2 research outputs found
Quantifying Dense Multicomponent Slurries with In-Line ATR-FTIR and Raman Spectroscopies: A Hanford Case Study
The multiphase nature of slurries can make them difficult
to process
and monitor in real time. For example, the nuclear waste slurries
present at the Hanford site in Washington State are multicomponent,
multiphase, and inhomogeneous. Current analytical techniques for analyzing
radioactive waste at Hanford rely on laboratory results from an on-site
analytical laboratory, which can delay processing speed and create
exposure risks for workers. However, in-line probes can provide an
alternative route to collect the necessary composition information.
In the present work, Raman spectroscopy and attenuated total reflectance–Fourier
transform infrared (ATR-FTIR) spectroscopy are tested on simulants
of nuclear waste slurries containing up to 23.2 wt % solids. We observe
ATR-FTIR spectroscopy to be effective in measuring the solution phase
of the studied slurry systems (3.52% mean percent error), while Raman
spectroscopy provides information about the suspended solids in the
slurry system (18.21% mean percent error). In-line measurement of
multicomponent solids typical of nuclear waste processing has been
previously unreported. The composition of both the solution and solid
phases is vital in ensuring stable glass formulation and effective
disposal of nuclear waste at Hanford. Raman and ATR-FTIR spectroscopies
can provide a safer and faster alternative for acquiring compositional
information on nuclear waste slurries
Feedback Control of Multicomponent Salt Crystallization
A closed-loop strategy is developed
for controlling batch cooling
multicomponent crystallization. The strategy represents the sequential
application of two established feedback control techniques: direct
nucleation control followed by supersaturation control. Experimental
results show that such a control scheme produces larger crystals (compared
to linear cooling crystallization with the same batch time). In using
this scheme to control the crystallization of a double salt from a
solution containing sodium nitrate and sodium sulfate, we demonstrate
the application of supersaturation control to a multicomponent salt
crystallizationî—¸which requires knowledge of the solubility
as a function of temperature, the ability to monitor concentrations
in a multicomponent solution, and an appropriate expression for the
driving force for crystallization of a salt. In this paper, a methodology
for rapidly identifying the solubility of a solute in a multicomponent
solution is presented and a new expression for supersaturationî—¸termed
the molar supersaturationî—¸is advanced as a measure of the driving
force for crystallization of salts