Influence of catalyst deactivation on the nature of the steady state solutions for reactions on catalytic surfaces

This article does not have an abstract

Comparison of History Effects in Magnetization in Weakly pinned Crystals of high-TcT_c and low-Tc_c Superconductors

A comparison of the history effects in weakly pinned single crystals of a high $T_c$ YBa$_2$Cu$_3$O$_{7 - \delta}$ (for H $\parallel$ c) and a low $T_c$ Ca$_3$Rh$_4$Sn$_{13}$, which show anomalous variations in critical current density $J_c(H)$ are presented via tracings of the minor magnetization hysteresis loops using a vibrating sample magnetometer. The sample histories focussed are, (i) the field cooled (FC), (ii) the zero field cooled (ZFC) and (iii) an isothermal reversal of field from the normal state. An understanding of the results in terms of the modulation in the plastic deformation of the elastic vortex solid and supercooling across order-disorder transition is sought.Comment: Presented in IWCC-200

Preparation of water hyacinth-based phosphocompost and its evaluation against certain phosphorus fertilizers along with phosphate solubilizing bacteria on P availability, uptake and rice productivity

Phosphorus (P) deficiency in soil limits crop yields and can be managed by P fertilizers. But mere applying P fertilizers alone may not be effective in justifying its bioavailability. At present global P reserves are declining in an increasing way which urges us to find out alternatives. Thus, the present work was taken to prepare phosphocompost using water hyacinth (Eichhornia crassipes) as feedstock, termite, and normal soil as bulking agents cum decomposers and enriched with single super phosphate. The effect of phosphocompost on rice(var.ADT-43) productivity, P availability and uptake was evaluated by comparing various P fertilizers (single super phosphate, rock phosphate, di-ammonium phosphate, nano phosphate) combined with or without phosphate solubilizing bacteria (PSB). The experiment was laid out in a completely randomized design with seven treatments including absolute control and replicated thrice. Phosphocompost produced with water hyacinth and termite soil microbes come with superior quality and early maturity compared to normal soil. Pot culture study results revealed that rice growth, yield, P availability and uptake were significantly (p<0.05) higher with SSP + PSB, and Nano phosphate +PSB treated plants, followed by Phosphocompost + PSB. The cost of P fertilizer (Rs/ha) related to yield (kg/ha) was found to be significantly low with phosphocompost (Rs.1132/-) than SSP (Rs.1530/-) and Nano P (Rs.2518/-). Further, phosphocompost combined PSB helps in optimizing the P availability in a long run through P solubilization thus sustained the P uptake. The present investigation brings light to the valorization of water hyacinth as compost will be an effective and economically viable alternative for P fertilizers

Stable and Metastable vortex states and the first order transition across the peak effect region in weakly pinned 2H-NbSe_2

The peak effect in weakly pinned superconductors is accompanied by metastable vortex states. Each metastable vortex configuration is characterized by a different critical current density J_c, which mainly depends on the past thermomagnetic history of the superconductor. A recent model [G. Ravikumar, et al, Phys. Rev. B 61, R6479 (2000)] proposed to explain the history dependent J_c postulates a stable state of vortex lattice with a critical current density J_c^{st}, determined uniquely by the field and temperature. In this paper, we present evidence for the existence of the stable state of the vortex lattice in the peak effect region of 2H-NbSe_2. It is shown that this stable state can be reached from any metastable vortex state by cycling the applied field by a small amplitude. The minor magnetization loops obtained by repeated field cycling allow us to determine the pinning and "equilibrium" properties of the stable state of the vortex lattice at a given field and temperature unambiguously. The data imply the occurence of a first order phase transition from an ordered phase to a disordered vortex phase across the peak effect.Comment: 20 pages, 10 figures. Corresponding author: S. Ramakrishna

Critical points in the Bragg glass phase of a weakly pinned crystal of Ca3_3Rh4_4Sn13_{13}

New experimental data are presented on the scan rate dependence of the magnetization hysteresis width $\Delta M(H)$ ($\propto$ critical current density $J_c(H)$) in isothermal $M-H$ scans in a weakly pinned single crystal of Ca$_3$Rh$_4$Sn$_{13}$, which displays second magnetization peak (SMP) anomaly as distinct from the peak effect (PE). We observe an interesting modulation in the field dependence of a parameter which purports to measure the dynamical annealing of the disordered bundles of vortices injected through the sample edges towards the destined equilibrium vortex state at a given $H$. These data, in conjunction with the earlier observations made while studying the thermomagnetic history dependence in $J_c(H)$ in the tracing of the minor hysteresis loops, imply that the partially disordered state heals towards the more ordered state between the peak field of the SMP anomaly and the onset field of the PE. The vortex phase diagram in the given crystal of Ca$_3$Rh$_4$Sn$_{13}$ has been updated in the context of the notion of the phase coexistence of the ordered and disordered regions between the onset field of the SMP anomaly and the spinodal line located just prior to the irreversibility line. A multi-critical point and a critical point in the ($H,T$) region of the Bragg glass phase have been marked in this phase diagram and the observed behaviour is discussed in the light of recent data on multi-critical point in the vortex phase diagram in a single crystal of Nb.Comment: To appear in Current trends in Vortex State Studies - Pramana J. Physic

Reentrant Peak Effect in an anisotropic superconductor 2H-NbSe_2 : Role of disorder

The reentrant nature of Peak Effect is established in a single crystal of 2H-NbSe_2 via electrical transport and dc magnetisation studies. The role of disorder on the reentrant branch of PE has been examined in three single crystals with varying levels of quenched random disorder. Increasing disorder presumably shrinks the (H,T) parameter space over which vortex array retains spatial order. Although, the upper branch of the PE curve is somewhat robust, the lower reentrant branch of the same curve is strongly affected by disorder.Comment: 5 Pages of text, 4 figure