found that the quantized nature of the vibrational modes is observed in pump-probe spectra particularly in weakly interacting electron-vibration systems such as cyanine dye molecules. Calculated results based on a harmonic potential model and molecular orbital calculations are compared with experimental results, and we also found that the materials parameters regarding with the geometrical structure of potential energy surfaces are directly determined by accurate measurement of time-resolved spectra.Comment: 19 pages, 6 figures, 1 tabl

Electronic susceptibilities in systems with anisotropic Fermi surfaces

The low temperature dependence of the spin and charge susceptibilities of an anisotropic electron system in two dimensions is analyzed. It is shown that the presence of inflection points at the Fermi surface leads, generically, to a $T \log T$ dependence, and a more singular behavior, $\chi \sim T ^{3/4} \log T$, is also possible. Applications to quasi two-dimensional materials are discussed.Comment: 8 pages, 5 figures, revtex 4 styl

A Spectropolarimetric Test of the Structure of the Intrinsic Absorbers in the Quasar HS1603+3820

We report the results of a spectropolarimetric observation of the C IV mini-BAL in the quasar HS1603+3820. The observations were carried out with the FOCAS instrument on the Subaru telescope and yielded an extremely high polarization sensitivity of 0.1%, at a resolving power of 1500. HS1603+3820 has been the target of a high-resolution spectroscopic monitoring campaign for more than four years, aimed at studying its highly variable C IV mini-BAL profile. Using the monitoring observations, in an earlier paper we were able to narrow down the causes of the variability to the following two scenarios: (1) scattering material of variable optical depth redirecting photons around the absorber, and (2) a variable, highly-ionized screen between the continuum source and the absorber which modulates the UV continuum incident on the absorber. The observations presented here provide a crucial test of the scattering scenario and lead us to disfavor it because (a) the polarization level is very small (p~0.6%) throughout the spectrum, and (b) the polarization level does not increase across the mini-BAL trough. Thus, the variable screen scenario emerges as our favored explanation of the C IV mini-BAL variability. Our conclusion is bolstered by recent X-ray observations of nearby mini-BAL quasars, which show a rapidly variable soft X-ray continuum that appears to be the result of transmission through an ionized absorber of variable ionization parameter and optical depth.Comment: To appear in the Astrophysical Journal, vol. 719, August 201

The Wide-Angle Outflow of the Lensed z = 1.51 AGN HS 0810+2554

We present results from X-ray observations of the gravitationally lensed z = 1.51 AGN HS 0810+2554 performed with the Chandra X-ray Observatory and XMM-Newton. Blueshifted absorption lines are detected in both observations at rest-frame energies ranging between ~1-12 keV at > 99% confidence. The inferred velocities of the outflowing components range between ~0.1c and ~0.4c. A strong emission line at ~6.8 keV accompanied by a significant absorption line at ~7.8 keV is also detected in the Chandra observation. The presence of these lines is a characteristic feature of a P-Cygni profile supporting the presence of an expanding outflowing highly ionized iron absorber in this quasar. Modeling of the P-Cygni profile constrains the covering factor of the wind to be > 0.6, assuming disk shielding. A disk-reflection component is detected in the XMM-Newton observation accompanied by blueshifted absorption lines. The XMM-Newton observation constrains the inclination angle to be < 45 degrees at 90% confidence, assuming the hard excess is due to blurred reflection from the accretion disk. The detection of an ultrafast and wide-angle wind in an AGN with intrinsic narrow absorption lines (NALs) would suggest that quasar winds may couple efficiently with the intergalactic medium and provide significant feedback if ubiquitous in all NAL and BAL quasars. We estimate the mass-outflow rate of the absorbers to lie in the range of 1.5 and 3.4 Msolar/yr for the two observations. We find the fraction of kinetic to electromagnetic luminosity released by HS 0810+2554 is large (epsilon = 9 (-6,+8)) suggesting that magnetic driving is likely a significant contributor to the acceleration of this outflow.Comment: 27 pages, 13 figures, Accepted for publication in Ap

The Mechanism of Formation of Iron Oxide and Oxyhydroxides in Aqueous Solutions at Room Temperature(Chemistry)

For a better understanding of the atmospheric rusting of iron and steels, the present work is aimed to explore the mechanism of formation of green rusts, Fe_3O_4, α-FeOOH, β-FeOOH, γ-FeOOH, δ-FeOOH and amorphous ferric oxyhydroxide in aqueous solution at room temperature. The formation processes on which end products are determined are strongly affected by the oxidation rate, pH and the structure and composition of initial and intermediate species of iron. The systematic diagram of formation processes of iron oxide and oxyhydroxides has been presented, in which both dissolved and solid species of iron are included

Leading Temperature Corrections to Fermi Liquid Theory in Two Dimensions

We calculate the basic parameters of the Fermi Liquid: the scattering vertex, the Landau interaction function, the effective mass, and physical susceptibilities for a model of two-dimensional (2D) fermions with a short ranged interaction at non-zero temperature. The leading temperature dependences of the spin components of the scattering vertex, the Landau function, and the spin susceptibility are found to be linear. T-linear terms in the effective mass and in the ``charge-sector''- quantities are found to cancel to second order in the interaction, but the cancellation is argued not to be generic. The connection with previous studies of the 2D Fermi-Liquid parameters is discussed.Comment: 4 pages, 1 figur

Neutron scattering and molecular correlations in a supercooled liquid

We show that the intermediate scattering function $S_n(q,t)$ for neutron scattering (ns) can be expanded naturely with respect to a set of molecular correlation functions that give a complete description of the translational and orientational two-point correlations in the liquid. The general properties of this expansion are discussed with special focus on the $q$-dependence and hints for a (partial) determination of the molecular correlation functions from neutron scattering results are given. The resulting representation of the static structure factor $S_n(q)$ is studied in detail for a model system using data from a molecular dynamics simulation of a supercooled liquid of rigid diatomic molecules. The comparison between the exact result for $S_n(q)$ and different approximations that result from a truncation of the series representation demonstrates its good convergence for the given model system. On the other hand it shows explicitly that the coupling between translational (TDOF) and orientational degrees of freedom (ODOF) of each molecule and rotational motion of different molecules can not be neglected in the supercooled regime.Further we report the existence of a prepeak in the ns-static structure factor of the examined fragile glassformer, demonstrating that prepeaks can occur even in the most simple molecular liquids. Besides examining the dependence of the prepeak on the scattering length and the temperature we use the expansion of $S_n(q)$ into molecular correlation functions to point out intermediate range orientational order as its principle origin.Comment: 13 pages, 7 figure

Formation of Fe(II)_1-Fe(III)_3 Green Complex on Oxidation of Ferrous Ion in Perchloric Acid Solution

The interaction between Fe(II)-Fe(III) in strong acidic solution has been investigated by means of electronic and Raman spectra, magnetic susceptibility measurement and chemical analysis of the solution. It was found that the green intermediate complex having an absorption band at 337 nm was formed on oxidation of Fe(H_2O)^_6 in perchloric acid solution. The Fe(II)/Fe(III) ratio in the green complex was a third. The configuration of the complex consisting of Fe(II)-O-Fe(III) oxo-bridges was suggested