4,104 research outputs found
Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of \u3cem\u3etrans\u3c/em\u3e-Pt(Pet\u3csub\u3e3\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3e(SePh)\u3csub\u3e2\u3c/sub\u3e
The crystal structure of trans-[((bis)triethylphosphine)(bis(phenylselenato))platinum (II)] has been determined by single crystal X-ray diffraction. Crystallization occurs in the triclinic space group P-1 (No. 2) with a = 8.9964(2) Å, b = 11.5103(2) Å, c = 14.9335(3) Å; α = 85.8750(10)°, β = 72.5350(10)°, γ = 68.4450(10)°. Details of the structure and spectroscopic results are presented and discussed and comparisons are made with related square planar platinum (II) structures
Study of bonding methods for flip chip and beam leaded devices
The results are presented of a comprehensive study and evaluation for the bonding of flip chip and beam leaded devices onto hybrid microcircuit substrates used in high reliability space applications. The program included the evaluation of aluminum flip chips, solder (silver/tin) bump chips, gold beam leaded devices, and aluminum beam leaded devices
\u3cem\u3eN\u3c/em\u3e-Methylbenzothiazole-2(3\u3cem\u3eH\u3c/em\u3e)-selone, C\u3csub\u3e8\u3c/sub\u3eH\u3csub\u3e7\u3c/sub\u3eNSSe
The crystal structure of N-methyl1,3-benzothiazole-2(3H)-selone, (mbts) has been studied to estimate the changes in the molecular geometry of the mbts ligand upon coordination. Hypervalent complexes of mbts with TeII and II have been studied by us previously. A significant elongation of the Se=C bond [from 1.817 (7) in mbts to 1.85-1.88 Ã… in the complexes] was found, but there were no significant changes in the other geometric parameters of the ligand. The only other bond-length decrease of note was for SeC-NMe [from 1.35 (1) in mbts to 1.32-1.34 Ã… in the complexes]. Thus, only the amino group takes part in electron redistribution upon coordination
Bis[(dimethyl-λ\u3csup\u3e4\u3c/sup\u3e-sulfanylidene)oxonium] hexabromidotellurate(IV) dimethyl sulfoxide disolvate
Bromobis(Diethyldithiocarbamato)(4-Methoxyphenyl)Tellurium(IV)
The crystals of the TeIV complex p-CH3OC6H4Te(Et2NCS2)2Br are isomorphous with those of the the iodine and mixed iodine/bromine analogues previously investigated. The structure is pentagonal bipyramidal at the Te atom with four S atoms [Te-S 2.618-2.721 (1) Å] and the Br atom [Te-Br 2.943 (1) Å] in equatorial positions. The p-methoxyphenyl group is axial [Te-C 2.147 (3) Å]. The second axial position is approached by a Br atom of a centrosymmetrically related complex [TeBr 3.423 (1) Å, C-TeBr 173.1 (1)°] so that the molecules are joined into centrosymmetric pairs by this weak secondary coordination
NASA micromin computer Monthly progress letter, Jan. 1967
Microminiature circuit development for flight control computer
Utility of electronic patient records for evaluating stroke secondary prevention in primary care
Self Calibration of Tomographic Weak Lensing for the Physics of Baryons to Constrain Dark Energy
Numerical studies indicate that uncertainties in the treatment of baryonic
physics can affect predictions for shear power spectra at a level that is
significant for forthcoming surveys such as DES, SNAP, and LSST.
Correspondingly, we show that baryonic effects can significantly bias dark
energy parameter measurements. Eliminating such biases by neglecting
information in multipoles beyond several hundred leads to weaker parameter
constraints by a factor of approximately 2 to 3 compared with using information
out to multipoles of several thousand. Fortunately, the same numerical studies
that explore the influence of baryons indicate that they primarily affect power
spectra by altering halo structure through the relation between halo mass and
mean effective halo concentration. We explore the ability of future weak
lensing surveys to constrain both the internal structures of halos and the
properties of the dark energy simultaneously as a first step toward self
calibrating for the physics of baryons. This greatly reduces parameter biases
and no parameter constraint is degraded by more than 40% in the case of LSST or
30% in the cases of SNAP or DES. Modest prior knowledge of the halo
concentration relation greatly improves even these forecasts. Additionally, we
find that these surveys can constrain effective halo concentrations near
m~10^14 Msun/h and z~0.2 to better than 10% with shear power spectra alone.
These results suggest that inferring dark energy parameters with measurements
of shear power spectra can be made robust to baryonic effects and may
simultaneously be competitive with other methods to inform models of galaxy
formation. (Abridged)Comment: 18 pages, 11 figures. Minor changes reflecting referee's comments.
Results and conclusions unchanged. Accepted for publication in Physical
Review
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