MATERIALS FOR AUTOMOTIVE INDUSTRY AND THEIR INFLUENCE ON THE DYNAMICS OF A CAR CRASH

The aim of this research was to determine the influence of the metallic materials characteristics on the dynamics of a car crash. Another important aspect is that the metallic parts are sometimes repaired after minor accidents and this fact influence strongly the mechanical characteristics and their influence on the dynamics of a car crash. In this paper, we analyze the mechanical characteristics of thin steel plates repaired by local heating associated with plastic deformation (similar to hot working) and cold straightening (similar to local cold working) for automotive side and door panels made of structural steel. Thin sheet plates, 0.9mm thickness, were deformed by impact and repaired by local heating using the flame and induction heating then plastically deformed while hot as well as straightened without heating. The heat repaired samples were studied by light microscopy to determine microstructure change and samples were tensile tested to determine their mechanical characteristics. Local excessive grain growth generates anisotropy, the assembly behaves as a composite material with regions that show significant plastic deformations while others little or no deformations at all. Without procedures adjusted to each material repairs involving heating are to be avoided, cold working should be employed when replacement is not possible

MATERIALS FOR AUTOMOTIVE INDUSTRY AND THEIR INFLUENCE ON THE DYNAMICS OF A CAR CRASH

The aim of this research was to determine the influence of the metallic materials characteristics on the dynamics of a car crash. Another important aspect is that the metallic parts are sometimes repaired after minor accidents and this fact influence strongly the mechanical characteristics and their influence on the dynamics of a car crash. In this paper, we analyze the mechanical characteristics of thin steel plates repaired by local heating associated with plastic deformation (similar to hot working) and cold straightening (similar to local cold working) for automotive side and door panels made of structural steel. Thin sheet plates, 0.9mm thickness, were deformed by impact and repaired by local heating using the flame and induction heating then plastically deformed while hot as well as straightened without heating. The heat repaired samples were studied by light microscopy to determine microstructure change and samples were tensile tested to determine their mechanical characteristics. Local excessive grain growth generates anisotropy, the assembly behaves as a composite material with regions that show significant plastic deformations while others little or no deformations at all. Without procedures adjusted to each material repairs involving heating are to be avoided, cold working should be employed when replacement is not possible

Biomimetic Calcium Phosphates Derived from Marine and Land Bioresources

This chapter aims to establish the key factors for technological optimization of biogenic calcium phosphate synthesis from marine and land resources. Three natural calcium sources—marble, seashell and bovine bone—were considered as raw materials. The proposed materials are suitable candidates for the synthesis of bone substitutes similar to the inorganic bone component. The synthesis processes were developed based on the investigations of thermal phenomena (TGA-DSC analysis) that can occur during thermal treatments. By this method, we were able to determine the optimum routes and temperatures for the complete dissociation of calcium carbonate as well as risk-free deproteinization of bovine bone. An exhaustive characterization, performed with modern and complementary techniques such as morphology (SEM), composition (EDS, XRF) and structure (FT-IR, XRD), is presented for each precursor. The final chemical composition of ceramic products can be modulated through a careful control of the key parameters involved in the conversion, in order to create long-term performant biphasic apatite biomaterials, with broad medical applicability. Identifying the suitable strategies for this modulation contributes to an appreciable advance in orthopedic tissue engineering

Synthesis and characterization of jellified composites form bovine bone-derived hydroxyapatite and starch as precursors for robocasting

Hydroxyapatite–starch composites solidify rapidly via jellification, making them suitable candidates for robocasting. However, many aspects related to hydroxyapatite powder characteristics, hydroxyapatite–starch interaction, and composites composition and properties need to be aligned with robocasting requirements to achieve a notable improvement in the functionality of printed scaffolds intended for bone regeneration. This article presents a preliminary evaluation of hydroxyapatite–starch microcomposites. Thermal analysis of the starting powders was performed for predicting composites’ behavior during heat-induced densification. Also, morphology, mechanical properties, and hydroxyapatite–starch interaction were evaluated for the jellified composites and the porous bodies obtained after conventional sintering, for different starch additions, and for ceramic particle size distributions. The results indicate that starch could be used for hydroxyapatite consolidation in limited quantities, whereas the composites shall be processed under controlled temperature. Due to a different mechanical behavior induced by particle size and geometry, a wide particle size distribution of hydroxyapatite powder is recommended for further robocasting ink development

Fire Behavior and Adhesion of Magnesium Phosphate Coatings for the Protection of Steel Structures

This paper presents the main properties of magnesium phosphate cements (MPCs) to be used as coatings for passive fire protection of steel structures. The influence of various additions, i.e., waste glass powder, fly ash, a styrene–acrylic dispersion, and expandable graphite, on the fire behavior and the adhesion to steel substrates of magnesium phosphate coatings is presented in this paper. The setting time of studied cements is extended when magnesia, the main component of MPCs, is partially replaced with fly ash or/and waste glass powder. The mineralogical composition of these cements, before and after thermal treatment at 1050 °C, was assessed by X-ray diffraction and could explain the changes in compressive strength, volume, and mass recorded for the thermally treated specimens. The studied magnesium phosphate coatings have a good adherence to the steel substrate (assessed by a pull-off test) both before and after direct contact with a flame (fire test) and decrease the temperature of the steel substrate by 30% with respect to the one recorded for the uncoated steel plate

Fire Behavior and Adhesion of Magnesium Phosphate Coatings for the Protection of Steel Structures

This paper presents the main properties of magnesium phosphate cements (MPCs) to be used as coatings for passive fire protection of steel structures. The influence of various additions, i.e., waste glass powder, fly ash, a styrene–acrylic dispersion, and expandable graphite, on the fire behavior and the adhesion to steel substrates of magnesium phosphate coatings is presented in this paper. The setting time of studied cements is extended when magnesia, the main component of MPCs, is partially replaced with fly ash or/and waste glass powder. The mineralogical composition of these cements, before and after thermal treatment at 1050 °C, was assessed by X-ray diffraction and could explain the changes in compressive strength, volume, and mass recorded for the thermally treated specimens. The studied magnesium phosphate coatings have a good adherence to the steel substrate (assessed by a pull-off test) both before and after direct contact with a flame (fire test) and decrease the temperature of the steel substrate by 30% with respect to the one recorded for the uncoated steel plate

Preliminary Studies on Graphene-Reinforced 3D Products Obtained by the One-Stage Sacrificial Template Method for Bone Reconstruction Applications

The bone remodeling field has shifted focus towards the delineation of products with two main critical attributes: internal architectures capable to promote fast cell colonization and good mechanical performance. In this paper, Luffa-fibers and graphene nanoplatelets were proposed as porogen template and mechanical reinforcing agent, respectively, in view of framing 3D products by a one-stage polymer-free process. The ceramic matrix was prepared through a reproducible technology, developed for the conversion of marble resources into calcium phosphates (CaP) powders. After the graphene incorporation (by mechanical and ultrasonication mixing) into the CaP matrix, and Luffa-fibers addition, the samples were evaluated in both as-admixed and thermally-treated form (compact/porous products) by complementary structural, morphological, and compositional techniques. The results confirmed the benefits of the two agents’ addition upon the compact products’ micro-porosity and the global mechanical features, inferred by compressive strength and elastic modulus determinations. For the porous products, overall optimal results were obtained at a graphene amount of <1 wt.%. Further, no influence of graphene on fibers’ ability to generate at high temperatures internal interconnected-channels-arrays was depicted. Moreover, its incorporation led to a general preservation of structural composition and stability for both the as-admixed and thermally-treated products. The developed CaP-reinforced structures sustain the premises for prospective non- and load-bearing biomedical applications

Bone Cements Used for Hip Prosthesis Fixation: The Influence of the Handling Procedures on Functional Properties Observed during In Vitro Study

The failure of hip prostheses is a problem that requires further investigation and analysis. Although total hip replacement is an extremely successful operation, the number of revision surgeries needed after this procedure is expected to continue to increase due to issues with both bone cement types and cementation techniques (depending on the producer). To conduct a comparative analysis, as a surgeon prepared the bone cement and introduced it in the body, this study’s team of researchers prepared three types of commercial bone cements with the samples mixed and placed them in specimens, following the timeline of the surgery. In order to evaluate the factors that influenced the chemical composition and structure of each bone cement sample under specific intraoperative conditions, analyses of the handling properties, mechanical properties, structure, and composition were carried out. The results show that poor handling can impede prosthesis–cement interface efficacy over time. Therefore, it is recommended that manual mixing be avoided as much as possible, as the manual preparation of the cement can sometimes lead to structural unevenness

MECHANICAL BEHAVIOUR OF THREE-UNIT ZIRCONIA INFRASTRUCTURES WITH MODIFIED COPINGS

Aim of the study The purpose of this in vitro study was to analyse the influence of various types zirconia copings on flexural strength of zirconia frameworks designated for posterior tooth-supported fixed dental prostheses. Materials and methods Zirconia samples (Pre-sintered Zirconia, 3Y-TZP, NOVAZir® ST, Novadent, Hamburg, Germany) were designed as three-unit bridge infrastructures, replacing the first right lower molar. The samples (n=4) were divided into two testing groups: the first group included two samples with copings having even thickness of 0.6mm (coded P1 and P2), and second group (coded P3 and P4) comprised modified copings with thickness varying from 0.80-0.84mm in specific occlusal-axial areas. The cross sectional area of all connectors was established at 9mm² with an elliptical shape. Mechanical tests (three-point flexural tests) were conducted on all samples using a universal testing machine. Results The evaluation of zirconia samples’ mechanical behaviour revealed group-depended differences: zirconia samples with modified copings demonstrated higher flexural strength in the applied mechanical tests (0.894kN for P3 and 1.109kN for P4) compared to zirconia samples with even coping thickness (0.561kN for P1 and 0.772kN for P2). Conclusions Modified zirconia copings have shown potential as an alternative to enhance the flexural strength of zirconia infrastructures, and could provide a more suitable support and an even thickness for veneering ceramic

Biocompatible Composite Filaments Printable by Fused Deposition Modelling Technique: Selection of Tuning Parameters by Influence of Biogenic Hydroxyapatite and Graphene Nanoplatelets Ratios

The proposed strategy for the extrusion of printable composite filaments follows the favourable association of biogenic hydroxyapatite (HA) and graphene nanoplatelets (GNP) as reinforcement materials for a poly(lactic acid) (PLA) matrix. HA particles were chosen in the <40 μm range, while GNP were selected in the micrometric range. During the melt–mixing incorporation into the PLA matrix, both reinforcement ratios were simultaneously modulated for the first time at different increments. Cylindrical composite pellets/test samples were obtained only for the mechanical and wettability behaviour evaluation. The Fourier-transformed infrared spectroscopy depicted two levels of overlapping structures due to the solid molecular bond between all materials. Scanning electron microscopy and surface wettability and mechanical evaluations vouched for the (1) uniform/homogenous dispersion/embedding of HA particles up to the highest HA/GNP ratio, (2) physical adhesion at the HA-PLA interface due to the HA particles’ porosity, (3) HA-GNP bonding, and (4) PLA-GNP synergy based on GNP complete exfoliation and dispersion into the matrix