13,462 research outputs found
Synthesis, Crystal Structure and Photophysical Properties of Lanthanide Coordination Polymers of 4- 4-(9H-Carbazol-9-Yl)Butoxy Benzoate: The Effect of Bidentate Nitrogen Donors on Luminescence
A new aromatic carboxylate ligand, 4-[4-(9H-carbazol-9-yl)butoxy]benzoic acid (HL), has been synthesized by the replacement of the hydroxyl hydrogen of 4-hydroxy benzoic acid with a 9-butyl-9H-carbazole moiety. The anion derived from HL has been used for the support of a series of lanthanide coordination compounds [Ln = Eu (1), Gd (2) and Tb (3)]. The new lanthanide complexes have been characterized by a variety of spectroscopic techniques. Complex 3 was structurally authenticated by single-crystal X-ray diffraction and found to exist as a solvent-free 1D coordination polymer with the formula [Tb(L)(3)](n). The structural data reveal that the terbium atoms in compound 3 reside in an octahedral ligand environment that is somewhat unusual for a lanthanide. It is interesting to note that each carboxylate group exhibits only a bridging-bidentate mode, with a complete lack of more complex connectivities that are commonly observed for extended lanthanide-containing solid-state structures. Examination of the packing diagram for 3 revealed the existence of two-dimensional molecular arrays held together by means of CH-pi interactions. Aromatic carboxylates of the lanthanides are known to exhibit highly efficient luminescence, thus offering the promise of applicability as optical devices. However, due to difficulties that arise on account of their polymeric nature, their practical application is somewhat limited. Accordingly, synthetic routes to discrete molecular species are highly desirable. For this purpose, a series of ternary lanthanide complexes was designed, synthesized and characterized, namely [Eu(L)(3)(phen)] (4), [Eu(L)(3)(tmphen)] (5), [Tb(L)(3)(phen)] (6) and [Tb(L)(3)(tmphen)] (7) (phen = 1,10-phenanthroline and tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). The photophysical properties of the foregoing complexes in the solid state at room temperature have been investigated. The quantum yields of the ternary complexes 4 (9.65%), 5 (21.00%), 6 (14.07%) and 7 (32.42%), were found to be significantly enhanced in the presence of bidentate nitrogen donors when compared with those of the corresponding binary compounds 1 (0.11%) and 3 (1.45%). Presumably this is due to effective energy transfer from the ancillary ligands.Council of Scientific and Industrial Research (CSIR-TAPSUN Project) SSL, NWP-55CSIR, New DelhiRobert A. Welch Foundation F-0003Chemistr
Interference mitigation in wireless mesh networks through radio co-location aware conflict graphs
Wireless Mesh Networks (WMNs) have evolved into a wireless communication technology of immense interest. But technological advancements in WMNs have inadvertently spawned a plethora of network performance bottlenecks, caused primarily by the rise in prevalent interference. Conflict Graphs are indispensable tools used to theoretically represent and estimate the interference in wireless networks. We propose a generic algorithm to generate conflict graphs which is independent of the underlying interference model. Further, we propose the notion of radio co-location interference, which is caused and experienced by spatially co-located radios in multi-radio multi-channel WMNs. We experimentally validate the concept, and propose a new all-encompassing algorithm to create a radio co-location aware conflict graph. Our novel conflict graph generation algorithm is demonstrated to be significantly superior and more efficient than the conventional approach, through theoretical interference estimates and comprehensive experiments. The results of an extensive set of ns-3 simulations run on the IEEE 802.11g platform strongly indicate that the radio co-location aware conflict graphs are a marked improvement over their conventional counterparts. We also question the use of total interference degree as a reliable metric to predict the performance of a Channel Assignment scheme in a given WMN deployment
The dynamics and control of large flexible space structures-V
A general survey of the progress made in the areas of mathematical modelling of the system dynamics, structural analysis, development of control algorithms, and simulation of environmental disturbances is presented. The use of graph theory techniques is employed to examine the effects of inherent damping associated with LSST systems on the number and locations of the required control actuators. A mathematical model of the forces and moments induced on a flexible orbiting beam due to solar radiation pressure is developed and typical steady state open loop responses obtained for the case when rotations and vibrations are limited to occur within the orbit plane. A preliminary controls analysis based on a truncated (13 mode) finite element model of the 122m. Hoop/Column antenna indicates that a minimum of six appropriately placed actuators is required for controllability. An algorithm to evaluate the coefficients which describe coupling between the rigid rotational and flexible modes and also intramodal coupling was developed and numerical evaluation based on the finite element model of Hoop/Column system is currently in progress
The dynamics and control of large flexible space structures-IV
The effects of solar radiation pressure as the main environmental disturbance torque were incorporated into the model of the rigid orbiting shallow shell and computer simulation results indicate that within the linear range the rigid modal amplitudes are excited in proportion to the area to mass ratio. The effect of higher order terms in the gravity-gradient torque expressions previously neglected was evaluated and found to be negligible for the size structures under consideration. A graph theory approach was employed for calculating the eigenvalues of a large flexible system by reducing the system (stiffness) matrix to lower ordered submatrices. The related reachability matrix and term rank concepts are used to verify controllability and can be more effective than the alternate numerical rank tests. Control laws were developed for the shape and orientation control of the orbiting flexible shallow shell and numerical results presented
ADVANCED RECEIVER ARCHITECTURES IN RADIOFREQUENCY APPLICATIONS
The general principles of several types of receivers fall under the two main headings of TRF (tuned radio frequency)receivers, where the received signal is processed at the incoming frequency right up to the detector stage, and the superhet(supersonic heterodyne) receiver, where the incoming signal is translated (sometimes after some amplification at theincoming frequency) to an intermediate frequency for further processing. There are however, a number of variants of each ofthese two main types. Regeneration (‘reaction’ or ‘tickling’) may be applied in a TRF receiver, to increase both its sensitivityand selectivity. This may be carried to the stage where the RF amplifier actually oscillates – either continuously, so that thereceiver operates as a synchrodyne or homodyne, or intermittently, so that the receiver operates as a super-regenerativereceiver, both of which have been described previously. The synchrodyne or homodyne may be considered alternatively as asuperhet, where the IF (intermediate frequency) is 0 Hz. In this paper we present the new type of receiver architectureswhich work in radiofrequencies.Keywords: supersonic heterodyne, tuned radio frequency
Composition of Jupiter irregular satellites sheds light on their origin
Irregular satellites of Jupiter with their highly eccentric, inclined and
distant orbits suggest that their capture took place just before the giant
planet migration. We aim to improve our understanding of the surface
composition of irregular satellites of Jupiter to gain insight into a narrow
time window when our Solar System was forming. We observed three Jovian
irregular satellites, Himalia, Elara, and Carme, using a medium-resolution
0.8-5.5 micro m spectrograph on the National Aeronautics and Space
Administration (NASA) Infrared Telescope Facility (IRTF). Using a linear
spectral unmixing model we have constrained the major mineral phases on the
surface of these three bodies. Our results confirm that the surface of Himalia,
Elara, and Carme are dominated by opaque materials such as those seen in
carbonaceous chondrite meteorites. Our spectral modeling of NIR spectra of
Himalia and Elara confirm that their surface composition is the same and
magnetite is the dominant mineral. A comparison of the spectral shape of
Himalia with the two large main C-type asteroids, Themis (D 176 km) and Europa
(D 352 km), suggests surface composition similar to Europa. The NIR spectrum of
Carme exhibits blue slope up to 1.5 microm and is spectrally distinct from
those of Himalia and Elara. Our model suggests that it is compositionally
similar to amorphous carbon. Himalia and Elara are compositionally similar but
differ significantly from Carme. These results support the hypotheses that the
Jupiter irregular satellites are captured bodies that were subject to further
breakup events and clustered as families based on their similar physical and
surface compositions
Experimental Evidence of Time Delay Induced Death in Coupled Limit Cycle Oscillators
Experimental observations of time delay induced amplitude death in a pair of
coupled nonlinear electronic circuits that are individually capable of
exhibiting limit cycle oscillations are described. In particular, the existence
of multiply connected death islands in the parameter space of the coupling
strength and the time delay parameter for coupled identical oscillators is
established. The existence of such regions was predicted earlier on theoretical
grounds in [Phys. Rev. Lett. 80, 5109 (1998); Physica 129D, 15 (1999)]. The
experiments also reveal the occurrence of multiple frequency states, frequency
suppression of oscillations with increased time delay and the onset of both
in-phase and anti-phase collective oscillations.Comment: 4 aps formatted RevTeX pages; 6 figures; to appear in Phys. Rev. Let
Changes in the ducts of the glands of the hard palate in reverse smokers
Three hundred fifty-nine cases of stomatitis nicotina were studied in reverse smokers of home made chuttas. One hundred thirty-five biopsies of papular unbilicated lesions of stomatitis nicotina were studied histopathologically. The biopsies were chosen after toluidine blue staining. Mild dysplastic to severe dysplastic changes were seen around the openings of the ducts of the glands. There were three cases of microinvasive carcinoma in the one hundred thirty-five biopsies. Cystic dilatation of the ducts, due to obstruction of the ducts by keratotic plugging, was not seen in stomatitis nicotina lesions but was seen in elderly women who had smoked reverse for more than 4 to 5 decades. The ducts of the glands could probably form a portal of entry for the tobacco pyrolytic products which may act as carcinogenics
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