48 research outputs found
Isochoric thermal conductivity of solid nitrogen
The isochoric thermal conductivity of solid nitrogen has been investigated on
four samples of different densities in the temperature interval from 20 K to
the onset of melting. In alfa-N2 the isochoric thermal conductivity exhibits a
dependence weaker than 1/T; in beta-N2 it increases slightly with temperature.
The experimental results are discussed within a model in which the heat is
transported by low-frequency phonons or by "diffusive" modes above the mobility
boundary. The growth of the thermal conductivity in beta-N2 is attributed to
the decreasing "rotational" component of the total thermal resistance, which
occurs as the rotational correlations between the neighboring molecules become
weaker.Comment: Postscript 12 pages, 3 figures, 1 table. To be published in 200
Stretching and immobilization of DNA for studies of protein–DNA interactions at the single-molecule level
Isochoric thermal conductivity of solid furan
Thermal conductivity of solid furan has been measured at isochoric conditions in the high-temperature orien-tationally-disordered phase I for samples of different densities. Our isochoric data show a gradual increase of ΛV with temperature whereas isobaric thermal conductivity goes down in this temperature range. The above effect is most clearly expressed in furan, where the atoms in the ring plane are not equivalent, as compared with earlier studied C₆H₆ and C₆H₁₂. The increase of ΛV with temperature can be attributed to weakening of the translation-al-orientational interaction which, in turn, leads to a decrease of phonon scattering on rotational excitations. The experimental data are described in terms of a modified Debye model of thermal conductivity with allowance for heat transfer by both low-frequency phonons and ―diffuse‖ modes
Heat transfer in solid halogenated methanes: trifluoromethane
The isochoric thermal conductivity of solid trifluoromethane was investigated for three samples of different densities in the interval from 75 K to the onset of melting. The isochoric thermal conductivity first decreases with increasing temperature, passes through a minimum at T ~ 100 K, and then starts to increase slowly. The results obtained are compared with the thermal conductivities of other freons of methane series. The correlation between the temperature dependence of isochoric thermal conductivity and the character of the rotational molecular motion is discussed