Analysis of thermal field within an urban canyon with variable thermophysical characteristics of the building's walls.

In a typical urban configuration, a microclimatic analysis has been carried out. Using a CFD method, a N-S oriented urban street canyon, with a given H/W ratio, has been examined. The standard k–ε turbulence model has been used to simulate a three-dimensional flow field and to calculate the thermo-fluid dynamics parameters that characterize the street canyon. In this study has been analyzed the thermal flow field when the walls of the building change the properties of solar radiation absorption, in particular for α=0.2 and α=0.8. Solar radiation considered is that of 21/07 in Milan in two different hours: at 11:00 a.m. and at 02:00 p.m. The study shows the importance of the thermophysical properties of a wall, in the development of the thermal field and flow field. This is a very important topic, in terms of improvement of well-being and the quality of the air within the cities, through the choice of materials and colors of the facades of buildings.

4,4′,4′′-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(1-methylpyridin-1-ium) Iodide

Despite having been known for a long time, quaternary 4,40-bipyridinium salts, or viologens, are still a highly inspiring class of compounds, thanks to their peculiar redox and charge transfer properties. However, more complex structures containing multiple pyridinium rings, also interspaced by conjugated moieties, allow an even wider synthetic variability and tunability of their characteristics. The compound described herein is a star-shaped, fully conjugated molecule with three methylated pyridinium rings connected by a triple bond spacer to a central benzene core, which was synthesized from readily available building blocks, representing a quite simple model of multi-pyridyl extended viologen; its UV–visible absorption and fluorescence spectra have also been investigated

Co-digestion of macroalgae for biogas production: an LCA-based environmental evaluation

Algae represent a favourable and potentially sustainable source of biomass for bioenergy-based industrial pathways in the future. The study, performed on a real pilot plant implemented in Augusta (Italy) within the frame of the BioWALK4Biofuels project, aims to figure out whether seaweed (macroalgae) cultivated in near-shore open ponds could be considered a beneficial aspect as a source of biomass for biogas production within the co-digestion with local agricultural biological waste. The LCA results confirm that the analysed A and B scenarios (namely the algae-based co-digestion scenario and agricultural mix feedstock scenario) present an environmental performance more favourable than that achieved with conventional non-renewable-based technologies (specifically natural gas - Scenario C). Results show that the use of seaweed (Scenario A) represent a feasible solution in order to replace classical biomass used for biofuel production from a land-based feedstock. The improvement of the environmental performances is quantifiable on 10% respect to Scenario B, and 38 times higher than Scenario

Non-Incomes Risk Mitigation Mechanisms for Cultural Heritage: Role of Insurances Facing Covid-19 in the Italian Context

Abstract The economic cultural heritages are exposed to several natural and nowadays biological hazards, which, in addition to causing potential structural damage, can lead to severe loss deriving from financial non-incomes. The paper aims to highlight the role of insurance in mitigating financial damages and losses, specifically explaining the key role of insurance in mitigating biological hazards like Covid-19. The paper is part of broader research by the authors and uses the assumptions and results already obtained previously in the context of the case study relating to the asset of Villa Adriana and Villa D'Este

COVID-19 Effects on Cultural Heritage: The Case of Villa Adriana and Villa D'Este

The paper aims to provide a clarification of assessing insurance risk related to an asset owned by a subject under public law and, more specifically, to an economic cultural asset. This study is aligned with key aspects proposed by the EU for the protection of the cultural heritage from natural disasters. In the first place, given the peculiarity of the material inherent to cultural heritage, a motivation underlies the search for the correlation between the latter and the commonality. Secondly, it appeared necessary to verify the differences, similarities and importance of the economic management of cultural heritage in order to understand the social, economic, material and intangible importance of an asset managed in an economic way within a social axis (municipality). The third reason relates to the general severity and the risk and subsequent damage that a hazard, such as a pandemic outbreak (COVID-19), can cause on one or more cultural heritage. In the final analysis, perhaps the most meaningful aspect underlies the verification of the possible consequences in the analysis of summations of losses generated by a hazard in order to allow a prospect of what could be the consequences of such a catastrophic scenario

Climate change management: a resilience strategy for flood risk using Blockchain tools

This work aims to offer a contribution in the analysis and management, from an economic and financial point of view, of the flood risk, and extended to the hydrogeological risk, from the perspective of a public administration. As main responsible actor for containing the phenomenon through the maintenance of the territory, public administration is responsible for the cost of restoring of the services that have been damaged by this type of phenomenon. The assets of which the public administration must ensure the restoration are all public infrastructures (i.e. transportation, energy and water supply system, communication) together with the damage suffered by private property, if these affect services to be guaranteed to the population. In this work, the authors propose possible strategies that a public administration can put in place to deal with flood risk. Three main strategies are analysed: an absolute passivity that provides for the payment of damages as they occur (i.e. business-as-usual scenario), a classic insurance scheme, a resilient and innovative insurance scheme. The economic–financial profiles of these strategies proposed in this work put an emphasis on how the assumption of a time horizon can change the convenience of one strategy compared to the others. This study highlights the key role of the quantification of flood risk mitigation measure from an engineering perspective, and their potential issues to pursue these objectives in connection to the regulatory framework of the public administrations. This synergy is supported by the potential use of Blockchain-based tools. Within the paper is highlighted the key role that such platform IT data management platform could have within risk analysis and management schemes, both as a data collection tool and as certification of the various steps necessary to complete the process

algae based biorefinery concept an lci analysis for a theoretical plant

Abstract Both micro and macro algae have a potential to be a valuable feedstock for biorefineries. The theoretical impact assessment of this kind of plant can be carried out through an LCA, which is a key tool in order to evaluate the potential environmental impact of a process throughout its entire life cycle. Hence, it is a priority to perform an LCI with the aim of gathering all the data and simulating all the unit process of a theoretical biorefinery. The Inventory ensures to obtain a simple and immediate way to represent several aspects of a biorefinery, e.g. productivity, environmental pressures, required resources in terms of raw materials and energy. One of the main aspects clearly shown in this study is the significant environmental pressures due to the cultivation and harvesting steps, for which it is desirable to consider a biomass collection from the environment, especially from areas where eutrophication phenomena are particularly recurrent. Another conclusion drawn from the study is that the total plant production per year appears very limited, if compared to any conventional refinery. The following approach can also provide a starting data set to perform a first approximate economic analysis of the costs/gains of the outlined project, and it could be used as a first concept design for the project development of a real plant

Assessment of trabecular bone score (TBS) in overweight/obese men: effect of metabolic and anthropometric factors

The "trabecular bone score" (TBS) indirectly explores bone quality, independently of bone mineral density (BMD). We investigated the effects of anthropometric and metabolic parameters on TBS in 87 overweight/obese men. We assessed BMD and TBS by DXA, and some parameters of glucose metabolism, sex-and calciotropic hormone levels. Regression models were adjusted for either age and BMI, or age and waist circumference, or age and waist/hip ratio, also considering BMI >35 (y/n) and metabolic syndrome (MS) (y/n). Correlations between TBS and parameters studied were higher when correcting for waist circumference, although not significant in subjects with BMI >35. The analysis of covariance showed that the same model always had a higher adjusted r-square index. BMD at lumbar spine and total hip, fasting glucose, bioavailable testosterone, and sex hormone-binding globulin are the only covariates having a significant effect (p 35 on TBS values or significant interaction terms between each covariate and either BMI >35 or the presence of MS. Obesity negatively affected TBS, despite unchanged BMD. Alterations of glucose homeostasis and sex hormone levels seem to influence this relationship, while calciotropic hormones have no role. The effect of waist circumference on TBS is more pronounced than that of BMI

From a distinctive sign to an exchangeable asset: exploring the U.S. market for trademark licensing

A remarkable growth in the value of trademark licensing has been recently recorded. Our paper contributes to the understanding of this under-explored phenomenon using a dataset newly released by the USPTO. Our study analyses the evolution of licensing activities in the U.S. during the 2003-2017 period, the characteristics of these trademarks and agreements, and certain features of the licensing parties involved. We found that licensing activities varied considerably during these years. They were usually signed between two parties only, and, on average, they involved more than one trademark. Excluding under-reporting effect, the analyses reveal that a large portion of heterogeneity in licensing activity is due to the NICE international classes associated with each trademark. Indeed, trademark licensing agreements appear to be unevenly distributed across these classes, suggesting that this activity and the way it is carried out is correlated with the market to which the licensed trademark refers