Stabilisation of peat with colloidal nano and micro silica

Peat occurs abundantly in wetlands across Iran, particularly around the disappearing Urmia Lake. Conventional chemical stabilisation has been widely used to tackle the high compressibility and shrinkage potential of peat. Whilst effective, this generally reduces the carbon storage capacity of peat. Exotic stabilisers such as nano-silica (NS) have been shown to be relatively less harmful and without any direct environmental risk. NS has proved effective in improving the mechanical properties (to some extent) and pH-dependent natural structure of peat, but is commercially nonviable. This article presents findings from an experimental study of Urmia Lake peat stabilised with composites of NS and cheaper micro-silica (MS). Unconfined compressive strength (UCS) and California Bearing Ratio (CBR) tests were conducted on untreated and treated compacted natural peat soil samples after 7, 14 and 28 days of curing. Nano-silica was varied from 3 % to 9 % (by dry mass) in 3 % increments and micro-silica was varied from 6 % to 24 % (by dry mass) in 6 % increments. The observations are explained in terms of micro-scale events using XRF spectroscopy and SEM imaging. The findings suggest that the UCS of peat can be increased by administration of NS-MS composites, and the effectiveness is dependent on the relative content and particle size of NS and MS. The UCS and elasticity modulus increase with curing time. As manifested in the CBR results, administration of the composites improves the bearing capacity of peat and transforms it into a sub-base with suitable engineering functions whilst safeguarding its ecosystem service provisions

Compacted Expansive Elastic Silt and Tyre Powder Waste

Building on/with expansive soils with no treatment brings complications. Compacted expansive soils specifically fall short in satisfying the minimum requirements for transport embankment infrastructures, requiring the adoption of hauled virgin mineral aggregates or a sustainable alternative. Use of hauled aggregates comes at a high carbon and economical cost. On average, every 9m high embankment built with quarried/hauled soils cost 12600 MJ.m-2 Embodied Energy (EE). A prospect of using mixed cutting-arising expansive soils with industrial/domestic wastes can reduce the carbon cost and ease the pressure on landfills. The widespread use of recycled materials has been extensively limited due to concerns over their long-term performance, generally low shear strength and stiffness. In this contribution, hydromechanical properties of a waste tyre sand-sized rubber (a mixture of polybutadiene, polyisoprene, elastomers, and styrene-butadiene) and expansive silt is studied, allowing the short- and long-term behaviour of optimum compacted composites to be better established. The inclusion of tyre shred substantially decreased the swelling potential/pressure and modestly lowered the compression index. Silt-Tyre powder replacement lowered the bulk density, allowing construction of lighter reinforced earth structures. The shear strength and stiffness decreased on addition of tyre powder, yet the contribution of matric suction to the shear strength remained constant for tyre shred contents up to 20%. Reinforced soils adopted a ductile post-peak plastic behaviour with enhanced failure strain, offering the opportunity to build more flexible subgrades as recommended for expansive soils. Residual water content and tyre shred content are directly correlated; tyre-reinforced silt showed a greater capacity of water storage (than natural silts) and hence a sustainable solution to waterlogging and surficial flooding particularly in urban settings. Crushed fine tyre shred mixed with expansive silts/sands at 15 to 20 wt% appear to offer the maximum reduction in swelling-shrinking properties at minimum cracking, strength loss and enhanced compressibility expenses

Comparison of three with six regions of interest analyses in patients with idiopathic constipation undertaking colon transit scintigraphy using 67Ga-citrate

OBJECTIVE AND INTRODUCTION: Preparation of data from 6 geometric regions of interest in the colon is time consuming, and can become impractical in the environment of busy Nuclear Medicine Departments. Therefore, we have investigated and demonstrated an alternative method for obtaining the same diagnostic information from an analysis of patients with idiopathic constipation who underwent colon transit scintigraphy using 67Ga-citrate. Data analysis methods using three regions of interest are compared to the results obtained using the more time consuming 6 regions of interest method to analyze the data. MATERIALS AND METHODS: In this study, we report our results of the comparative reanalysis of data obtained by more traditional methods. We compare 3 regions of interest (ROI) which were taken from areas including the right colon, left colon and the rectosigmoid colon, with original work using our alternative 6 (ROI) diagnostic methodology. In addition, the proximal colonic emptying (PCE) was determined at 24 hr post ingestion among members of 3 identified subject groups. RESULTS: The distribution of activity as the ingested 67Ga-citrate passes through the colon constitutes an activity profile. The mean activity position in the colon can be determined from subsequent radiographic images and from this the mean clearance time can be calculated. In quantitative assessment, this represents the time at which half of activity was eliminated from colon (mean half clearance time - MCT) which did not appear different in the reanalysis. There is no significant difference in the current study in GMC 24h, GMC 48h and GMC 72h between two groups using the Man Whitney u test (p > 0.05), while in the previous work the results were statistically significant for the two later time periods GMC (GMC 48h and GMC 72h) (p = 0.016 and p = 0.027 respectively). The PCE in the group 1 was = 2.50 (0.37); group 2, 1.57 (0.47) and group 3, 2.97. The PCE was not different between the two groups (p = 0.21). CONCLUSIONS: This investigation demonstrated that the radionuclide colon transit study using 67Ga-citrate is a safe, physiologic, and quantitative method for evaluating the transit of fecal material from cecum to rectum. Although, the visual assessment of diagnosis of the subjects in the two analyses is the same, it was not completely supported by quantitative measurements. Therefore, further studies need to be done

Anisotropy in Sand–Fibre Composites and Undrained Stress–Strain Implications

Among the plethora of studies on anisotropy in fibre-reinforced sands, there exist conflicting views on effects on the steady-state deformations of initial packing. These conflicting views are further confused by strictly limited experimental evidence on flow in complex loading environments where the principal stresses rotate whereby shearing and torsional stresses combine, and when extension in soil relieves the compressive stresses. In the heuristic of intrinsically anisotropic nature of the soil and in recognition of the inability of placement methods to overcome such anisotropy, this paper aims to use the orientation of principal stress and soil initial packing state combined as proxy parameters to further the knowledge of plastic behaviour in fibre-reinforced sands. This study furthers the knowledge of the dependency of steady states on anisotropy in composite geomaterials. In doing so, the direction of principal stress orientation is varied from 15° to 60° (from vertical axis), taking an intermediate principal stress ratio of 0.5 and 1.0 and two initial confining pressures. Twenty-four undrained torsional shear tests are conducted using a hollow cylindrical torsional shear apparatus. Under compression and plain strain conditions, torsional stresses limit the improvements in soils’ undrained shear strength upon fibre reinforcement. Extension in soil remarkably increases fibres’ contribution to betterment of undrained strength. Fibres are least effective under low isotropic confining pressures and also for certain ranges of torsional stresses

The effect of an iodine restricted including no sea foods diet, on technetium-99m thyroid scintigraphy: A neglected issue in nuclear medicine practice

Although it is recommended to patients to avoid sea food and iodine-containing medications prior to iodine-131 ( 131I) scanning, the efficacy of this diet as for technetium-99m pertechnetate ( 99mTc-P) thyroid scintigraphy is not well addressed in the literature. We evaluated a self-managed, outpatients, iodine restricted diet (IRD) designed to reduce total body iodine in preparation for such a scan. We have studied 39 patients who referred to our Department for multinodular goiter, 30 females and 9 males, aged: 14-54 years and their 99mTc-P thyroid scintigraphy showed poor visualization of the thyroid gland. These patiens were living in regions with high consumption of sea foods went underwent a two-weeks iodine restriction including restriction of sea food diet for the reduction of iodine body content. These patients were called for a repeated scan after going on a IRD for at least two weeks. The two scans were compared visually, and by semiquantitative analysis. Semiquantitative analysis was applied in 8 regions of interest (ROI) by using Wilcoxon signed rank test. Thirty-six subjects had better quality scintigraphy images in the post IRD thyroid scan, as was visually assessed by two nuclear medicine physicians. Semiquantitatetively, there was a significant difference in the mean counts of ROI of the right and the left thyroid lobes in favor of the post IRD scans (P<0.05). In conclusion, this study suggests that in patients with multinodular goiter, living in regions with high consumption of sea foods a two-weeks diet for the reduction of iodine body content induces in most of the cases a slightly better diagnostic thyroid 99mTc-P scan

Stabilisation of peat with colloidal nanosilica

Colloidal nanosilica hydrosols are electrochemically stabilised polymerised amorphous silica in low viscosity suspensions. They have no known adverse impact on soil health and ecosystem service functions, thereby having a scope for use in groundworks as an alternative low-viscose stabilising material. Six grades of colloidal nanosilica are synthesised through an in-house procedure and introduced to a natural peat soil. The peak and residual compressive strength of compacted and modified soils are measured immediately after treatment and in four strain levels post treatment. Findings suggest that, despite the direct correlation between the nanosilica content and compressive strength, an increase in nanosilica content does not necessarily offer stability at larger strains. This is a major limitation. The particle-level kinematics in modified peat is discussed to gain a new insight into the role played by silica flocs on the build-up of macro-mechanical quantities such as peak and critical state strength. Overall, modification of peat with nanosilica leads to improvements in strength and formation of composites with generally more dilative behaviour. When used as a single stabiliser, a design 15 % to 20 % grade nanosilica solution yields a reasonably high strength although precautions against excessive straining of modified peat soils need to be taken in the first seven days post treatment. At this optimum grade, the loss of strength on further straining is capped to 9 % at plastic strains 1.5 times the peak strain

Fractals for the Sustainable Design of Engineered Particulate Systems

The engineering properties of particulate materials are the collective manifestation of interactions among their constituent particles and are structures within which particles adopt their spatial arrangement. For the first time in the literature, this paper employs an extended concept of ‘fractals’ to show that materials constituting particles of a certain size can be rationalized in three universal fractals. Within each fractal, materials build repeatable, reproducible, and predictable traits, and exhibit the stress-strain behaviors of nondifferentiable, self-similar trajectories. We present experimental evidence for such repeatable traits by subjecting six different particulate materials to static undrained isotropic, static undrained anisotropic, and cyclic undrained isotropic stresses. This paper shows that universal fractals are associated with fractal structures; herein, we explore the matters that influence their spatial arrangement. Within the context of sustainable design, ways of engineering natural particulate systems to improve a product’s physical and hydromechanical properties are already well established. In this review, a novel extended concept of fractals is introduced to inform the biomimetic design of particulate systems, to show how biomimicry can benefit in preserving general behavioral traits, and how biomimicry can offer predicated forms, thereby enhancing the design efficiency. To pursue such an ideal, processes that lead to the engineering of natural materials should not compromise their loyalty to the parent universal fractal

Concurrent papillary thyroid cancer and parathyroid adenoma as a rare condition: A case report

Although the pathological relationship between parathyroid and thyroid diseases is common, an association between parathyroid adenoma and thyroid cancer is rare. Concomitant thyroid cancer in patients with primary hyperparathyroidism (pHPT) has been reported at varying frequencies. WE present here a 23-year-old man who had papillary thyroid carcinoma in the right thyroid lobe and a parathyroid adenoma in the left thyroid lobe, which were confirmed surgically. Copyright © 2012 Via Medica