311 research outputs found
A star-shaped triphenylamine Ï-conjugated system with internal charge-transfer as donor material for hetero-junction solar cells
Introduction of dicyanovinyl groups on a triphenylamine-based conjugated system leads to an intramolecular charge transfer which extends the spectral response and raises the open-circuit voltage of the resulting hetero-junction solar cells
3D-conjugated systems based on oligothiophenes and phosphorus nodes
3D-conjugated systems based on oligothiophene segments grafted on a phosphorus or on a phosphine oxide node have been synthesized. Under Stille coupling conditions, bromide terminated thienyl phosphine derivatives undergo a breaking of the phosphorusâcarbon bond attributed to a ligand exchange with the Pd catalyst. The electronic properties of the new compounds have been analyzed by UV-vis and fluorescence spectroscopy and cyclic voltammetry
Light-Emitting Organic Solar Cells Based on a 3D Conjugated System with Internal Charge Transfer
Simple single-layered diodes based on a glass-forming triphenylamine-thienylenevinylene with internal charge transfer show a photovoltaic effect in solar light and red electroluminescence when forward biased (see figure and cover). The use of an additional layer of C60 as electron acceptor improves the photovoltaic performance without affecting the electroluminescence
Three-dimensional tetra(oligothienyl)silanes as donor material for organic solar cells
Tetrahedral conjugated systems involving four conjugated oligothiophene chains fixed onto a central silicon node (1, 2) have been synthesized and used as donor materials in hetero-junction solar cells. Bilayer solar cells have been realized by thermal evaporation of compounds1 and 2 as donors and N,NâČ-bis-tridecylperylenedicarboxyimide as an acceptor. Comparison of the performances of these devices to those of a reference system based on dihexylterthienyl (H3T) shows that despite comparable effective conjugation lengths, the 3D compounds 1 and 2lead to a power conversion efficiency fourâfive times higher, suggesting better absorption of the incident light and better hole transport properties. Whereas fabrication of bulk hetero-junction with H3T was prevented by the lack of film forming properties, a prototype bulk hetero-junction based on compound 2 as the donor and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the acceptor has been realized. A short-circuit current density of 1.13 mA cmâ2 and a power conversion efficiency of 0.30% has been measured under AM 1.5 simulated solar irradiation at 80 mW cmâ2
TriphenylamineâThienylenevinylene Hybrid Systems with Internal Charge Transfer as Donor Materials for Heterojunction Solar Cells
Star-shaped molecules based on a triphenylamine core derivatized with various combinations of thienylenevinylene conjugated branches and electron-withdrawing indanedione or dicyanovinyl groups have been synthesized. UVâvis absorption and fluorescence emission data show that the introduction of the electron-acceptor groups induces an intramolecular charge transfer that results in a shift of the absorption onset toward longer wavelengths and a quenching of photoluminescence. Cyclic voltammetry shows that all compounds present a reversible first oxidation process whose potential increases with the number of electron-withdrawing groups in the structure. Prototype bulk and bilayer heterojunction solar cells have been realized using fullerene C60 derivatives as acceptor material. The results obtained with both kinds of devices show that the introduction of electron-acceptor groups in the donor structure induces an extension of the photoresponse in the visible spectral region, an increase of the maximum external quantum efficiency, and an increase of the open-circuit voltage under white light illumination. These synergistic effects allow reaching power conversion efficiencies of âŒ1.20% under simulated AM 1.5 solar irradiation at 100 mW cm-2
TriphenylamineâOligothiophene Conjugated Systems as Organic Semiconductors for Opto-Electronics
Two novel âhybridâ systems consisting of a triphenylamine core carrying Ă°-conjugated terthienyl
branches have been synthesized and characterized by differential scanning calorimetry, X-ray diffraction,
cyclic voltammetry, UV-vis absorption, and fluorescence spectroscopy. The semiconductor potentialities
of these compounds, which lead to glassy or amourphous films, have been evaluated by their
implementation in very simple prototype devices that display electroluminescence at low voltage as well
as a photovoltaic effect. Moreover, field-effect transistors based on one of these novel molecules display
a high hole mobility (1.1 10-2 cm V-1 s-1). These results suggest that molecules leading to amorphous
materials could represent a valid alternative as compared to systems that require control of the molecular
orientation/organizatio
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Pitch perception and production in congenital amusia: evidence from Cantonese speakers
This study investigated pitch perception and production in speech and music in individuals with congenital amusia (a disorder of musical pitch processing) who are native speakers of Cantonese, a tone language with a highly complex tonal system. Sixteen Cantonese-speaking congenital amusics and 16 controls performed a set of lexical tone perception, production, singing, and psychophysical pitch threshold tasks. Their tone production accuracy and singing proficiency were subsequently judged by independent listeners, and subjected to acoustic analyses. Relative to controls, amusics showed impaired discrimination of lexical tones in both speech and non-speech conditions. They also received lower ratings for singing proficiency, producing larger pitch interval deviations and making more pitch interval errors compared to controls. Demonstrating higher pitch direction identification thresholds than controls for both speech syllables and piano tones, amusics nevertheless produced native lexical tones with comparable pitch heights/contours and intelligibility as controls. Significant correlations were found between pitch threshold and lexical tone perception, music perception and production, but not between lexical tone perception and production for amusics. These findings provide further evidence that congenital amusia is domain-general language-independent pitch-processing deficit that is associated with severely impaired music perception and production, mildly impaired speech perception, and largely intact speech production
3,4-Phenylenedioxythiophene (PheDOT): a novel platform for the synthesis of planar substituted pi-donor conjugated systems
3,4-Phenylenedioxythiophene (PheDOT), a benzenic analogue of 3,4-ethylenedioxythiophene (EDOT), has been synthesized using two different routes namely etherification of 2,5-dicarboethoxy-3,4-dihydroxythiophene with halo-aromatics and transetherification of 3,4-dimethoxythiophene with catechols. Quantum calculations and electrochemical measurements show that replacement of the ethylene bridge of EDOT by a phenyl group leads to an increase of the HOMO level and to a stabilization of the cation radical, making electropolymerization of PheDOT more difficult than that of EDOT. The synthesis of several PheDOT derivatives is described together with preliminary results on their electrochemical polymerization and on the properties of the resulting polymers and copolymers
Molecular and supramolecular engineering of Ï-conjugated systems for photovoltaic conversion
Various series of conjugated systems have been used as donor in hetero-junction solar cells. The results obtained with EDOT-containing Ï-conjugated oligomers show that besides their direct effect on the electronic properties of the conjugated chain, the number and position of the EDOT units control to a large extent the orientation of the molecules on the substrate and hence the performances of the derived solar cells. The characteristics of the cells based on oligothienylenevinylenes donors show that in this case structural control of orientation can be achieved by means of substitution of the conjugated structure by alkyl chains.
Donors based on star-shaped oligothiophenes provide another example of control of horizontal molecular orientation by design. The photovoltaic characteristics of bi-layer hetero-junctions show that the combined effects of controlled molecular orientation and planarization of the structure by the use of a fused tri-thienobenzene central core lead to power conversion efficiencies approaching 1%.
In order to avoid the need to control molecular orientation first examples of bulk hetero-junctions based on PCBM and three-dimensional conjugated systems with isotropic electronic properties have been realized. A power conversion efficiency of 0.30% has been obtained under 79 mW cmâ 2 white light illumination. This result obtained with a 3D donor based on a terthiophene conjugated chain with very limited absorption of the visible spectrum demonstrates the large potentialities of this novel concept
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