Fine-Grained Tb₃Al₅O₁₂ Transparent Ceramics Prepared by Co-Precipitation Synthesis and Two-Step Sintering

In recent years, transparent terbium aluminum garnet (TAG) ceramics have attracted much attention for use in high-power Faraday isolators. Fine-grained ceramics usually possess better mechanical properties and accordingly better service performance. In this work, transparent TAG ceramics with fine grains were prepared using a two-step sintering procedure based on the low-temperature sintering process to suppress grain growth. The composition of TAG precursor and powders calcined at different temperatures was studied in detail. The microstructure and relative density of air pre-sintered TAG ceramics were studied to meet the requirements of hot isostatic pressing (HIP) post-treatment. Driven by the low pre-sintering temperature in air, the average grain sizes of the obtained TAG ceramics after HIP treatment are about 2.9–5.3 μm. The TAG ceramics (1.2 mm thick) pre-sintered at 1450 °C with HIP post-treatment at 1550 °C for 3 h under a 176 MPa Ar atmosphere possess the highest in-line transmittance of 80.3% at 1064 nm. The Verdet constant of the TAG ceramics at 632.8 nm is −180.5 rad·T−1·m−1 at room temperature, which is about 1.3 times larger than that of the commercial Tb3Ga5O12 single crystals

Reactive sintering of highly-doped YAG/Nd3+ :YAG/YAG composite ceramics

Multilayer YAG/Nd3+:YAG/YAG composite laser ceramics were obtained by the reactive sintering in vacuum. The effect of the neodymium ion concentration (1–4 at.%) on the formation of defects and optical quality of composite ceramics was studied. It was found that neodymium ions modify densification kinetics during solid-state reactive sintering of the highly-doped Nd3+:YAG ceramics by decreasing shrinkage rate in the temperature range 1320–1350 °C. Differences in phase transformation kinetics during reactive sintering lead to generation of pores at the interface of adjacent layers which decrease the optical homogeneity of fabricated YAG/Nd3+:YAG/YAG composite ceramics. The influence of layered structure on the laser performance of optical ceramics was investigated. It was shown that the ceramics with multilayer composite architecture have slope efficiency almost twice as the single-layer ceramics with the same composition (22% and 12.5%, respectively)