4,157 research outputs found
Sliding friction between an elastomer network and a grafted polymer layer: the role of cooperative effects
We study the friction between a flat solid surface where polymer chains have
been end-grafted and a cross-linked elastomer at low sliding velocity. The
contribution of isolated grafted chains' penetration in the sliding elastomer
has been early identified as a weakly velocity dependent pull-out force. Recent
experiments have shown that the interactions between the grafted chains at high
grafting density modify the friction force by grafted chain. We develop here a
simple model that takes into account those interactions and gives a limit
grafting density beyond which the friction no longer increases with the
grafting density, in good agreement with the experimental dataComment: Submitted to Europhys. Letter
Random Time Forward Starting Options
We introduce a natural generalization of the forward-starting options, first
discussed by M. Rubinstein. The main feature of the contract presented here is
that the strike-determination time is not fixed ex-ante, but allowed to be
random, usually related to the occurrence of some event, either of financial
nature or not. We will call these options {\bf Random Time Forward Starting
(RTFS)}. We show that, under an appropriate "martingale preserving" hypothesis,
we can exhibit arbitrage free prices, which can be explicitly computed in many
classical market models, at least under independence between the random time
and the assets' prices. Practical implementations of the pricing methodologies
are also provided. Finally a credit value adjustment formula for these OTC
options is computed for the unilateral counterparty credit risk.Comment: 19 pages, 1 figur
Shear flow effects on phase separation of entangled polymer blends
We introduce an entanglement model mixing rule for stress relaxation in a polymer blend to a modified Cahn-Hilliard equation of motion for concentration fluctuations in the presence of shear flow. Such an approach predicts both shear-induced mixing and demixing, depending on the relative relaxation times and plateau moduli of the two components
Fitting Isochrones to Open Cluster photometric data: A new global optimization tool
We present a new technique to fit color-magnitude diagrams of open clusters
based on the Cross-Entropy global optimization algorithm. The method uses
theoretical isochrones available in the literature and maximizes a weighted
likelihood function based on distances measured in the color-magnitude space.
The weights are obtained through a non parametric technique that takes into
account the star distance to the observed center of the cluster, observed
magnitude uncertainties, the stellar density profile of the cluster among
others. The parameters determined simultaneously are distance, reddening, age
and metallicity. The method takes binary fraction into account and uses a
Monte-Carlo approach to obtain uncertainties on the determined parameters for
the cluster by running the fitting algorithm many times with a re-sampled data
set through a bootstrapping procedure. We present results for 9 well studied
open clusters, based on 15 distinct data sets, and show that the results are
consistent with previous studies. The method is shown to be reliable and free
of the subjectivity of most previous visual isochrone fitting techniques.Comment: 19 pages, 25 figures, accepted for publication in
Astronomy&Astrophysic
Boundary conditions associated with the Painlev\'e III' and V evaluations of some random matrix averages
In a previous work a random matrix average for the Laguerre unitary ensemble,
generalising the generating function for the probability that an interval at the hard edge contains eigenvalues, was evaluated in terms of
a Painlev\'e V transcendent in -form. However the boundary conditions
for the corresponding differential equation were not specified for the full
parameter space. Here this task is accomplished in general, and the obtained
functional form is compared against the most general small behaviour of
the Painlev\'e V equation in -form known from the work of Jimbo. An
analogous study is carried out for the the hard edge scaling limit of the
random matrix average, which we have previously evaluated in terms of a
Painlev\'e \IIId transcendent in -form. An application of the latter
result is given to the rapid evaluation of a Hankel determinant appearing in a
recent work of Conrey, Rubinstein and Snaith relating to the derivative of the
Riemann zeta function
Area-preserving dynamics of a long slender finger by curvature: a test case for the globally conserved phase ordering
A long and slender finger can serve as a simple ``test bed'' for different
phase ordering models. In this work, the globally-conserved,
interface-controlled dynamics of a long finger is investigated, analytically
and numerically, in two dimensions. An important limit is considered when the
finger dynamics are reducible to the area-preserving motion by curvature. A
free boundary problem for the finger shape is formulated. An asymptotic
perturbation theory is developed that uses the finger aspect ratio as a small
parameter. The leading-order approximation is a modification of ``the Mullins
finger" (a well-known analytic solution) which width is allowed to slowly vary
with time. This time dependence is described, in the leading order, by an
exponential law with the characteristic time proportional to the (constant)
finger area. The subleading terms of the asymptotic theory are also calculated.
Finally, the finger dynamics is investigated numerically, employing the
Ginzburg-Landau equation with a global conservation law. The theory is in a
very good agreement with the numerical solution.Comment: 8 pages, 4 figures, Latex; corrected typo
Nonaffine rubber elasticity for stiff polymer networks
We present a theory for the elasticity of cross-linked stiff polymer
networks. Stiff polymers, unlike their flexible counterparts, are highly
anisotropic elastic objects. Similar to mechanical beams stiff polymers easily
deform in bending, while they are much stiffer with respect to tensile forces
(``stretching''). Unlike in previous approaches, where network elasticity is
derived from the stretching mode, our theory properly accounts for the soft
bending response. A self-consistent effective medium approach is used to
calculate the macroscopic elastic moduli starting from a microscopic
characterization of the deformation field in terms of ``floppy modes'' --
low-energy bending excitations that retain a high degree of non-affinity. The
length-scale characterizing the emergent non-affinity is given by the ``fiber
length'' , defined as the scale over which the polymers remain straight.
The calculated scaling properties for the shear modulus are in excellent
agreement with the results of recent simulations obtained in two-dimensional
model networks. Furthermore, our theory can be applied to rationalize bulk
rheological data in reconstituted actin networks.Comment: 12 pages, 10 figures, revised Section II
Acceptance conditions in automated negotiation
In every negotiation with a deadline, one of the negotiating parties has to accept an offer to avoid a break off. A break off is usually an undesirable outcome for both parties, therefore it is important that a negotiator employs a proficient mechanism to decide under which conditions to accept. When designing such conditions one is faced with the acceptance dilemma: accepting the current offer may be suboptimal, as better offers may still be presented. On the other hand, accepting too late may prevent an agreement from being reached, resulting in a break off with no gain for either party. Motivated by the challenges of bilateral negotiations between automated agents and by the results and insights of the automated negotiating agents competition (ANAC), we classify and compare state-of-the-art generic acceptance conditions. We focus on decoupled acceptance conditions, i.e. conditions that do not depend on the bidding strategy that is used. We performed extensive experiments to compare the performance of acceptance conditions in combination with a broad range of bidding strategies and negotiation domains. Furthermore we propose new acceptance conditions and we demonstrate that they outperform the other conditions that we study. In particular, it is shown that they outperform the standard acceptance condition of comparing the current offer with the offer the agent is ready to send out. We also provide insight in to why some conditions work better than others and investigate correlations between the properties of the negotiation environment and the efficacy of acceptance condition
Regular dendritic patterns induced by non-local time-periodic forcing
The dynamic response of dendritic solidification to spatially homogeneous
time-periodic forcing has been studied. Phase-field calculations performed in
two dimensions (2D) and experiments on thin (quasi 2D) liquid crystal layers
show that the frequency of dendritic side-branching can be tuned by oscillatory
pressure or heating. The sensitivity of this phenomenon to the relevant
parameters, the frequency and amplitude of the modulation, the initial
undercooling and the anisotropies of the interfacial free energy and molecule
attachment kinetics, has been explored. It has been demonstrated that besides
the side-branching mode synchronous with external forcing as emerging from the
linear Wentzel-Kramers-Brillouin analysis, modes that oscillate with higher
harmonic frequencies are also present with perceptible amplitudes.Comment: 15 pages, 23 figures, Submitted to Phys. Rev.
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