24 research outputs found

    On the coordination of molybdenum in AgIAg2OMoO3AgI-Ag_2O-MoO_3 glasses using XANES and EXAFS

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    X-ray absorption near edge structure (XANES) and EXAFS analysis was made of the Mo K-edge spectra in a series of AgIAg2OMoO3AgI-Ag_2O-MoO_3 glasses to detect the coordination of Mo in the glass. Mo exists in a tetrahedrally coordinated shell of four O atoms. Limitation of the EXAFS technique in discerning small distance differences in the first shell is discussed

    On the coordination of molybdenum in AgI-Ag<SUB>2</SUB>O-MoO<SUB>3</SUB> glasses using XANES and EXAFS

    No full text
    XANES and EXAFS analysis of the MoK-edge spectra in a series of AgI-Ag<SUB>2</SUB>O-MoO<SUB>3</SUB> glasses has been performed in order to determine the coordination of molybdenum in the glass. Mo has been found to exist in a tetrahedrally coordinated shell of four oxygens. Limitation of theexafs technique in discerning small distance differences in the first shell has also been discussed

    Effect of pressure on the fast-ion conduction in silver iodide-silver oxide-molybdenum oxide glasses

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    The effect of pressure (\leq80 kbar) on the electronic condense of a series of fast-ion conducting AgIAg2OMoO3AgI-Ag_2O-MoO_3 glasses was studied. The results are consistent with a cluster model

    High pressure transport behaviour of AgI-Ag2O-MoO3 glasses and the cluster model

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    The effect of pressure on the conductivity of fast ion conducting AgI-Ag2O-MoO3 glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application of cluster model to the ionic glasses

    Effect of pressure on the fast-ion conduction in AgI-Ag<SUB>2</SUB>O-MoO<SUB>3</SUB> glasses

    No full text
    The effect of pressure (up to 80 kbars) on the electrical conductivity of a series of fast-ion conducting AgI-Ag<SUB>2</SUB>O-MoO<SUB>2</SUB> glasses has been investigated. The results are consistent with a cluster model

    High pressure transport behaviour of AgI-Ag<SUB>2</SUB>O-MoO<SUB>3</SUB> glasses and the cluster model

    No full text
    The effect of pressure on the conductivity of fast ion conducting AgI-Ag<SUB>2</SUB>O-MoO<SUB>3</SUB> glasses has been investigated down to 150 K. The observed variation of conductivities appears to support the application of cluster model to the ionic glasses

    High pressure studies on AgI-Ag2O-MoO3 glasses

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    A self-associating hepatitis B surface antigen-derived peptide that is immunogenic in alum

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    We previously described an oligomeric synthetic peptide derived from the hepatitis B surface antigen that displayed a limited tendency to form self-associating macromolecular structures in solution. Here it is demonstrated that amino-terminal myristylation of this peptide results in near quantitative aggregation of the oligomeric peptide. The myristylated peptide is highly immunogenic when used in conjunction with alum as adjuvant in both the rabbit and rhesus monkey models. The antibody response generated by peptide also cross-reacted with native antigen and was long-lasting. Collectively the results described in this and previous reports offer an attractive new approach for generating immunogenic peptide mimetics of conformational epitopes that may find application as vaccines
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