592 research outputs found

    Low-energy photon-photon collisions to two loops revisited

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    In view of ongoing experimental activities to determine the pion polarizabilities, we have started to recalculate the available two-loop expressions in the framework of chiral perturbation theory, because they have never been checked before. We make use of the chiral Lagrangian at order p^6 now available, and of improved techniques to evaluate the two-loop diagrams. Here, we present the result for the neutral pions. The cross section for the reaction gamma+gamma->pi0+pi0 agrees with the earlier calculation within a fraction of a percent. We present analytic results for the dipole and quadrupole polarizabilities, and compare the latter with a recent evaluation from data on gamma+gamma->pi0+pi0.Comment: 28 pages, 7-eps figures, 1 tabl

    Discriminability of tryptophan containing dipeptides using quantum control

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    We show that the coherent manipulation of molecular wavepackets in the excited states of trp-containing dipeptides allows efficient discrimination among them. Optimal dynamic discrimination fails, however, for some dipeptide couples. When considering the limited spectral resources at play (3nm bandwidth at 266nm), we discuss the concept of discriminability, which appears uncorrelated to both static spectra and relaxation lifetime

    Molecular structure of nitrogen trichloride as determined by electron diffraction

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    Nitrogen trichloride was found to have a bond length of rg = 1.759 +/- 0.002 A and a Cl-N-Cl angle of 107.1 +/- 0.5[deg]. The bond angle is larger than that found in NF3, consistent with the (recently revised) trends displayed by the trihalides of phosphorus and arsenic, but much lower than the 120[deg] angle reported for the isoelectronic molecule N(SiH3)3. Moreover, a comparison between selected compounds reveals that the N-Cl bond length is appreciably greater, relatively, than the N-Si bond length. Accordingly, the bond angles and bond lengths suggest a greater reluctance of the nitrogen lone pairs to delocalize onto Cl than onto SiH3 groups. Mean amplitudes of vibration of NCl3 were derived both from the diffraction data and from recently published infrared and Raman frequencies. The values agree within the estimated uncertainties.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/33551/1/0000052.pd

    Quantum Holographic Encoding in a Two-dimensional Electron Gas

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    The advent of bottom-up atomic manipulation heralded a new horizon for attainable information density, as it allowed a bit of information to be represented by a single atom. The discrete spacing between atoms in condensed matter has thus set a rigid limit on the maximum possible information density. While modern technologies are still far from this scale, all theoretical downscaling of devices terminates at this spatial limit. Here, however, we break this barrier with electronic quantum encoding scaled to subatomic densities. We use atomic manipulation to first construct open nanostructures--"molecular holograms"--which in turn concentrate information into a medium free of lattice constraints: the quantum states of a two-dimensional degenerate Fermi gas of electrons. The information embedded in the holograms is transcoded at even smaller length scales into an atomically uniform area of a copper surface, where it is densely projected into both two spatial degrees of freedom and a third holographic dimension mapped to energy. In analogy to optical volume holography, this requires precise amplitude and phase engineering of electron wavefunctions to assemble pages of information volumetrically. This data is read out by mapping the energy-resolved electron density of states with a scanning tunnelling microscope. As the projection and readout are both extremely near-field, and because we use native quantum states rather than an external beam, we are not limited by lensing or collimation and can create electronically projected objects with features as small as ~0.3 nm. These techniques reach unprecedented densities exceeding 20 bits/nm2 and place tens of bits into a single fermionic state.Comment: Published online 25 January 2009 in Nature Nanotechnology; 12 page manuscript (including 4 figures) + 2 page supplement (including 1 figure); supplementary movie available at http://mota.stanford.ed

    Modelling and simulating change in reforesting mountain landscapes using a social-ecological framework

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    Natural reforestation of European mountain landscapes raises major environmental and societal issues. With local stakeholders in the Pyrenees National Park area (France), we studied agricultural landscape colonisation by ash (Fraxinus excelsior) to enlighten its impacts on biodiversity and other landscape functions of importance for the valley socio-economics. The study comprised an integrated assessment of land-use and land-cover change (LUCC) since the 1950s, and a scenario analysis of alternative future policy. We combined knowledge and methods from landscape ecology, land change and agricultural sciences, and a set of coordinated field studies to capture interactions and feedback in the local landscape/land-use system. Our results elicited the hierarchically-nested relationships between social and ecological processes. Agricultural change played a preeminent role in the spatial and temporal patterns of LUCC. Landscape colonisation by ash at the parcel level of organisation was merely controlled by grassland management, and in fact depended on the farmer's land management at the whole-farm level. LUCC patterns at the landscape level depended to a great extent on interactions between farm household behaviours and the spatial arrangement of landholdings within the landscape mosaic. Our results stressed the need to represent the local SES function at a fine scale to adequately capture scenarios of change in landscape functions. These findings orientated our modelling choices in the building an agent-based model for LUCC simulation (SMASH - Spatialized Multi-Agent System of landscape colonization by ASH). We discuss our method and results with reference to topical issues in interdisciplinary research into the sustainability of multifunctional landscapes

    Consensus guideline for the diagnosis and treatment of tetrahydrobiopterin (BH4) deficiencies

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    Background: Tetrahydrobiopterin (BH4) deficiencies comprise a group of six rare neurometabolic disorders characterized by insufficient synthesis of the monoamine neurotransmitters dopamine and serotonin due to a disturbance of BH4 biosynthesis or recycling. Hyperphenylalaninemia (HPA) is the first diagnostic hallmark for most BH4 deficiencies, apart from autosomal dominant guanosine triphosphate cyclohydrolase I deficiency and sepiapterin reductase deficiency. Early supplementation of neurotransmitter precursors and where appropriate, treatment of HPA results in significant improvement of motor and cognitive function. Management approaches differ across the world and therefore these guidelines have been developed aiming to harmonize and optimize patient care. Representatives of the International Working Group on Neurotransmitter related Disorders (iNTD) developed the guidelines according to the SIGN (Scottish Intercollegiate Guidelines Network) methodology by evaluating all available evidence for the diagnosis and treatment of BH4 deficiencies. Conclusion: Although the total body of evidence in the literature was mainly rated as low or very low, these consensus guidelines will help to harmonize clinical practice and to standardize and improve care for BH4 deficient patients

    Effect of a school-based active play intervention on sedentary time and physical activity in preschool children

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    Early childhood is a critical time for promoting physical activity. Few studies have investigated the effect of interventions in this population. The aim of this study was to investigate the effect of a school-based active play intervention on preschool children’s sedentary time and physical activity. Preschool children were recruited from randomly selected preschools. Schools were randomly assigned to an intervention or comparison group. One teacher per intervention school received training from active play professionals in the delivery of a 6-week active play programme. Comparison schools continued their usual practice. Children wore a uni-axial accelerometer for 7 days at baseline, immediately after and at 6-month post-intervention. No significant intervention effects were observed for sedentary time or physical activity. However, sex and hours spent at school were significant predictors of physical activity. Children who spent fewer hours (half-day children) at school were significantly more active than their full-day counterparts. Physical activity during the intervention classes was high even though neither daily physical activity nor sedentary time changed. Notably children who spent more time at preschool were less active suggesting that preschool was not as conducive to physical activity engagement as other environments

    One-Dimensional Energy Dispersion of Single-Walled Carbon Nanotubes by Resonant Electron Scattering

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    We characterized the energy band dispersion near the Fermi level in single-walled carbon nanotubes using low-temperature scanning tunneling microscopy. Analysis of energy dependent standing wave oscillations, which result from quantum interference of electrons resonantly scattered by defects, yield a linear energy dispersion near EF, and indicate the importance of parity in scattering for armchair single-walled carbon nanotubes. Additionally, these data provide values of the tight-binding overlap integral and Fermi wavevector in good agreement with previous work, but indicate that the electron coherence length is substantially shortened.Comment: 5 pages, 3 figure
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