Scattering studies from polymer blends.

Polymer Science and EngineeringDoctor of Philosophy (PhD

Indentation of ultrathin elastic films and the emergence of asymptotic isometry

We study the indentation of a thin elastic film floating at the surface of a liquid. We focus on the onset of radial wrinkles at a threshold indentation depth and the evolution of the wrinkle pattern as indentation progresses far beyond this threshold. Comparison between experiments on thin polymer films and theoretical calculations shows that the system very quickly reaches the Far from Threshold (FT) regime, in which wrinkles lead to the relaxation of azimuthal compression. Furthermore, when the indentation depth is sufficiently large that the wrinkles cover most of the film, we recognize a novel mechanical response in which the work of indentation is transmitted almost solely to the liquid, rather than to the floating film. We attribute this unique response to a nontrivial isometry attained by the deformed film, and discuss the scaling laws and the relevance of similar isometries to other systems in which a confined sheet is subjected to weak tensile loads.Comment: 5 pages, close to published versio

Poly(oxime-ester) Vitrimers with Catalyst-Free Bond Exchange.

Vitrimers are network polymers that undergo associative bond exchange reactions in the condensed phase above a threshold temperature, dictated by the exchangeable bonds comprising the vitrimer. For vitrimers, chemistries reliant on poorly nucleophilic bond exchange partners (e.g., hydroxy-functionalized alkanes) or poorly electrophilic exchangeable bonds, catalysts are required to lower the threshold temperature, which is undesirable in that catalyst leaching or deactivation diminishes its influence over time and may compromise reuse. Here we show how to access catalyst-free bond exchange reactions in catalyst-dependent polyester vitrimers by obviating conventional ester bonds in favor of oxime-esters. Poly(oxime-ester) (POE) vitrimers are synthesized using thiol-ene click chemistry, affording high stretchability and malleability. POE vitrimers are readily recycled with little degradation of their initial mechanical properties, suggesting exciting opportunities for sustainable plastics

The Dynamical Environment of Dawn at Vesta

Dawn is the first NASA mission to operate in the vicinity of the two most massive asteroids in the main belt, Ceres and Vesta. This double-rendezvous mission is enabled by the use of low-thrust solar electric propulsion. Dawn will arrive at Vesta in 2011 and will operate in its vicinity for approximately one year. Vesta's mass and non-spherical shape, coupled with its rotational period, presents very interesting challenges to a spacecraft that depends principally upon low-thrust propulsion for trajectory-changing maneuvers. The details of Vesta's high-order gravitational terms will not be determined until after Dawn's arrival at Vesta, but it is clear that their effect on Dawn operations creates the most complex operational environment for a NASA mission to date. Gravitational perturbations give rise to oscillations in Dawn's orbital radius, and it is found that trapping of the spacecraft is possible near the 1:1 resonance between Dawn's orbital period and Vesta's rotational period, located approximately between 520 and 580 km orbital radius.This resonant trapping can be escaped by thrusting at the appropriate orbital phase. Having passed through the 1:1 resonance, gravitational perturbations ultimately limit the minimum radius for low-altitude operations to about 400 km,in order to safely prevent surface impact. The lowest practical orbit is desirable in order to maximize signal-to-noise and spatial resolution of the Gamma-Ray and Neutron Detector and to provide the highest spatial resolution observations by Dawn's Framing Camera and Visible InfraRed mapping spectrometer. Dawn dynamical behavior is modeled in the context of a wide range of Vesta gravity models. Many of these models are distinguishable during Dawn's High Altitude Mapping Orbit and the remainder are resolved during Dawn's Low Altitude Mapping Orbit, providing insight into Vesta's interior structure.Comment: Corrected normalization coefficients; updated table text and reference

From solid surfactants to micromotors: An overview of the synthesis and applications of heterogeneous particles

Colloid science has classically concerned itself with the investigation of the properties of dispersed phases in a bulk medium. This has led to the development of a rich amount of chemistry, physics, and engineering that have facilitated the evolution and maturation of this field. One of the many developments made over the last 30 years is the introduction of particles that are heterogeneous in chemistry and shape. These heterogeneities can introduce behaviors that are not achievable in homogeneous systems and that are specific to the type and class of nonuniformity. This has led to the development of numerous technologies, two of which are Janus micromotors and solid surfactants. This review aims to familiarize the reader with the field of heterogeneous particles. We begin with an overview of various synthetic methods to produce colloidal particles that are heterogeneous in chemistry and shape. We then discuss their use as solid surfactants and autonomous micromotors. We then close by summarizing and providing a future perspective on the field

X-ray Modeling of \eta\ Carinae and WR140 from SPH Simulations

The colliding wind binary (CWB) systems \eta\ Carinae and WR140 provide unique laboratories for X-ray astrophysics. Their wind-wind collisions produce hard X-rays that have been monitored extensively by several X-ray telescopes, including RXTE. To interpret these RXTE X-ray light curves, we model the wind-wind collision using 3D smoothed particle hydrodynamics (SPH) simulations. Adiabatic simulations that account for the absorption of X-rays from an assumed point source at the apex of the wind-collision shock cone by the distorted winds can closely match the observed 2-10keV RXTE light curves of both \eta\ Car and WR140. This point-source model can also explain the early recovery of \eta\ Car's X-ray light curve from the 2009.0 minimum by a factor of 2-4 reduction in the mass loss rate of \eta\ Car. Our more recent models relax the point-source approximation and account for the spatially extended emission along the wind-wind interaction shock front. For WR140, the computed X-ray light curve again matches the RXTE observations quite well. But for \eta\ Car, a hot, post-periastron bubble leads to an emission level that does not match the extended X-ray minimum observed by RXTE. Initial results from incorporating radiative cooling and radiatively-driven wind acceleration via a new anti-gravity approach into the SPH code are also discussed.Comment: 5 pages, 3 figures, Proceedings of the 39th Li\'ege Astrophysical Colloquium, held in Li\`ege 12-16 July 2010, edited by G. Rauw, M. De Becker, Y. Naz\'e, J.-M. Vreux, P. William

Creating a Plug-In Electric Vehicle Industry Cluster in Michigan: Prospects and Policy Options

This Article seeks to examine how policy can be used strategically to foster the development of a plug-in electric vehicle ( PEV ) industry cluster in Michigan. The tendency for certain industries to localize in particular regions has captured the interest of much economic research and policy discussion in recent years. The trend toward the clustering of new industries has stayed strong despite the acceleration of globalization. Attention to clusters has proven to be an enduring theme in economic development circles for nearly thirty years. Clusters generate synergies that make industrial activity greater than the sum of contributions by individual players. In this Article, we review a broad array of literature on the development of economic clusters in general, assess the key elements of the PEV value chain, and summarize interviews with several major players along the electric vehicle value chain. Our goal is to look beyond simply buying jobs with tax subsidies, and to identify ways in which targeted policy support can spark a self-perpetuating, high-technology PEV economic cluster centered in the State of Michigan. The remainder of this Article is organized as follows. First, in Part I, we review the literature on industrial clusters in order to identify the broad features of clustering behavior. In Part II, we explore the factors that lead industries to cluster in the first place, apply this analysis to the case of the automobile industry in the twentieth century, and assesses the likelihood of development of PEVs within one or more industrial clusters. Part III turns to the key characteristics of successful clusters. Part IV explores the factors Michigan will need to successfully build a PEV cluster and examines the range of policy options that have been used to support cluster development in various locations around the world. Part V pulls the foregoing analysis together by presenting a set of policy recommendations that may support the creation of a successful PEV cluster in Michigan