660 research outputs found
Pressure-induced amorphization, crystal-crystal transformations and the memory glass effect in interacting particles in two dimensions
We study a model of interacting particles in two dimensions to address the
relation between crystal-crystal transformations and pressure-induced
amorphization. On increasing pressure at very low temperature, our model
undergoes a martensitic crystal-crystal transformation. The characteristics of
the resulting polycrystalline structure depend on defect density, compression
rate, and nucleation and growth barriers. We find two different limiting cases.
In one of them the martensite crystals, once nucleated, grow easily
perpendicularly to the invariant interface, and the final structure contains
large crystals of the different martensite variants. Upon decompression almost
every atom returns to its original position, and the original crystal is fully
recovered. In the second limiting case, after nucleation the growth of
martensite crystals is inhibited by energetic barriers. The final morphology in
this case is that of a polycrystal with a very small crystal size. This may be
taken to be amorphous if we have only access (as experimentally may be the
case) to the angularly averaged structure factor. However, this `X-ray
amorphous' material is anisotropic, and this shows up upon decompression, when
it recovers the original crystalline structure with an orientation correlated
with the one it had prior to compression. The memory effect of this X-ray
amorphous material is a natural consequence of the memory effect associated to
the underlying martensitic transformation. We suggest that this kind of
mechanism is present in many of the experimental observations of the memory
glass effect, in which a crystal with the original orientation is recovered
from an apparently amorphous sample when pressure is released.Comment: 13 pages, 13 figures, to be published in Phys. Rev.
Temperature Evolution of Sodium Nitrite Structure in a Restricted Geometry
The NaNO nanocomposite ferroelectric material in porous glass was
studied by neutron diffraction. For the first time the details of the crystal
structure including positions and anisotropic thermal parameters were
determined for the solid material, embedded in a porous matrix, in ferro- and
paraelectric phases. It is demonstrated that in the ferroelectric phase the
structure is consistent with bulk data but above transition temperature the
giant growth of amplitudes of thermal vibrations is observed, resulting in the
formation of a "premelted state". Such a conclusion is in a good agreement with
the results of dielectric measurements published earlier.Comment: 4 pages, 4 figure
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