162,199 research outputs found
Extended Hubbard model on a C molecule
The electronic correlations on a C molecule, as described by an
extended Hubbard Hamiltonian with a nearest neighbor Coulomb interaction of
strength , are studied using quantum Monte Carlo and exact diagonalization
methods. For electron doped C, it is known that pair-binding arising
from a purely electronic mechanism is absent within the standard Hubbard model
(V=0). Here we show that this is also the case for hole doping for and that, for both electron and hole doping, the effect of a non-zero is
to work against pair-binding. We also study the magnetic properties of the
neutral molecule, and find transitions between spin singlet and triplet ground
states for either fixed or values. In addition, spin, charge and
pairing correlation functions on C are computed. The spin-spin and
charge-charge correlations are very short-range, although a weak enhancement in
the pairing correlation is observed for a distance equal to the molecular
diameter.Comment: 9 pages, 8 figures, 4 table
Phase dynamics of inductively coupled intrinsic Josephson junctions and terahertz electromagnetic radiation
The Josephson effects associated with quantum tunneling of Cooper pairs
manifest as nonlinear relations between the superconductivity phase difference
and the bias current and voltage. Many novel phenomena appear, such as Shapiro
steps in dc cuurent-voltage (IV) characteristics of a Josephson junction under
microwave shining, which can be used as a voltage standard. Inversely, the
Josephson effects provide a unique way to generate high-frequency
electromagnetic (EM) radiation by dc bias voltage. The discovery of cuprate
high-Tc superconductors accelerated the effort to develop novel source of EM
waves based on a stack of atomically dense-packed intrinsic Josephson junctions
(IJJs), since the large superconductivity gap covers the whole terahertz
frequency band. Very recently, strong and coherent terahertz radiations have
been successfully generated from a mesa structure of
single crystal which works both as the source
of energy gain and as the cavity for resonance. It is then found theoretically
that, due to huge inductive coupling of IJJs produced by the nanometer junction
separation and the large London penetration depth of order of of
the material, a novel dynamic state is stabilized in the coupled sine-Gordon
system, in which kinks in phase differences are developed responding
to the standing wave of Josephson plasma and are stacked alternatively in the
c-axis. This novel solution of the inductively coupled sine-Gordon equations
captures the important features of experimental observations. The theory
predicts an optimal radiation power larger than the one available to date by
orders of magnitude, and thus suggests the technological relevance of the
phenomena.Comment: review article (69 pages, 30 figures
Stereospecific synthesis of the aglycone of pseudopterosin E
No description supplie
Agrobacterium tumefaciens Deploys a Superfamily of Type VI Secretion DNase Effectors as Weapons for Interbacterial Competition In Planta
The type VI secretion system (T6SS) is a widespread molecular weapon deployed by many Proteobacteria to target effectors/toxins into both eukaryotic and prokaryotic cells. We report that Agrobacterium tumefaciens, a soil bacterium that triggers tumorigenesis in plants, produces a family of type VI DNase effectors (Tde) that are distinct from previously known polymorphic toxins and nucleases. Tde exhibits an antibacterial DNase activity that relies on a conserved HxxD motif and can be counteracted by a cognate immunity protein, Tdi. In vitro, A. tumefaciens T6SS could kill Escherichia coli but triggered a lethal counterattack by Pseudomonas aeruginosa upon injection of the Tde toxins. However, in an in planta coinfection assay, A. tumefaciens used Tde effectors to attack both siblings cells and P. aeruginosa to ultimately gain a competitive advantage. Such acquired T6SS-dependent fitness in vivo and conservation of Tde-Tdi couples in bacteria highlights a widespread antibacterial weapon beneficial for niche colonization
Hierarchical Stochastic Block Model for Community Detection in Multiplex Networks
Multiplex networks have become increasingly more prevalent in many fields,
and have emerged as a powerful tool for modeling the complexity of real
networks. There is a critical need for developing inference models for
multiplex networks that can take into account potential dependencies across
different layers, particularly when the aim is community detection. We add to a
limited literature by proposing a novel and efficient Bayesian model for
community detection in multiplex networks. A key feature of our approach is the
ability to model varying communities at different network layers. In contrast,
many existing models assume the same communities for all layers. Moreover, our
model automatically picks up the necessary number of communities at each layer
(as validated by real data examples). This is appealing, since deciding the
number of communities is a challenging aspect of community detection, and
especially so in the multiplex setting, if one allows the communities to change
across layers. Borrowing ideas from hierarchical Bayesian modeling, we use a
hierarchical Dirichlet prior to model community labels across layers, allowing
dependency in their structure. Given the community labels, a stochastic block
model (SBM) is assumed for each layer. We develop an efficient slice sampler
for sampling the posterior distribution of the community labels as well as the
link probabilities between communities. In doing so, we address some unique
challenges posed by coupling the complex likelihood of SBM with the
hierarchical nature of the prior on the labels. An extensive empirical
validation is performed on simulated and real data, demonstrating the superior
performance of the model over single-layer alternatives, as well as the ability
to uncover interesting structures in real networks
The quality of price formation at market openings and closings: evidence from the Nasdaq stock market
Central counterparties (CCPs) have increasingly become a cornerstone of financial markets infrastructure. We present a model where trades are time-critical, liquidity is limited and there is limited enforcement of trades. We show a CCP novating trades implements efficient trading behaviour. It is optimal for the CCP to face default losses to achieve the efficient level of trade. To cover these losses, the CCP optimally uses margin calls, and, as the default problem becomes more severe, also requires default funds and then imposes position limits
Estimates of Effective Hubbard Model Parameters for C20 isomers
We report on an effective Hubbard Hamiltonian approach for the study of
electronic correlations in C isomers, cage, bowl and ring, with quantum
Monte Carlo and exact diagonalization methods. The tight-binding hopping
parameter, , in the effective Hamiltonian is determined by a fit to density
functional theory calculations, and the on-site Coulomb interaction, , is
determined by calculating the isomers' affinity energies, which are compared to
experimental values. For the C fullerene cage we estimate eV and . The resulting
effective Hamiltonian is then used to study the shift of spectral peaks in the
density of states of neutral and one-electron-doped C isomers. Energy
gaps are also extracted for possible future comparison with experiments.Comment: 6 pages, 5 figure
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