A General Method for Complete Population Transfer in Degenerate Systems

A simple theoretical solution to the design of a control field that generates complete population transfer from an initial state, via $N$ nondegenerate intermediate states, to one arbitrary member of $M$ ($M\leq N$) degenerate states is constructed. The full control field exploits an $(M+N-1)$-node null adiabatic state, created by designing the relative phases and amplitudes of the component fields that together make up the full field. The solution found is universal in the sense that it does not depend on the exact number of the unwanted degenerate states or their properties. The results obtained suggest that a class of multi-level quantum systems with degenerate states can be completely controllable, even under extremely strong constraints, e.g., never populating a Hilbert subspace that is only a few dimensions smaller than the whole Hilbert space.Comment: 12 pages, 5 figures, submitted to Phys. Rev.

Field-free molecular orientation by THz laser pulses at high temperature

We investigate to which extend a THz laser pulse can be used to produce field-free molecular orientation at high temperature. We consider laser pulses that can be implemented with the state of the art technology and we show that the efficiency of the control scheme crucially depends on the parameters of the molecule. We analyze the temperature effects on molecular dynamics and we demonstrate that, for some molecules, a noticeable orientation can be achieved at high temperature.Comment: 13 pages, 7 figure

Accurate statistics of a flexible polymer chain in shear flow

We present exact and analytically accurate results for the problem of a flexible polymer chain in shear flow. Under such a flow the polymer tumbles, and the probability distribution of the tumbling times $\tau$ of the polymer decays exponentially as $\sim \exp(-\alpha \tau/\tau_0)$ (where $\tau_0$ is the longest relaxation time). We show that for a Rouse chain, this nontrivial constant $\alpha$ can be calculated in the limit of large Weissenberg number (high shear rate) and is in excellent agreement with our simulation result of $\alpha \simeq 0.324$. We also derive exactly the distribution functions for the length and the orientational angles of the end-to-end vector of the polymer.Comment: 4 pages, 2 figures. Minor changes. Texts differ slightly from the PRL published versio

Bichromatically driven double well: parametric perspective of the strong-field control landscape reveals the influence of chaotic states

The aim of this work is to understand the influence of chaotic states in control problems involving strong fields. Towards this end, we numerically construct and study the strong field control landscape of a bichromatically driven double well. A novel measure based on correlating the overlap intensities between Floquet states and an initial phase space coherent state with the parametric motion of the quasienergies is used to construct and interpret the landscape features. "Walls" of no control, robust under variations of the relative phase between the fields, are seen on the control landscape and associated with multilevel interactions involving chaotic Floquet states.Comment: 9 pages and 6 figures. Rewritten and expanded version of arXiv:0707.4547 [nlin.CD]. Accepted for publication in J. Chem. Phys. (2008

Strong Coupling Expansions for Antiferromagnetic Heisenberg S=1/2 Ladders

The properties of antiferromagnetic Heisenberg $S=\frac{1}{2}$ ladders with 2, 3, and 4 chains are expanded in the ratio of the intra- and interchain coupling constants. A simple mapping procedure is introduced to relate the 4 and 2-chain ladders which holds down to moderate values of the expansion parameters. A second order calculation of the spin gap to the lowest triplet excitation in the 2- and 4-chain ladders is found to be quite accurate even at the isotropic point where the couplings are equal. Similar expansions and mapping procedures are presented for the 3-chain ladders which are in the same universality class as single chains.Comment: 10 physical pages, uuencoded compressed PostScript file including 12 figures, ETH-TH/942

Disproportionation and electronic phase separation in parent manganite LaMnO_3

Nominally pure undoped parent manganite LaMnO_3 exhibits a puzzling behavior inconsistent with a simple picture of an A-type antiferromagnetic insulator (A-AFI) with a cooperative Jahn-Teller ordering. We do assign its anomalous properties to charge transfer instabilities and competition between insulating A-AFI phase and metallic-like dynamically disproportionated phase formally separated by a first-order phase transition at T_{disp}=T_{JT}\approx 750 K. The unconventional high-temperature phase is addressed to be a specific electron-hole Bose liquid (EHBL) rather than a simple "chemically" disproportionated R(Mn^{2+}Mn^{4+})O_3 phase. New phase does nucleate as a result of the charge transfer (CT) instability and evolves from the self-trapped CT excitons, or specific EH-dimers, which seem to be a precursor of both insulating and metallic-like ferromagnetic phases observed in manganites. We arrive at highly frustrated system of triplet (e_g^2)^3A_{2g} bosons moving in a lattice formed by hole Mn^{4+} centers. Starting with different experimental data we have reproduced a typical temperature dependence of the volume fraction of high-temperature mixed-valent EHBL phase. We argue that a slight nonisovalent substitution, photo-irradiation, external pressure or magnetic field gives rise to an electronic phase separation with a nucleation or an overgrowth of EH-droplets. Such a scenario provides a comprehensive explanation of numerous puzzling properties observed in parent and nonisovalently doped manganite LaMnO_3 including an intriguing manifestation of superconducting fluctuations.Comment: 20 pages, 8 figure

Random wave functions and percolation

Recently it was conjectured that nodal domains of random wave functions are adequately described by critical percolation theory. In this paper we strengthen this conjecture in two respects. First, we show that, though wave function correlations decay slowly, a careful use of Harris' criterion confirms that these correlations are unessential and nodal domains of random wave functions belong to the same universality class as non critical percolation. Second, we argue that level domains of random wave functions are described by the non-critical percolation model.Comment: 13 page

Spin Gaps in Coupled t-J Ladders

Spin gaps in coupled $t$-$J$ ladders are investigated by exact diagonalization of small clusters up to 4$\times$8 sites. At half-filling, the numerical results for the triplet excitation spectrum are in very good agreement with a second order perturbation expansion in term of small inter-ladder and intra-ladder exchange couplings between rungs ($J/J^\prime$$<$$0.25$). The band of local triplet excitations moving coherently along the ladder (with momenta close to $\pi$) is split by the inter-ladder coupling. For intermediate couplings finite size scaling is used to estimate the spin gap. In the isotropic infinite 4-chain system (two coupled ladders) we find a spin gap of $0.245 J$, roughly half of the single ladder spin gap. When the system is hole doped, bonding and anti-bonding bound pairs of holes can propagate coherently along the chains and the spin gap remains finite.Comment: 11 pages, 5 figures, uuencoded form of postscript files of figures and text, LPQTH-94/

Signum Function Method for Generation of Correlated Dichotomic Chains

We analyze the signum-generation method for creating random dichotomic sequences with prescribed correlation properties. The method is based on a binary mapping of the convolution of continuous random numbers with some function originated from the Fourier transform of a binary correlator. The goal of our study is to reveal conditions under which one can construct binary sequences with a given pair correlator. Our results can be used in the construction of superlattices and waveguides with selective transport properties.Comment: 14 pages, 7 figure