Amorphization of Cu nanoparticles: effects on surface plasmon resonance

Crystalline copper nanoparticles (NPs) were formed in silica by multi-energy MeV ion implantations and then transformed to amorphous NPs by irradiation with 5 MeV Sn3+ ions. Optical absorptionspectra of both the phases were evaluated in the ultra-violet to near-infrared regions. Compared with corresponding crystalline NPs of the same mean diameter, the amorphous NPs showed a low-energy shift of the surface plasmon resonance around 2.2 eV and less prominent absorptionstructure around 4 eV. These differences are explained by a strongly reduced electron mean-free-path in the amorphous NPs due to the loss of lattice periodicity

Direct observation of substitutional Ga after ion implantation in Ge by means of extended x-ray absorption fine structure

We present an experimental lattice location study of Ga atoms in Ge after ion implantation at elevated temperature (250°C). Using extended x-rayabsorption fine structure (EXAFS) experiments and a dedicated sample preparation method, we have studied the lattice location of Ga atoms in Ge with a concentration ranging from 0.5 at. % down to 0.005 at. %. At Ga concentrations ≤0.05 at.%, all Ga dopants are substitutional directly after ion implantation, without the need for post-implantation thermal annealing. At higher Ga concentrations, a reduction in the EXAFS amplitude is observed, indicating that a fraction of the Ga atoms is located in a defective environment. The local strain induced by the Ga atoms in the Ge matrix is independent of the Ga concentration and extends only to the first nearest neighbor Ge shell, where a 1% contraction in bond length has been measured, in agreement with density functional theory calculations.We acknowledge the support from the Research Foundation Flanders, the epi-team from imec, the KU Leuven GOA 09/06 project, the IUAP program P6/42 and the Australian Research Council. S.C. acknowledges support from OCAS NV by an OCAS-endowed chair at Ghent University

Static Black Hole Solutions without Rotational Symmetry

We construct static black hole solutions that have no rotational symmetry. These arise in theories, including the standard electroweak model, that include charged vector mesons with mass $m\ne 0$. In such theories, a magnetically charged Reissner-Nordstrom black hole with horizon radius less than a critical value of the order of $m^{-1}$ is classically unstable against the development of a nonzero vector meson field just outside the horizon, indicating the existence of static black hole solutions with vector meson hair. For the case of unit magnetic charge, spherically symmetric solutions of this type have previously been studied. For other values of the magnetic charge, general arguments show that any new solution with hair cannot be spherically symmetric. In this paper we develop and apply a perturbative scheme (which may have applicability in other contexts) for constructing such solutions in the case where the Reissner-Nordstrom solution is just barely unstable. For a few low values of the magnetic charge the black holes retain a rotational symmetry about a single axis, but this axial symmetry disappears for higher charges. While the vector meson fields vanish exponentially fast at distances greater than $O(m^{-1})$, the magnetic field and the metric have higher multipole components that decrease only as powers of the distance from the black hole.Comment: 42 pages, phyzzx. 4 figures (PostScript, 1.7 MB when uncompressed) available by email from the Authors on reques

A polarographic method for following the rates of cholinesterase-catalyzed hydrolyses of acetylthiocholine

A rapid and simple polarographic method for following the rates of the cholinesterase-catalyzed hydrolysis of acetylthiocholine and the rates of inhibition of this hydrolysis is described. This method has the advantage that it can follow quite rapid reactions, as meaningful data can be obtained after 10 sec of mixing of the solutions. The method follows the rate of increase of the anodic polarographic wave of thiocholine produced by the hydrolysis. The validity of the method was determined by comparing the rates of production of thiocholine spectrophotometrically and polarographically. Also the values of Km for the hydrolysis, and Km and K1 for the inhibition reaction of neostigmine were determined and compared to values reported in the literature.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/31994/1/0000036.pd

Identification of SH Δv=1\Delta v=1 ro-vibrational lines in R And

We report the identification of SH $\Delta v=1$ ro-vibrational lines in the published high-resolution infrared spectrum of the S-type star, R And. This is the first astronomical detection of this molecule. The lines show inverse P-Cygni profiles, indicating infall motion of the molecular layer due to stellar pulsation. A simple spherical shell model with a constant infall velocity is adopted to determine the condition of the layer. It is found that a single excitation temperature of 2200 K reproduces the observed line intensities satisfactory. SH is located in a layer from 1.0 to ~1.1 stellar radii, which is moving inward with a velocity of 9 km s-1. These results are consistent with the previous measurements of CO $\Delta v=3$ transitions. The estimated molecular abundance SH/H is 1x10^-7, consistent with a thermal equilibrium calculation.Comment: 10 pages, 2 figures. Accepted for publication in ApJ Letter

Static Axially Symmetric Solutions of Einstein-Yang-Mills-Dilaton Theory

We construct static axially symmetric solutions of SU(2) Einstein-Yang-Mills-dilaton theory. Like their spherically symmetric counterparts, these solutions are nonsingular and asymptotically flat. The solutions are characterized by the winding number n and the node number k of the gauge field functions. For fixed n with increasing k the solutions tend to ``extremal'' Einstein-Maxwell-dilaton black holes with n units of magnetic charge.Comment: 11 pages, including 2 postscript figure

Electronic properties of (Ga,Mn)N thin films with high Mn content

Optical and dc resistivity measurements as well as x-ray spectroscopies have been performed on (Ga,Mn)N films containing Mn at up to 11 at. %. The results indicate that at higher Mn contents, the Fermi level is situated within extended states, while GaN host interband optical transitions are unaffected. The Mn state is confirmed to be 3d⁵, as in the case of lower Mn content films; however, the high Mn content merges the 3d levels into a band located just below the host conduction band. The Fermi level is located within these Mn states just below the conduction band, in sharp contrast to its midgap position in fully crystalline, low Mn concentration materials. The difference in the position of the Fermi level at high Mn dopant levels has important implications for the promotion of ferromagnetism in this material.The authors gratefully acknowledge financial support from the New Zealand Foundation for Research Science and Technology through its New Economy Research Fund and through a postdoctoral fellowship of one of the authors B.J.R.. The work of the MacDiarmid Institute is supported by a New Zealand Centre of Research Excellence award. Another author S.G. wishes to thank Education New Zealand for financial support of the XANES measurements

Perturbation theory for self-gravitating gauge fields I: The odd-parity sector

A gauge and coordinate invariant perturbation theory for self-gravitating non-Abelian gauge fields is developed and used to analyze local uniqueness and linear stability properties of non-Abelian equilibrium configurations. It is shown that all admissible stationary odd-parity excitations of the static and spherically symmetric Einstein-Yang-Mills soliton and black hole solutions have total angular momentum number $\ell = 1$, and are characterized by non-vanishing asymptotic flux integrals. Local uniqueness results with respect to non-Abelian perturbations are also established for the Schwarzschild and the Reissner-Nordstr\"om solutions, which, in addition, are shown to be linearly stable under dynamical Einstein-Yang-Mills perturbations. Finally, unstable modes with $\ell = 1$ are also excluded for the static and spherically symmetric non-Abelian solitons and black holes.Comment: 23 pages, revtex, no figure

Static black hole solutions with axial symmetry

We construct a new class of asymptotically flat black hole solutions in Einstein-Yang-Mills and Einstein-Yang-Mills-dilaton theory. These black hole solutions are static, and they have a regular event horizon. However, they possess only axial symmetry. Like their regular counterparts, the black hole solutions are characterized by two integers, the winding number $n$ and the node number $k$ of the gauge field functions.Comment: 14 pages, including 4 postscript figures, LaTe