Comparison of C═C bond hydrogenation in C-4 unsaturated nitriles over Pt/alumina

The hydrogenation of allyl cyanide (but-1-ene-4-nitrile, AC), trans- and cis-crotononitrile (E- and Z-but-2-ene nitrile, TCN and CCN), and methacrylonitrile (2-cyano-1-propene, MCN) were studied, both singly and competitively, over a Pt/alumina catalyst in the liquid phase. Each unsaturated nitrile only underwent C═C bond hydrogenation: no evidence was found for the formation of the saturated or unsaturated amine. The nonconjugated allyl cyanide was found to be the most reactive unsaturated nitrile. Activation energies for the hydrogenation of the C═C bond in AC and MCN were determined giving values of 64 ± 7 kJ mol–1 for AC and 37 ± 4 kJ mol–1 for MCN. The reaction was zero order for both nitriles. Competitive hydrogenations revealed that not only does allyl cyanide react preferentially over the other isomers but also it inhibits the hydrogenation of the other isomers. When all four nitriles were simultaneously hydrogenated, inhibition effects were easily seen suggesting that in terms of strength of bonding to the surface an order of AC > CCN > TCN ∼ MN can be generated

Emulating and evaluating hybrid memory for managed languages on NUMA hardware

Non-volatile memory (NVM) has the potential to become a mainstream memory technology and challenge DRAM. Researchers evaluating the speed, endurance, and abstractions of hybrid memories with DRAM and NVM typically use simulation, making it easy to evaluate the impact of different hardware technologies and parameters. Simulation is, however, extremely slow, limiting the applications and datasets in the evaluation. Simulation also precludes critical workloads, especially those written in managed languages such as Java and C#. Good methodology embraces a variety of techniques for evaluating new ideas, expanding the experimental scope, and uncovering new insights. This paper introduces a platform to emulate hybrid memory for managed languages using commodity NUMA servers. Emulation complements simulation but offers richer software experimentation. We use a thread-local socket to emulate DRAM and a remote socket to emulate NVM. We use standard C library routines to allocate heap memory on the DRAM and NVM sockets for use with explicit memory management or garbage collection. We evaluate the emulator using various configurations of write-rationing garbage collectors that improve NVM lifetimes by limiting writes to NVM, using 15 applications and various datasets and workload configurations. We show emulation and simulation confirm each other's trends in terms of writes to NVM for different software configurations, increasing our confidence in predicting future system effects. Emulation brings novel insights, such as the non-linear effects of multi-programmed workloads on NVM writes, and that Java applications write significantly more than their C++ equivalents. We make our software infrastructure publicly available to advance the evaluation of novel memory management schemes on hybrid memories

Distance Aware Relaying Energy-efficient: DARE to Monitor Patients in Multi-hop Body Area Sensor Networks

In recent years, interests in the applications of Wireless Body Area Sensor Network (WBASN) is noticeably developed. WBASN is playing a significant role to get the real time and precise data with reduced level of energy consumption. It comprises of tiny, lightweight and energy restricted sensors, placed in/on the human body, to monitor any ambiguity in body organs and measure various biomedical parameters. In this study, a protocol named Distance Aware Relaying Energy-efficient (DARE) to monitor patients in multi-hop Body Area Sensor Networks (BASNs) is proposed. The protocol operates by investigating the ward of a hospital comprising of eight patients, under different topologies by positioning the sink at different locations or making it static or mobile. Seven sensors are attached to each patient, measuring different parameters of Electrocardiogram (ECG), pulse rate, heart rate, temperature level, glucose level, toxins level and motion. To reduce the energy consumption, these sensors communicate with the sink via an on-body relay, affixed on the chest of each patient. The body relay possesses higher energy resources as compared to the body sensors as, they perform aggregation and relaying of data to the sink node. A comparison is also conducted conducted with another protocol of BAN named, Mobility-supporting Adaptive Threshold-based Thermal-aware Energy-efficient Multi-hop ProTocol (M-ATTEMPT). The simulation results show that, the proposed protocol achieves increased network lifetime and efficiently reduces the energy consumption, in relative to M-ATTEMPT protocol.Comment: IEEE 8th International Conference on Broadband and Wireless Computing, Communication and Applications (BWCCA'13), Compiegne, Franc

Properties of Bipolar Fuzzy Hypergraphs

In this article, we apply the concept of bipolar fuzzy sets to hypergraphs and investigate some properties of bipolar fuzzy hypergraphs. We introduce the notion of $A-$ tempered bipolar fuzzy hypergraphs and present some of their properties. We also present application examples of bipolar fuzzy hypergraphs

Non-Invasive Induction Link Model for Implantable Biomedical Microsystems: Pacemaker to Monitor Arrhythmic Patients in Body Area Networks

In this paper, a non-invasive inductive link model for an Implantable Biomedical Microsystems (IBMs) such as, a pacemaker to monitor Arrhythmic Patients (APs) in Body Area Networks (BANs) is proposed. The model acts as a driving source to keep the batteries charged, inside a device called, pacemaker. The device monitors any drift from natural human heart beats, a condition of arrythmia and also in turn, produces electrical pulses that create forced rhythms that, matches with the original normal heart rhythms. It constantly sends a medical report to the health center to keep the medical personnel aware of the patient's conditions and let them handle any critical condition, before it actually happens. Two equivalent models are compared by carrying the simulations, based on the parameters of voltage gain and link efficiency. Results depict that the series tuned primary and parallel tuned secondary circuit achieves the best results for both the parameters, keeping in view the constraint of coupling co-efficient (k), which should be less than a value \emph{0.45} as, desirable for the safety of body tissues.Comment: IEEE 8th International Conference on Broadband and Wireless Computing, Communication and Applications (BWCCA'13), Compiegne, Franc

THE-FAME: THreshold based Energy-efficient FAtigue MEasurment for Wireless Body Area Sensor Networks using Multiple Sinks

Wireless Body Area Sensor Network (WBASN) is a technology employed mainly for patient health monitoring. New research is being done to take the technology to the next level i.e. player's fatigue monitoring in sports. Muscle fatigue is the main cause of player's performance degradation. This type of fatigue can be measured by sensing the accumulation of lactic acid in muscles. Excess of lactic acid makes muscles feel lethargic. Keeping this in mind we propose a protocol \underline{TH}reshold based \underline{E}nergy-efficient \underline{FA}tigue \underline{ME}asurement (THE-FAME) for soccer players using WBASN. In THE-FAME protocol, a composite parameter has been used that consists of a threshold parameter for lactic acid accumulation and a parameter for measuring distance covered by a particular player. When any parameters's value in this composite parameter shows an increase beyond threshold, the players is declared to be in a fatigue state. The size of battery and sensor should be very small for the sake of players' best performance. These sensor nodes, implanted inside player's body, are made energy efficient by using multiple sinks instead of a single sink. Matlab simulation results show the effectiveness of THE-FAME.Comment: IEEE 8th International Conference on Broadband and Wireless Computing, Communication and Applications (BWCCA'13), Compiegne, Franc

Mass transfer efficiency of a tall and low plate free area liquid pulsed sieve-plate extraction column

Acknowledgements The authors would like to acknowledge Chakwal group of industries for funding the project. Ms. Madiha, Ms. Zona, Mr. Sohaib, Mr. Abdullah, Mr. Mudassar, and Mr. Salahuddin also deserve our acknowledgements for their assistance in different ways.Peer reviewedPublisher PD

GRIDCC: Real-time workflow system

The Grid is a concept which allows the sharing of resources between distributed communities, allowing each to progress towards potentially different goals. As adoption of the Grid increases so are the activities that people wish to conduct through it. The GRIDCC project is a European Union funded project addressing the issues of integrating instruments into the Grid. This increases the requirement of workflows and Quality of Service upon these workflows as many of these instruments have real-time requirements. In this paper we present the workflow management service within the GRIDCC project which is tasked with optimising the workflows and ensuring that they meet the pre-defined QoS requirements specified upon them