How many metals does it take to fix N2? A mechanistic overview of biological nitrogen fixation

During the process of biological nitrogen fixation, the enzyme nitrogenase catalyzes the ATP-dependent reduction of dinitrogen to ammonia. Nitrogenase consists of two component metalloproteins, the iron (Fe) protein and the molybdenum-iron (MoFe) protein; the Fe protein mediates the coupling of ATP hydrolysis to interprotein electron transfer, whereas the active site of the MoFe protein contains the polynuclear FeMo cofactor, a species composed of seven iron atoms, one molybdenum atom, nine sulfur atoms, an interstitial light atom, and one homocitrate molecule. This Perspective provides an overview of biological nitrogen fixation and introduces three contributions to this special feature that address central aspects of the mechanism and assembly of nitrogenase

Implications of very rapid TeV variability in blazars

We discuss the implications of rapid (few-minute) variability in the TeV flux of blazars, which has been observed recently with the HESS and MAGIC telescopes. The variability timescales seen in PKS 2155-304 and Mrk 501 are much shorter than inferred light-crossing times at the black hole horizon, suggesting that the variability involves enhanced emission in a small region within an outflowing jet. The enhancement could be triggered by dissipation in part of the black hole's magnetosphere at the base of the outflow, or else by instabilities in the jet itself. By considering the energetics of the observed flares, along with the requirement that TeV photons escape without producing pairs, we deduce that the bulk Lorentz factors in the jets must be >50. The distance of the emission region from the central black hole is less well-constrained. We discuss possible consequences for multi-wavelength observations.Comment: 5 pages, no figures, accepted for publication in Monthly Notices of the Royal Astronomical Society Letter

Limits from rapid TeV variability of Mrk 421

The extreme variability event in the TeV emission of Mrk 421, recently reported by the Whipple team, imposes the tightest limits on the typical size of the TeV emitting regions in Active Galactic Nuclei (AGN). We examine the consequences that this imposes on the bulk Lorentz factor of the emitting plasma and on the radiation fields present in the central region of this Active Nucleus. No strong evidence is found for extreme Lorentz factors. However, energetics arguments suggest that any accretion in Mrk 421 has to take place at small rates, compatible with an advection-dominated regime.Comment: 5 pages (Latex MNRAS style), revised version, submitted to MNRA

The matter content of the jet in M87: evidence for an electron-positron jet

Recent observations have allowed the geometry and kinematics of the M87 jet to be tightly constrained. We combine these constraints with historical Very Long Baseline Interferometry (VLBI) results and the theory of synchrotron self-absorbed radio cores in order to investigate the physical properties of the jet. Our results strongly suggest the jet to be dominated by an electron-positron (pair) plasma. Although our conservative constraints cannot conclusively dismiss an electron-proton plasma, the viability of this solution is extremely vulnerable to further tightening of VLBI surface brightness limits. The arguments presented, coupled with future high-resolution multi-frequency VLBI studies of the jet core, will be able to firmly distinguish these two possibilities.Comment: 8 pages, 1 ps figure. Revised and accepted for publication in MNRA

Fitting Pulsar Wind Tori. II. Error Analysis and Applications

We have applied the torus fitting procedure described in Ng & Romani (2004) to PWNe observations in the Chandra data archive. This study provides quantitative measurement of the PWN geometry and we characterize the uncertainties in the fits, with statistical errors coming from the fit uncertainties and systematic errors estimated by varying the assumed fitting model. The symmetry axis $\Psi$ of the PWN are generally well determined, and highly model-independent. We often derive a robust value for the spin inclination $\zeta$. We briefly discuss the utility of these results in comparison with new radio and high energy pulse measurementsComment: 15 pages, 3 figures, ApJ in pres

Steep Slopes and Preferred Breaks in GRB Spectra: the Role of Photospheres and Comptonization

The role of a photospheric component and of pair breakdown is examined in the internal shock model of gamma-ray bursts. We discuss some of the mechanisms by which they would produce anomalously steep low energy slopes, X-ray excesses and preferred energy breaks. Sub-relativistic comptonization should dominate in high comoving luminosity bursts with high baryon load, while synchrotron radiation dominates the power law component in bursts which have lower comoving luminosity or have moderate to low baryon loads. A photosphere leading to steep low energy spectral slopes should be prominent in the lowest baryon loadComment: ApJ'00, in press; minor revs. 10/5/99; (uses aaspp4.sty), 15 pages, 3 figure