7 research outputs found
Integração numérica de leis de velocidade diferenciais com o uso do SCILAB
In this work, we applied the free open source SCILAB software for the numerical integration of differential rate law equations to obtain the concentration profiles of chemical species involved in the kinetics of some complex reactions. An automated method was applied to construct the system of ordinary differential equations (ODE) from the postulated chemical models. The solutions of the ODEs were obtained numerically by standard SCILAB functions. We successfully simulated even complex chemical systems such as pH oscillators. This communication opens up the possibility of using SCILAB in simulations and modeling by our chemistry undergraduate students
Integração numérica de leis de velocidade diferenciais com o uso do SCILAB Numerical integration of differential rate laws by means of SCILAB
<abstract language="eng">In this work, we applied the free open source SCILAB software for the numerical integration of differential rate law equations to obtain the concentration profiles of chemical species involved in the kinetics of some complex reactions. An automated method was applied to construct the system of ordinary differential equations (ODE) from the postulated chemical models. The solutions of the ODEs were obtained numerically by standard SCILAB functions. We successfully simulated even complex chemical systems such as pH oscillators. This communication opens up the possibility of using SCILAB in simulations and modeling by our chemistry undergraduate students
Face-Dependent Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy of 2,2′-Bipyridine on Au(100) and Au(111)
We have investigated the potential-dependent assembly
of 2,2′-bipyridine
molecules on both Au(100) and Au(111) surfaces using a newly developed
Shell-Isolated Nanoparticle Enhanced-Raman Spectroscopy (SHINERS)
technique. We present potential-dependent SHINERS spectra of 2,2′-bipyridine
adsorbed on both surfaces collected under anodic as well as cathodic
polarization. A series of processes were characterized by the analysis
of the data set with Perturbation Correlation Moving Window Two-Dimensional
Spectroscopy (PCMW2D) and Two-Dimensional Correlation Spectroscopy
(2DCOS). Exquisite spectral detail was achieved and allowed for the
characterization of the complicated ring breathing mode and C–C
inter-ring stretching modes that are diagnostic of molecular orientation
on the surfaces. Detection of several occluded vibration peaks was
also made possible with SHINERS. Analysis reveals that in very negative
potentials 2,2′-bipyridine adsorbs in a disordered, mixed state
with both π-flat cis and several different vertically N-bound
cis orientations, in contrast to previously published reports. Our
findings provide insight into 2,2′-bipyridine adsorption on
Au single crystals and also powerfully combine SHINERS with two-dimensional
correlation analysis to yield a more detailed view of spectral transitions