A route to explain water anomalies from results on an aqueous solution of salt

In this paper we investigate the possibility to detect the hypothesized liquid-liquid critical point of water in supercooled aqueous solutions of salts. Molecular dynamics computer simulations are conducted on bulk TIP4P water and on an aqueous solution of sodium chloride in TIP4P water, with concentration c = 0.67 mol/kg. The liquid-liquid critical point is found both in the bulk and in the solution. Its position in the thermodynamic plane shifts to higher temperature and lower pressure for the solution. Comparison with available experimental data allowed us to produce the phase diagrams of both bulk water and the aqueous solution as measurable in experiments. Given the position of the liquid-liquid critical point in the solution as obtained from our simulations, the experimental determination of the hypothesized liquid-liquid critical point of water in aqueous solutions of salts appears possible.Comment: 5 pages, 6 figures. Accepted for publication on the Journal of Chemical Physics (2010)

Non-strategic nuclear weapons: the next step in multilateral arms control

This paper by Crispin Rovere and Kalman A Robertson addresses the many barriers to including tactical nuclear weapons in disarmament talks. It considers the difficulty of bringing other emerging powers such as China into the nuclear arms control equation. The study proposes a new arms control treaty that would ban outright the development and possession of a special kind of tactical nuclear weapon called \u27low-yield nuclear weapons\u27 that the authors argue carries an increasingly grave risk of starting a nuclear war. The paper says that Australia should take the lead in promoting a new treaty banning low-yield nuclear weapons. A longer discussion paper, which includes a more thorough exploration of the technical, strategic and legal issues, as well as many references for further reading is available below

The untapped potential of plant thin cell layers

Thin cell layers (TCLs), which contain a small number of cells or tissues, are explants excised from different organs (stems, leaves, roots, inflorescences, flowers, cotyledons, hypocotyls/epicotyls, and embryos). After almost 45 years of research, this culture system has been used for several monocotyledonous and dicotyledonous plants of commercial importance, and for model plants. The limited amount of cells in a TCL is of paramount importance because marker molecules/genes of differentiation can be easily localized in situ in the target/responsive cells. Thus, the use of TCLs has allowed, and continues to allow, for the expansion of knowledge in plant research in a practical and applied manner into the fields of tissue culture and micropropagation, cell and organ genetics, molecular biology, biochemistry, and development. Starting from a brief historical background, the actual and potential uses of the TCL system are briefly reviewed

Glass transition and layering effects in confined water: a computer simulation study

Single particle dynamics of water confined in a nanopore is studied through Computer Molecular Dynamics. The pore is modeled to represent the average properties of a pore of Vycor glass. Dynamics is analyzed at different hydration levels and upon supercooling. At all hydration levels and all temperatures investigated a layering effect is observed due to the strong hydrophilicity of the substrate. The time density correlators show, already at ambient temperature, strong deviations from the Debye and the stretched exponential behavior. Both on decreasing hydration level and upon supercooling we find features that can be related to the cage effect typical of a supercooled liquid undergoing a kinetic glass transition. Nonetheless the behavior predicted by Mode Coupling Theory can be observed only by carrying out a proper shell analysis of the density correlators. Water molecules within the first two layers from the substrate are in a glassy state already at ambient temperature (bound water). The remaining subset of molecules (free water) undergoes a kinetic glass transition; the relaxation of the density correlators agree with the main predictions of the theory. From our data we can predict the temperature of structural arrest of free water.Comment: 14 pages, 15 figures inserted in the text, to be published in J. Chem. Phys. (2000

Targeting Research for Enhanced Impact on Poverty in Marginal Areas: The Representative Case of the Dry Areas of Syria

Agricultural research in marginal dry areas can contribute to reducing poverty through the development of technological, institutional and policy options for poor farmers by addressing diversified opportunities and development pathways. This paper analyzes the diversity of rural livelihood strategies in the Khanasser Valley in northwest Syria, an area representative of marginal drylands. We experimentally define an operational classification of household typologies based on their different livelihood strategies, capabilities, and opportunities by applying a Sustainable Livelihoods framework. Livelihoods diversity has implications on where and how research must be targeted to have impact on poverty. Households less endowed in land and natural resources and with livelihoods only marginally based on farming have to rely on off-farm income or exit agriculture. Poorest households with livelihoods based on migration and scarce land assets can benefit little or only indirectly from agricultural research. Yet the poor laborers with enough assets can benefit more and directly from pro-poor agricultural research. We discuss the pathways that these different groups can undertake to escape poverty, with emphasis on those that use agricultural technologies developed within an Integrated Natural Resources Management approach by a benchmark project of ICARDA in the Khanasser area. Some of the technologies, assessed ex-ante based on extensive experimental data, can contribute to improving livelihoods and preserving the natural resource base. If, however, these are to become part of effective development pathways and impact on poverty, they must meet various policy and institutional conditions, that we discuss vis-a-vis the different typologies of users.Impact, Livelihoods, Marginal Areas, Poverty, Syria, D1, I3, O3, Q12, Q16, Food Security and Poverty,

Manual for conducting socioeconomic surveys through Pocket Portable Device Assistants (PDAs) and personal computers

Socioeconomic environment, Surveys, Computers, Computer software, Data collection, PDAs, Personal computers, Research Methods/ Statistical Methods, U40, E10,

Exploring associations between micro-level models of innovation diffusion and emerging macro-level adoption patterns

A micro-level agent-based model of innovation diffusion was developed that explicitly combines (a) an individual's perception of the advantages or relative utility derived from adoption, and (b) social influence from members of the individual's social network. The micro-model was used to simulate macro-level diffusion patterns emerging from different configurations of micro-model parameters. Micro-level simulation results matched very closely the adoption patterns predicted by the widely-used Bass macro-level model (Bass, 1969). For a portion of the domain, results from micro-simulations were consistent with aggregate-level adoption patterns reported in the literature. Induced Bass macro-level parameters and responded to changes in micro-parameters: (1) increased with the number of innovators and with the rate at which innovators are introduced; (2) increased with the probability of rewiring in small-world networks, as the characteristic path length decreases; and (3) an increase in the overall perceived utility of an innovation caused a corresponding increase in induced and values. Understanding micro to macro linkages can inform the design and assessment of marketing interventions on micro-variables - or processes related to them - to enhance adoption of future products or technologies.Comment: 20 pages, 4 figures and a table of supplementary data. Accepted for publicatio

Impacts of CIMMYT's International Training Linked to Long-Term Trials in Conservation Agriculture: 1996-2006

Education, Training courses, International cooperation, Research institutions, Natural resources, Resource conservation, Environmental Economics and Policy,

A molecular dynamics simulation of water confined in a cylindrical SiO2 pore

A molecular dynamics simulation of water confined in a silica pore is performed in order to compare it with recent experimental results on water confined in porous Vycor glass at room temperature. A cylindrical pore of 40 A is created inside a vitreous SiO2 cell, obtained by computer simulation. The resulting cavity offers to water a rough hydrophilic surface and its geometry and size are similar to those of a typical pore in porous Vycor glass. The site-site distribution functions of water inside the pore are evaluated and compared with bulk water results. We find that the modifications of the site-site distribution functions, induced by confinement, are in qualitative agreement with the recent neutron diffraction experiment, confirming that the disturbance to the microscopic structure of water mainly concerns orientational arrangement of neighbouring molecules. A layer analysis of MD results indicates that, while the geometrical constraint gives an almost constant density profile up to the layers closest to the interface, with an uniform average number of hydrogen bonds (HB), the hydrophilic interaction produces the wetting of the pore surface at the expenses of the adjacent water layers. Moreover the orientational disorder togheter with a reduction of the average number of HB persists in the layers close to the interface, while water molecules cluster in the middle of the pore at a density and with a coordination similar to bulk water.Comment: RevTex, 11 pages, 12 figures; to appear in June 15 issue of J. Chem. Phy

Local order in aqueous solutions of rare gases and the role of the solute concentration: a computer simulation study with a polarizable potential

Aqueous solutions of rare gases are studied by computer simulation employing a polarizable potential for both water and solutes. The use of a polarizable potential allows to study the systems from ambient to supercritical conditions for water. In particular the effects of increasing the concentration and the size of the apolar solutes are considered in an extended range of temperatures. By comparing the results at increasing temperature it appears clearly the change of behaviour from the tendency to demix at ambient conditions to a regime of complete solubility in the supercritical region. In this respect the role of the hydrogen bond network of water is evidenced.Comment: Accepted for publication in Molecular Physics 2004. 19 pages, 10 figure