Tunable Wigner States with Dipolar Atoms and Molecules

We study the few-body physics of trapped atoms or molecules with electric or magnetic dipole moments aligned by an external field. Using exact numerical diagonalization appropriate for the strongly correlated regime, as well as a classical analysis, we show how Wigner localization emerges with increasing coupling strength. The Wigner states exhibit non-trivial geometries due to the anisotropy of the interaction. This leads to transitions between different Wigner states as the tilt angle of the dipoles with the confining plane is changed. Intriguingly, while the individual Wigner states are well described by a classical analysis, the transitions between different Wigner states are strongly affected by quantum statistics. This can be understood by considering the interplay between quantum-mechanical and spatial symmetry properties. Finally, we demonstrate that our results are relevant to experimentally realistic systems.Comment: 4 pages, 6 figure

PROTEINS IN VACUO. A MORE EFFICIENT MEANS OF CALCULATING ORIENTATIONALLY-AVERAGED COLLISION CROSS SECTIONS OF PROTEIN IONS

With the aim of understanding solvent effects in protein folding, unfolding, stability and dynamic behavior, studies of protein ions in vacuo have become popular in recent years. One experimental descriptor which gives a general overview of ionic structure is the orientationally-averaged collision cross section , which is obtained from ion drift mobility (IDM) and other kinds of measurements. In modelling protein structures in vacuo with molecular dynamics simulations, it is necessary to calculate for a plurality of model structures for comparison with experiments. The collision cross section is sensitive to the roughness (concavity) of the protein surface because of the possibility of multiple collisions during an encounter between a given bath gas particle and the protein. Calculations of , though in principle straightforward, are time consuming. In the work presented below, it was investigated whether a more efficient calculation scheme can be employed without sacrificing too much accuracy. In the new scheme, atomic-scale protein surface granularity is smoothed out by a collected-atoms approach, while large-scale concavity of the protein is essentially preserved. (Received August 31, 2001; revised December 26, 2001) Bull.Chem.Soc.Ethiop. 2001, 15(2), 157-16

Vortices in Bose-Einstein condensates - finite-size effects and the thermodynamic limit

For a weakly-interacting Bose gas rotating in a harmonic trap we relate the yrast states of small systems (that can be treated exactly) to the thermodynamic limit (derived within the mean-field approximation). For a few dozens of atoms, the yrast line shows distinct quasi-periodic oscillations with increasing angular momentum that originate from the internal structure of the exact many-body states. These finite-size effects disappear in the thermodynamic limit, where the Gross-Pitaevskii approximation provides the exact energy to leading order in the number of particles N. However, the exact yrast states reveal significant structure not captured by the mean-field approximation: Even in the limit of large N, the corresponding mean-field solution accounts for only a fraction of the total weight of the exact quantum state.Comment: Phys Rev A, in pres

Size distribution of sputtered particles from Au nanoislands due to MeV self-ion bombardment

Nanoisland gold films, deposited by vacuum evaporation of gold onto Si(100) substrates, were irradiated with 1.5 MeV Au$^{2+}$ ions up to a fluence of $5\times 10^{14}$ ions cm$^{-2}$ and at incidence angles up to $60^{\circ}$ with respect to the surface normal. The sputtered particles were collected on carbon coated grids (catcher grid) during ion irradiation and were analyzed with transmission electron microscopy and Rutherford backscattering spectrometry. The average sputtered particle size and the areal coverage are determined from transmission electron microscopy measurements, whereas the amount of gold on the substrate is found by Rutherford backscattering spectrometry. The size distributions of larger particles (number of atoms/particle, $n$ $\ge$ 1,000) show an inverse power-law with an exponent of $\sim$ -1 in broad agreement with a molecular dynamics simulation of ion impact on cluster targets.Comment: 13 pages, 8 figures, Submitted for publication in JA

Mixtures of Bose gases confined in concentrically coupled annular traps

A two-component Bose-Einstein condensate confined in an axially-symmetric potential with two local minima, resembling two concentric annular traps, is investigated. The system shows a number of quantum phase transitions that result from the competition between phase coexistence, and radial/azimuthal phase separation. The ground-state phase diagram, as well as the rotational properties, including the (meta)stability of currents in this system, are analysed.Comment: 6 pages, 5 figures, minor revision

Equilibration of quantum systems and subsystems

We unify two recent results concerning equilibration in quantum theory. We first generalise a proof of Reimann [PRL 101,190403 (2008)], that the expectation value of 'realistic' quantum observables will equilibrate under very general conditions, and discuss its implications for the equilibration of quantum systems. We then use this to re-derive an independent result of Linden et. al. [PRE 79, 061103 (2009)], showing that small subsystems generically evolve to an approximately static equilibrium state. Finally, we consider subspaces in which all initial states effectively equilibrate to the same state.Comment: 5 page

Resonant Activation Phenomenon for Non-Markovian Potential-Fluctuation Processes

We consider a generalization of the model by Doering and Gadoua to non-Markovian potential-switching generated by arbitrary renewal processes. For the Markovian switching process, we extend the original results by Doering and Gadoua by giving a complete description of the absorption process. For all non-Markovian processes having the first moment of the waiting time distributions, we get qualitatively the same results as in the Markovian case. However, for distributions without the first moment, the mean first passage time curves do not exhibit the resonant activation minimum. We thus come to the conjecture that the generic mechanism of the resonant activation fails for fluctuating processes widely deviating from Markovian.Comment: RevTeX 4, 5 pages, 4 figures; considerably shortened version accepted as a brief report to Phys. Rev.

Transition from anomalous to normal hysteresis in a system of coupled Brownian motors: a mean field approach

We address a recently introduced model describing a system of periodically coupled nonlinear phase oscillators submitted to multiplicative white noises, wherein a ratchet-like transport mechanism arises through a symmetry-breaking noise-induced nonequilibrium phase transition. Numerical simulations of this system reveal amazing novel features such as negative zero-bias conductance and anomalous hysteresis, explained resorting to a strong-coupling analysis in the thermodynamic limit. Using an explicit mean-field approximation we explore the whole ordered phase finding a transition from anomalous to normal hysteresis inside this phase, estimating its locus and identifying (within this scheme) a mechanism whereby it takes place.Comment: RevTex, 21 pgs, 15 figures. Submited to Physical Review E (2000

Establishing geochemical background variation and threshold values for 59 elements in Australian surface soil

During the National Geochemical Survey of Australia over 1300 top (0–10 cm depth) and bottom (~ 60–80 cm depth) sediment samples (including ~ 10% field duplicates) were collected from the outlet of 1186 catchments covering 81% of the continent at an average sample density of 1 site/5200 km2. The < 2 mm fraction of these samples was analysed for 59 elements by ICP-MS following an aqua regia digestion. Results are used here to establish the geochemical background variation of these elements, including potentially toxic elements (PTEs), in Australian surface soil. Different methods of obtaining geochemical threshold values, which differentiate between background and those samples with unusually high element concentrations and requiring attention, are presented and compared to Western Australia's ‘ecological investigation levels’ (EILs) established for 14 PTEs. For Mn and V these EILs are so low that an unrealistically large proportion (~ 24%) of the sampled sites would need investigation in Australia. For the 12 remaining elements (As, Ba, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sn and Zn) few sample sites require investigation and as most of these are located far from human activity centres, they potentially suggest either minor local contamination or mineral exploration potential rather than pollution. No major diffuse source of contamination by PTEs affects Australian soil at the continental scale. Of the statistical methods used to establish geochemical threshold values, the most pertinent results come from identifying breaks in cumulative probability distributions, the Tukey inner fence and the 98th percentile. Geochemical threshold values for 59 elements, including emerging ‘high-tech’ critical elements such as lanthanides, Be, Ga or Ge, for which no EILs currently exist, are presented