21 research outputs found

    Incidence of isopod parasitism on gobiid fishes

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    Volume: 95Start Page: 367End Page: 36

    The Huisgen 1,4-dipolar cycloaddition involving isoquinoline, dimethyl butynedioate and activated styrenes: a facile synthesis of tetrahydrobenzoquinolizine derivatives

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    A three-component reaction involving isoquinoline, dimethyl butynedioate and electrophilic styrenes is described. The reaction proceeds through a Huisgen 1,4-dipolar cycloaddition pathway

    20. on a Report of Tetraodon (Monotretus) Travancoricus, from South Kanara, Karnataka, India

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    Volume: 97Start Page: 441End Page: 44

    Domino alkylation/oxa-Michael of 1,3-cyclohexanediones: steering the C/O-chemoselectivity to reach tetrahydrobenzofuranones.

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    International audienceAn unprecedented domino synthesis of tetrahydrobenzofuran-4-ones is described implicating chemoselective alkylation of various 1,3-cyclohexanediones with bromocrotonate or crotonitrile followed by oxa-Michael cyclization. Further transformations of this core to reach molecular diversity are also presented

    New record of a rare loach Noemacheilus monilis from Anaimalai Hills, Western Ghats, Tamil Nadu

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    Volume: 95Start Page: 521End Page: 52

    A facile synthesis of thiaaza- and thiadiaza-fluorene derivatives involving benzothiazole-DMAD zwitterion with arylidenemalononitriles and N-tosylimines

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    An efficient protocol for the one-pot synthesis of thiaazafluorene and thiadiazafluorene derivatives are described

    One-pot, four-component reaction of isocyanides, dimethyl acetylenedicarboxylate, and cyclobutene-1,2-diones: a synthesis of novel spiroheterocycles

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    Isocyanides, dimethyl acetylenedicarboxylate, and cyclobutene-1,2-diones react in one-pot to afford novel spirocyclic compounds with double insertion of the isocyanide

    Chiral 3-aminopyrrolidines as a rigid diamino scaffold for organocatalysis and organometallic chemistry

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    International audienceOver 20 new and easily prepd. diamines were screened for the asym. Morita-Baylis-Hillman reaction. Chiral 3-(N,N-dimethylamino)-1-methylpyrrolidine was found to promote efficiently the reaction of Me vinyl ketone and substituted benzaldehydes. Enantiomeric excesses up to 73% were reached with electron-deficient benzaldehyde derivs. After a simple deprotonation, one of these diamines was transformed into a chiral mixed aggregate for the enantioselective synthesis of (R)-1-o-tolylethanol with 76% ee
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