6 research outputs found
Barreiras de potencial mapeadas por microscopia de força atômica em cerâmicas à base de BaTiO3 dopadas com lantânio Potential barriers mapping by atomic force microscopy in lanthanum doped BaTiO3 based ceramics
Cerâmicas Ă base de titanato de bário (BaTiO3) dopadas com 0,4% em mol de La e 150 ppm de Mn foram investigadas por microscopia de força atĂ´mica no modo de monitoramento de gradientes de campo elĂ©trico, denominado microscopia de força elĂ©trica, para revelar as barreiras de potencial nos contornos de grĂŁo. Estas barreiras elĂ©tricas sĂŁo associadas com o abrupto aumento na resistividade elĂ©trica que ocorre a partir da temperatura de transição ferroelĂ©trica- paraelĂ©trica em BaTiO3 dopado com pequenas quantidades de doadores. Mostramos que para a composição utilizada neste estudo a largura das barreiras elĂ©tricas Ă© da ordem de 350 nm-400 nm, presentes nos contornos de grĂŁos de tamanho mĂ©dio de 1µm.<br>Barium titanate (BaTiO3) based ceramics doped with La as donor (0.4at%t) and Mn as acceptor (150 ppm) were investigated through atomic force microscopy operating in electric force microscopy mode in order to reveal the potential barriers at grain boundaries. These barriers are associated with the steep rise in the resistivity above the ferroelectric-paraelectric phase transition temperature in BaTiO3 doped with small amounts of donor impurities. We show here that for such a composition the potential barrier width are of the order of 350-400 nm, present at grain boundaries of grains with size around 1 µm
Effect of a BaO-CuO-Bi2O3-B2O3 glass flux, and its processing on the dielectric properties of BaTiO3
A seriesofBaTiO3 along withvarious flux oxideshasbeensinteredstep-wiselytoyieldalowsinteringtemperature flux glasscomposition.
The developedglass flux (Ba-Cu-Bi-Bsystem)wasaddedtoBaTiO3 with differentamount,andeventuallyyieldedalowsinteringtemperatureof
BaTiO3 at 900 1C with7wt% flux glassaddition.Toinvestigatetheinfluence ofprocessingmethods,a flux glassshell-BaTiO3 core structure
was developedbyusingseparateballmillingscheduleofglassandbariumtitanatepowders.Comparisonofresultantdielectricpropertieswas
made amongdifferentprocessingmethods,andthis flux shellprocessingmethodsnotablymodifies thedielectricpropertiesofsinteredsamples
comparing toconventionalprocessingmethods.Thesubsequentstructuralinformation,morphology,andphasestabilityofsinteredsampleswere
investigated byInfraredspectroscopy,X-rayphotoelectronspectroscopy(XPS),scanningelectronmicroscopy(SEM)andX-raydiffraction
(XRD) respectively.93wt%BaTiO3-7 wt%glasswiththe flux shellstructuredisplayedaninhibitedcubicphasegraingrowth,andareduced
tetragonality associatedwithCudopingwasconfirmed byX-raydiffraction.Ahighdielectricconstant(43000) aswellasalowlossyfactor
(o0.03) ofthisparticularseriesofsamplewasreported.X-rayphotoelectronspectroscopyshowedthatbridgingoxygenspeciesdecreaseswith
increasing Ndaddition,indicatingthattheNdbondstotheglassnetworkasanetworkmodifier insteadofbeingdopedintoBaTiO3 lattice
through the flux shell.Thus,weconcludedthattheglass flux shellplaystheroleofsinteringadditive,Cudopingion(containedinglass)carrier,
and Ndaliendopantblock