Structural, electronic, and chemical properties of multiply iodized aluminum clusters

The electronic structure, stability, and reactivity of iodized aluminum clusters, which have been investigated via reactivity studies, are examined by first-principles gradient corrected density functional calculations. The observed behavior of Al13I−x and Al14I−x clusters is shown to indicate that for x⩽8, they consist of compact Al−13 and Al++14 cores, respectively, demonstrating that they behave as halogen- or alkaline earthlike superatoms. For x\u3e8, the Al cores assume a cagelike structure associated with the charging of the cores. The observed mass spectra of the reacted clusters reveal that Al13I−x species are more stable for even x while Al14I−x exhibit enhanced stability for odd x(x⩾3). It is shown that these observations are linked to the formation and filling of “active sites,” demonstrating a novel chemistry of superatoms

A quantum mechanical description of the experiment on the observation of gravitationally bound states

Quantum states in the Earth's gravitational field were observed, when ultra-cold neutrons fall under gravity. The experimental results can be described by the quantum mechanical scattering model as it is presented here. We also discuss other geometries of the experimental setup which correspond to the absence or the reversion of gravity. Since our quantum mechanical model describes, particularly, the experimentally realized situation of reversed gravity quantitatively, we can practically rule out alternative explanations of the quantum states in terms of pure confinement effects.Comment: LaTeX, 10 pages, 4 figures, v2: references adde

Composition, Morphology, and Stratigraphy of Noachian Crust around the Isidis basin

Definitive exposures of pristine, ancient crust on Mars are rare, and the finding that much of the ancient Noachian terrain on Mars exhibits evidence of phyllosilicate alteration adds further complexity. We have analyzed high-resolution data from the Mars Reconnaissance Orbiter in the well-exposed Noachian crust surrounding the Isidis basin. We focus on data from the Compact Reconnaissance Imaging Spectrometer for Mars as well as imaging data sets from High Resolution Imagine Science Experiment and Context Imager. These data show the lowermost unit of Noachian crust in this region is a complex, brecciated unit of diverse compositions. Breccia blocks consisting of unaltered mafic rocks together with rocks showing signatures of Fe/Mg-phyllosilicates are commonly observed. In regions of good exposure, layered or banded phyllosilicate-bearing breccia rocks are observed suggestive of pre-Isidis sedimentary deposits. In places, the phyllosilicate-bearing material appears as a matrix surrounding mafic blocks, and the mafic rocks show evidence of complex folded relationships possibly formed in the turbulent flow during emplacement of basin-scale ejecta. These materials likely include both pre-Isidis basement rocks as well as the brecciated products of the Isidis basin–forming event at 3.9 Ga. A banded olivine unit capped by a mafic unit covers a large topographic and geographic range from northwest of Nili Fossae to the southern edge of the Isidis basin. This olivine-mafic cap combination superimposes the phyllosilicate-bearing basement rocks and distinctly conforms to the underlying basement topography. This may be due to draping of the topography by a fluid or tectonic deformation of a previously flatter lying morphology. We interpret the draping, superposed olivine-mafic cap combination to be impact melt from the Isidis basin–forming event. While some distinct post-Isidis alteration is evident (carbonate, kaolinite, and serpentine), the persistence of olivine from the time of Isidis basin suggests that large-scale aqueous alteration processes had ceased by the time this unit was emplaced

Ohio Economic Insects and Related Anthropods

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Discovery of the Acoustic Faraday Effect in Superfluid 3He-B

We report the discovery of the acoustic Faraday effect in superfluid 3He-B. The observation of this effect provides the first direct evidence for propagating transverse acoustic waves in liquid 3He, a mode first predicted by Landau in 1957. The Faraday rotation is large and observable because of spontaneously broken spin-orbit symmetry in 3He-B. We compare the experimental observations with a simulation of the transverse acoustic impedance that includes the field-induced circular birefringence of transverse waves.Comment: 4 pages in RevTex plus 3 postscript figures; new version includes: minor corrections to the text and an updated of list of reference

Rhythm in the speech of a person with right hemisphere damage: Applying the pairwise variability index

Although several aspects of prosody have been studied in speakers with right hemisphere damage (RHD), rhythm remains largely uninvestigated. This study compares the rhythm of an Australian English speaker with right hemisphere damage (due to a stroke, but with no concomitant dysarthria) to that of a neurologically unimpaired individual. The speakers' rhythm is compared using the pairwise variability index (PVI) which allows for an acoustic characterization of rhythm by comparing the duration of successive vocalic and intervocalic intervals. A sample of speech from a structured interview between a speech and language therapist and each participant was analysed. Previous research has shown that speakers with RHD may have difficulties with intonation production, and therefore it was hypothesized that there may also be rhythmic disturbance. Results show that the neurologically normal control uses a similar rhythm to that reported for British English (there are no previous studies available for Australian English), whilst the speaker with RHD produces speech with a less strongly stress-timed rhythm. This finding was statistically significant for the intervocalic intervals measured (t(8) = 4.7, p < .01), and suggests that some aspects of prosody may be right lateralized for this speaker. The findings are discussed in relation to previous findings of dysprosody in RHD populations, and in relation to syllable-timed speech of people with other neurological conditions