17,693 research outputs found
Impurity crystal in a Bose-Einstein condensate
We investigate the behavior of impurity fields immersed in a larger
condensate field in 1, 2, and 3 dimensions. We discuss the localization of a
single impurity field within a condensate and note the effects of surface
energy. We derive the functional form of the attractive interaction between two
impurities due to mediation from the condensate. Generalizing the analysis to
impurity fields, we show that within various parameter regimes a crystal of
impurity fields can form spontaneously in the condensate. Finally, the system
of condensate and crystallized impurity structure is shown to have nonclassical
rotational inertia, which is characteristic of superfluidity, i.e. the system
can be seen to exhibit supersolid behavior.Comment: 5 pages, 3 color figures; Accepted to Phys. Rev. Let
Cold-water coral reef frameworks, megafaunal communities and evidence for coral carbonate mounds on the Hatton Bank, north east Atlantic
Offshore banks and seamounts sustain diverse megafaunal communities, including framework reefs formed by cold-water corals. Few studies have quantified environmental effects on the alpha or beta diversity of these communities. We adopted an interdisciplinary approach that used historical geophysical data to identify topographic highs on Hatton Bank, which were surveyed visually. The resulting photographic data were used to examine relationships between megafaunal communities and macrohabitat, the latter defined into six categories (mud, sand, cobbles, coral rubble, coral framework, rock). The survey stations revealed considerable small-scale variability in macrohabitat from exposed Late Palaeocene lava flows to quiescent muddy habitats and coral-built carbonate mounds. The first reported evidence for coral carbonate mound development in UK waters is presented, which was most pronounced near present-day or former sites of topographic change, suggesting that local current acceleration favoured coral framework growth and mound initiation. Alpha diversity varied significantly across macrohabitats, but not between rock and coral rubble, or between smaller grain sized categories of cobbles, sand and mud. Community composition differed between most macrohabitats, and variation in beta diversity across Hatton Bank was largely explained by fine-scale substratum. Certain megafauna were clearly associated with particular macrohabitats, with stylasterid corals notably associated with cobble and rock habitats and coral habitats characterized by a diverse community of suspension-feeders. The visual surveys also produced novel images of deep-water megafauna including a new photographic record of the gorgonian coral Paragorgia arborea, a species not previously reported from Rockall Plateau. Further interdisciplinary studies are needed to interpret beta diversity across these and other environmental gradients on Hatton Bank. It is clear that efforts are also needed to improve our understanding of the genetic connectivity and biogeography of vulnerable deep-water ecosystems and to develop predictive models of their occurrence that can help inform future conservation measures
Time-resolved velocity map imaging of methyl elimination from photoexcited anisole
To date, H-atom elimination from heteroaromatic molecules following UV excitation has been extensively studied, with the focus on key biological molecules such as chromophores of DNA bases and amino acids. Extending these studies to look at elimination of other non-hydride photoproducts is essential in creating a more complete picture of the photochemistry of these biomolecules in the gas-phase. To this effect, CH3 elimination in anisole has been studied using time resolved velocity map imaging (TR-VMI) for the first time, providing both time and energy information on the dynamics following photoexcitation at 200 nm. The extra dimension of energy afforded by these measurements has enabled us to address the role of πσ* states in the excited state dynamics of anisole as compared to the hydride counterpart (phenol), providing strong evidence to suggest that only CH3 fragments eliminated with high kinetic energy are due to direct dissociation involving a 1πσ* state. These measurements also suggest that indirect mechanisms such as statistical unimolecular decay could be contributing to the dynamics at much longer times
Quantum-mechanical calculations of the stabilities of fluxional isomers of C_4H_7^+ in solution
Although numerous quantum calculations have been made over the years of the stabilities of the fluxional isomers of C4H7+, none have been reported for other than the gas phase (which is unrealistic for these ionic species) that exhibit exceptional fluxional properties in solution. To be sure, quantum-mechanical calculations for solutions are subject to substantial uncertainties, but nonetheless it is important to see whether the trends seen for the gas-phase C4H7+ species are also found in calculations for polar solutions. Of the C4H7+ species, commonly designated bisected-cyclopropylcarbinyl 1, unsym-bicyclobutonium-2, sym-bicyclobutonium 3, allylcarbinyl 4, and pyramidal structure 6, the most advanced gas-phase calculations available thus far suggest that the order of stability is 1 ≥ 2 ≥ 3 >> 4 >> 6 with barriers of only ~1 kcal/mol for interconversions among 1, 2, and 3. We report here that, when account is taken of solvation, 2 turns out to be slightly more stable than 1 or 3 in polar solvents. The pattern of the overall results is unexpected, in that despite substantial differences in structures and charge distributions between the primary players in the C4H7+ equilibria and the large differences in solvation energies calculated for the solvents considered, the differential solvent effects from species to species are rather small
Toward Modernization: Using Strategic Development to Address Deficits in the Juvenile Justice System
The Juvenile Justice System was established on the premise of rehabilitative action for behaviors that have led youth to the criminal justice system. However, the system has increasingly moved away from this original concept toward a punitive model. The authors present how this movement resulted in the devolution of human rights for the youth involved, a decrease in public safety, and a radical departure from fiscal responsibility related to the theoretical origins of rehabilitation. Studies on topics ranging from costs of correctional centers to trauma experienced by youth in these systems, along with many others, are compared to identify specific areas for renovation. Evidence-based pathways are presented to address these concerns along with pragmatic strategies for utilization of a constructed theory focused on the relationship between diversionary policies, attrition, and growth through the reinvestment of existing resources
Exact solution of an infinite-range, non-collective dissipative transverse-field Ising model
The dissipative variant of the Ising model in a transverse field is one of
the most important models in the analysis of open quantum many-body systems,
due to its paradigmatic character for understanding driven-dissipative quantum
phase transitions, as well as its relevance in modelling diverse experimental
platforms in atomic physics and quantum simulation. Here, we present an exact
solution for the steady state of the transverse-field Ising model in the limit
of infinite-range interactions, with local dissipation and inhomogeneous
transverse fields. Our solution holds despite the lack of any collective spin
symmetry or even permutation symmetry. It allows us to investigate first- and
second-order dissipative phase transitions, driven-dissipative criticality, and
captures the emergence of a surprising ``spin blockade" phenomenon. The ability
of the solution to describe spatially-varying local fields provides a new tool
to study disordered open quantum systems in regimes that would be extremely
difficult to treat with numerical methods.Comment: 15 pages (including appendices), 3 figure
Intrapartum epidural analgesia and breastfeeding: a prospective cohort study
BACKGROUND Anecdotal reports suggest that the addition of fentanyl (an opioid) to epidural analgesia for women during childbirth results in difficulty establishing breastfeeding. The aim of this paper is to determine any association between epidural analgesia and 1) breastfeeding in the first week postpartum and 2) breastfeeding cessation during the first 24 weeks postpartum. METHODS A prospective cohort study of 1280 women aged > or = 16 years, who gave birth to a single live infant in the Australian Capital Territory in 1997 was conducted. Women completed questionnaires at weeks 1, 8, 16 and 24 postpartum. Breastfeeding information was collected in each of the four surveys and women were categorised as either fully breastfeeding, partially breastfeeding or not breastfeeding at all. Women who had stopped breastfeeding since the previous survey were asked when they stopped. RESULTS In the first week postpartum, 93% of women were either fully or partially breastfeeding their baby and 60% were continuing to breastfeed at 24 weeks. Intrapartum analgesia and type of birth were associated with partial breastfeeding and breastfeeding difficulties in the first postpartum week (p < 0.0001). Analgesia, maternal age and education were associated with breastfeeding cessation in the first 24 weeks (p < 0.0001), with women who had epidurals being more likely to stop breastfeeding than women who used non-pharmacological methods of pain relief (adjusted hazard ratio 2.02, 95% CI 1.53, 2.67). CONCLUSION Women in this cohort who had epidurals were less likely to fully breastfeed their infant in the few days after birth and more likely to stop breastfeeding in the first 24 weeks. Although this relationship may not be causal, it is important that women at higher risk of breastfeeding cessation are provided with adequate breastfeeding assistance and support.Christine Roberts is supported by a National Health and Medical
Research Council (NHMRC) of Australia Public Health Practitioner Fellowship
and Siranda Torvaldsen is supported by a NHMRC Australian Research
Training Fellowship. The cohort study was supported by a project grant
from The Canberra Hospital Private Practice Fund. Additional funding was
provided by The Canberra Hospital Auxiliary, the Nurses' Board of the
Australian Capital Territory, and the Australian Capital Territory Department
of Health & Community Care
Unconditional Fock state generation using arbitrarily weak photonic nonlinearities
We present a new mechanism that harnesses extremely weak Kerr-type
nonlinearities in a single driven cavity to deterministically generate single
photon Fock states, and more general photon-blockaded states. Our method is
effective even for nonlinearities that are orders-of-magnitude smaller than
photonic loss. It is also completely distinct from so-called unconventional
photon blockade mechanisms, as the generated states are non-Gaussian, exhibit a
sharp cut-off in their photon number distribution, and can be arbitrary close
to a single-photon Fock state. Our ideas require only standard linear and
parametric drives, and is hence compatible with a variety of different photonic
platforms.Comment: 10 pages, 6 figure
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