745 research outputs found
Theory for Metal Hydrides with Switchable Optical Properties
Recently it has been discovered that lanthanum, yttrium, and other metal
hydride films show dramatic changes in the optical properties at the
metal-insulator transition. Such changes on a high energy scale suggest the
electronic structure is best described by a local model based on negatively
charged hydrogen (H) ions. We develop a many-body theory for the strong
correlation in a H ion lattice. The metal hydride is described by a large
-limit of an Anderson lattice model. We use lanthanum hydride as a prototype
of these compounds, and find LaH is an insulator with a substantial gap
consistent with experiments. It may be viewed either as a Kondo insulator or a
band insulator due to strong electron correlation. A H vacancy state in LaH
is found to be highly localized due to the strong bonding between the electron
orbitals of hydrogen and metal atoms. Unlike the impurity states in the usual
semiconductors, there is only weak internal optical transitions within the
vacancy. The metal-insulator transition takes place in a band of these vacancy
states.Comment: 18 pages, 16 figures and 6 tables. Submitted to PR
A new look at energy release rates for quasistatically propagating cracks in inelastic materials
A mapping technique is used to derive an integral expression for the energy release rate for a quasistatically propagating crack. The derivation does not depend on any assumptions in regard to the contitutive behavior of the material. It leads to a contour integral around the crack tip, plus an area integral over the region enclosed by this contour. Only the stress and displacement fields appear in the integrands. Although for stationary crack solutions known to the authors the area integral is not convergent, for propagating crack solutions in elastoplastic material, the integrals are convergent, and lead to zero energy release rate. This confirms conclusions by Rice from an independent point of view.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/42773/1/10704_2004_Article_BF00012388.pd
Transformation of in-plane in at fixed oxygen content
This paper reveals the origin of variation in the magnitude and temperature
dependence of the normal state resistivity frequently observed in different
YBCO single crystal or thin film samples with the same . We investigated
temperature dependence of resistivity in thin films
with 7- and 6.90, which were subjected to annealing in argon at
400-420 K (). Before annealing these films exhibited a non-linear
, with a flattening below 230 K, similar to and
observed in untwinned and twinned YBCO crystals, respectively.
For all films the annealing causes an increase of resistivity and a
transformation of from a non-linear dependence towards a more
linear one (less flattening). In films with 7- the increase of
resistivity is also associated with an increase in . We proposed the
model that provides an explanation of these phenomena in terms of thermally
activated redistribution of residual O(5) oxygens in the chain-layer of YBCO.
Good agreement between the experimental data for , where t is
the annealing time, and numerical calculations was obtained.Comment: 8 pages, 9 figures, submitted to PR
Formation of two-dimensional weak localization in conducting Langmuir-Blodgett films
We report the magnetotransport properties up to 7 T in the organic highly
conducting Langmuir-Blodgett(LB) films formed by a molecular association of the
electroactive donor molecule bis(ethylendioxy)tetrathiafulvalene (BEDO-TTF) and
stearic acid CH(CH)COOH. We show the logarithmic decrease of dc
conductivity and the negative transverse magnetoresistance at low temperature.
They are interpreted in the weak localization of two-dimensional (2D)
electronic system based on the homogeneous conducting layer with the molecular
size thickness of BEDO-TTF. The electronic length with phase memory is given at
the mesoscopic scale, which provides for the first time evidence of the 2D
coherent charge transport in the conducting LB films.Comment: 5 pages, 1 Table and 5 figure
Exploring play and creativity in pre-schoolers' use of apps:A report for the children's media industry
Localization by disorder in the infrared conductivity of (Y,Pr)Ba2Cu3O7 films
The ab-plane reflectivity of (Y{1-x}Prx)Ba2Cu3O7 thin films was measured in
the 30-30000 cm-1 range for samples with x = 0 (Tc = 90 K), x = 0.4 (Tc = 35 K)
and x = 0.5 (Tc = 19 K) as a function of temperature in the normal state. The
effective charge density obtained from the integrated spectral weight decreases
with increasing x. The variation is consistent with the higher dc resistivity
for x = 0.4, but is one order of magnitude smaller than what would be expected
for x = 0.5. In the latter sample, the conductivity is dominated at all
temperatures by a large localization peak. Its magnitude increases as the
temperature decreases. We relate this peak to the dc resistivity enhancement. A
simple localization-by-disorder model accounts for the optical conductivity of
the x = 0.5 sample.Comment: 7 pages with (4) figures include
A quantum Monte Carlo study of the one-dimensional ionic Hubbard model
Quantum Monte Carlo methods are used to study a quantum phase transition in a
1D Hubbard model with a staggered ionic potential (D). Using recently
formulated methods, the electronic polarization and localization are determined
directly from the correlated ground state wavefunction and compared to results
of previous work using exact diagonalization and Hartree-Fock. We find that the
model undergoes a thermodynamic transition from a band insulator (BI) to a
broken-symmetry bond ordered (BO) phase as the ratio of U/D is increased. Since
it is known that at D = 0 the usual Hubbard model is a Mott insulator (MI) with
no long-range order, we have searched for a second transition to this state by
(i) increasing U at fixed ionic potential (D) and (ii) decreasing D at fixed U.
We find no transition from the BO to MI state, and we propose that the MI state
in 1D is unstable to bond ordering under the addition of any finite ionic
potential. In real 1D systems the symmetric MI phase is never stable and the
transition is from a symmetric BI phase to a dimerized BO phase, with a
metallic point at the transition
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