5 research outputs found
Excitation Energy Dependent Ultrafast Luminescence Behavior of CdS Nanostructures
Selected
semiconductor nanostructures provide extremely localized
coherent light sources. Here an ensemble of CdS nanostructures was
excited by UV/vis femtosecond laser pulses and their ultrafast luminescence
characteristics were investigated as functions of the pulse energy
fluence and the photon quantum energy. All optical Kerr gating enabled
studies of the emission dynamics with a time resolution of 150 fs
avoiding any influence on the CdS emission. The initially observed
emission built up after a delay of 0.1ā3 ps and decayed rapidly
in a biexponential way, strongly dependent on both the laser energy
fluence and the quantum energy. The central wavelength of the emission
spectrum revealed a significant blue-shift within the first few ps
followed by a transient red-shift relative to spontaneous excitonic
emission of CdS. All findings are mainly attributed to stimulated
radiative carrier recombination in the laser excited electronāhole
plasma after its thermalization with the CdS lattice
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Triplet-Encoded Prebiotic RNA Aminoacylation
The encoding step of translation involves attachment of amino acids to cognate tRNAs by aminoacyl-tRNA synthetases, themselves the product of coded peptide synthesis. So, the question arisesbefore these enzymes evolved, how were primordial tRNAs selectively aminoacylated? Here, we demonstrate enzyme-free, sequence-dependent, chemoselective aminoacylation of RNA. We investigated two potentially prebiotic routes to aminoacyl-tRNA acceptor stem-overhang mimics and analyzed those oligonucleotides undergoing the most efficient aminoacylation. Overhang sequences do not significantly influence the chemoselectivity of aminoacylation by either route. For aminoacyl-transfer from a mixed anhydride donor strand, the chemoselectivity and stereoselectivity of aminoacylation depend on the terminal three base pairs of the stem. The results support early suggestions of a second genetic code in the acceptor stem
Spectroscopic Characterization of Rocksalt-Type Aluminum Nitride
Starting from nanocrystalline and
submicron wurtzite-aluminum nitride (w-AlN) powder rocksalt structure
(rs-AlN) samples were synthesized by two different methods of shock
wave recovery experiments. The resulting samples contained up to 86%
rs-AlN, stable at room temperature, giving for the first time the
possibility to comprehensively characterize the material by powder
X-ray diffraction, Fourier transform infrared (IR), Raman, and <sup>27</sup>Al NMR spectroscopy. Raman and IR modes were calculated by
density functional theory, allowing for the interpretation of the
respective experimental spectra. By <sup>27</sup>Al NMR the chemical
shift of rs-AlN was determined, and the quadrupolar coupling constant
was estimated