34,274 research outputs found
Quantum frustration in organic Mott insulators: from spin liquids to unconventional superconductors
We review the interplay of frustration and strong electronic correlations in
quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X
and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases
including spin liquids, valence bond crystals, pseudogapped metals, and
unconventional superconductivity. Of particular interest is that in several
materials there is a direct transition as a function of pressure from a spin
liquid Mott insulating state to a superconducting state. Experiments on these
materials raise a number of profound questions about the quantum behaviour of
frustrated systems, particularly the intimate connection between spin liquids
and superconductivity. Insights into these questions have come from a wide
range of theoretical techniques including first principles electronic
structure, quantum many-body theory and quantum field theory. In this review we
introduce the basic ideas of the field by discussing a simple frustrated
Heisenberg model with four spins. We then describe the key experimental
results, emphasizing that for two materials, k-(BEDT-TTF)_2Cu_2(CN)_3 and
EtMe_3Sb[Pd(dmit)_2]_2, there is strong evidence for a spin liquid ground
state, and for EtMe_3P[Pd(dmit)_2]_2, a valence bond solid ground state. We
review theoretical attempts to explain these phenomena, arguing that this can
be captured by a Hubbard model on the anisotropic triangular lattice at half
filling, and that resonating valence bond wavefunctions can capture most of the
essential physics. We review evidence that this model can have a spin liquid
ground state for a range of parameters that are realistic for the relevant
materials. We conclude by summarising the progress made thus far and
identifying some of the key questions still to be answered.Comment: Major rewrite. New material added and many typos corrected. 67 pages,
41 figures. Thanks to those who commented on the previous versio
Symmetry of the superconducting order parameter in frustrated systems determined by the spatial anisotropy of spin correlations
We study the resonating valence bond (RVB) theory of the Hubbard-Heisenberg
model on the half-filled anisotropic triangular lattice. Varying the
frustration changes the wavevector of maximum spin correlation in the Mott
insulating phase. This, in turn, changes the symmetry of the superconducting
state, that occurs at the boundary of the Mott insulating phase. We propose
that this physics is realised in several families of quasi-two-dimensional
organic superconductors.Comment: To appear in Phys. Rev. Lett. - 5 pages, 4 fig
Interplay of frustration, magnetism, charge ordering, and covalency in a model of Na0.5CoO2
We investigate an effective Hamiltonian for Na0.5CoO2 that includes the
electrostatic potential due to the ordered Na ions and strong electronic
correlations. This model displays a subtle interplay between metallic and
insulating phases and between charge and magnetic order. For realistic
parameters, the model predicts an insulating phase with similarities to a
covalent insulator. We show that this interpretation gives a consistent
explanation of experiments on Na0.5CoO2, including the small degree of charge
ordering, the small charge gap, the large moment, and the optical conductivity.Comment: 5 pages, 4 figures. Text revised making more emphasis on model
properties. Figures compacte
Larval Ecology of Some Lower Michigan Black Flies (Diptera: Simuliidae) With Keys to the Immature Stages
The species composition, succession, and seasonal abundance of -immature simuliids ocmrrhg in the Rose Lake Wildlife Research Area in lower Michigan are presented. Selected physical and chemical characteristics of streams in the above area were examined and compared in relation to faunal distributions. Comparisons of species differences between permanent and temporary streams were made utilizing the functional group concept based on feeding mechanisms.
Keys and illustrations are presented for the identiiication of larvae and pupae of four genera (Prosimulium, Simulium, Stegopterna, Cnephia) and 19 species of Simuliidae known to occur in lower Michigan. Two species, Cnephia ornithophilia and Simulium vemum, were recorded for the first time in Michigan
Spin Fluctuations and the Pseudogap in Organic Superconductors
We show that there are strong similarities in the spin lattice relaxation of
non-magnetic organic charge transfer salts, and that these similarities can be
understood in terms of spin fluctuations. Further, we show that, in all of the
kappa-phase organic superconductors for which there is nuclear magnetic
resonance data, the energy scale for the spin fluctuations coincides with the
energy scale for the pseudogap. This suggests that the pseudogap is caused by
short-range spin correlations. In the weakly frustrated metals
k-(BEDT-TTF)_2Cu[N(CN)_2]Br, k-(BEDT-TTF)_2Cu(NCS)_2, and
k-(BEDT-TTF)_2Cu[N(CN)_2]Cl (under pressure) the pseudogap opens at the same
temperature as coherence emerges in the (intralayer) transport. We argue that
this is because the spin correlations are cut off by the loss of intralayer
coherence at high temperatures. We discuss what might happen to these two
energy scales at high pressures, where the electronic correlations are weaker.
In these weakly frustrated materials the data is well described by the chemical
pressure hypothesis (that anion substitution is equivalent to hydrostatic
pressure). However, we find important differences in the metallic state of
k-(BEDT-TTF)_2Cu_2(CN)_3, which is highly frustrated and displays a spin liquid
insulating phase. We also show that the characteristic temperature scale of the
spin fluctuations in (TMTSF)_2ClO_4 is the same as superconducting critical
temperature, which may be evidence that spin fluctuations mediate the
superconductivity in the Bechgaard salts.Comment: 7 pages, 4 figures; to appear in PR
Sensitivity of the photo-physical properties of organometallic complexes to small chemical changes
We investigate an effective model Hamiltonian for organometallic complexes
that are widely used in optoelectronic devices. The two most important
parameters in the model are , the effective exchange interaction between the
and orbitals of the ligands, and , the renormalized
energy gap between the highest occupied orbitals on the metal and on the
ligand. We find that the degree of metal-to-ligand charge transfer (MLCT)
character of the lowest triplet state is strongly dependent on the ratio
. is purely a property of the complex and can be
changed significantly by even small variations in the complex's chemistry, such
as replacing substituents on the ligands. We find that that small changes in
can cause large changes in the properties of the complex,
including the lifetime of the triplet state and the probability of injected
charges (electrons and holes) forming triplet excitations. These results give
some insight into the observed large changes in the photophysical properties of
organometallic complexes caused by small changes in the ligands.Comment: Accepted for publication in J. Chem. Phys. 14 pages, 9 figures,
Supplementary Info: 15 pages, 17 figure
Effects of Clinostat Rotation on Aurelia Statolith Synthesis
Aurelia ephyrae develop eight graviceptors (rhopalia) during their metamorphosis from polyps, which are used for positional orientation with respect to gravity. In three experiments for each speed of 1/15, 1/8, 1/2, 1, and 24 rpm, groups of six polyps were rotated in the horizontal or vertical plane (control) using clinostats. Other controls were kept stationary in the two planes. Ten ephyrae from each group were collected after 5 to 6 days at 27 C in iodine and the number of statoliths per rhopalium were counted. Statistical analyses of statolith numbers revealed that horizontal clinostat rotation at 1/4 and 1/2 rpm caused the formation of significantly fewer statoliths per rhopalium than were found in controls. The finding that these slow rates of rotation reduces statolith numbers suggests that the developing ephyrae were disoriented with respect to gravity at these speeds, causing fewer statocytes to differentiate or to mineralize
Investigation of passive shock wave-boundary layer control for transonic airfoil drag reduction
The passive drag control concept, consisting of a porous surface with a cavity beneath it, was investigated with a 12-percent-thick circular arc and a 14-percent-thick supercritical airfoil mounted on the test section bottom wall. The porous surface was positioned in the shock wave/boundary layer interaction region. The flow circulating through the porous surface, from the downstream to the upstream of the terminating shock wave location, produced a lambda shock wave system and a pressure decrease in the downstream region minimizing the flow separation. The wake impact pressure data show an appreciably drag reduction with the porous surface at transonic speeds. To determine the optimum size of porosity and cavity, tunnel tests were conducted with different airfoil porosities, cavities and flow Mach numbers. A higher drag reduction was obtained by the 2.5 percent porosity and the 1/4-inch deep cavity
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