Bis(diethyl­enetriamine)­cobalt(III) hexa­chloridoindate(III)

The title compound, [Co(C4H13N3)2][InCl6], was synthesized under hydro­thermal conditions. In the cation, the Co—N bond lengths lie in the range 1.967 (2)–1.9684 (15) Å. In the anion, the InIII atom is coordinated by six Cl atoms resulting in a slightly distorted octa­hedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N—H⋯Cl hydrogen bonds between cations and anions consolidate the crystal packing

Tris(2,2′-bi-1H-imidazole-κ2 N 3,N 3′)cobalt(II) hydrogen phosphate

The title compound, [Co(C6H6N4)3]HPO4, was synthesized under hydro­thermal conditions. In the cation, the CoII atom is octa­hedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Inter­molecular N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure

Zur Behandlung von Ueberstrukturen in der Roentgenstrukturanalyse

Available from TIB Hannover: DW 7024 / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekSIGLEDEGerman