Dyes removal from water using low cost absorbents

In this study, the removal capacity of low cost adsorbents during the adsorption of Methylene Blue (MB) and Congo Red (CR) at different concentrations (50 and 100mg•L-1) was evaluated. These adsorbents were produced from wood wastes (cedar and teak) by chemical activation (ZnCl2). Both studied materials, Activated Cedar (AC) and activated teak (AT) showed a good fit of their experimental data to the pseudo second order kinetic model and Langmuir isotherms. The maximum adsorption capacities for AC were 2000.0 and 444.4mg•g-1 for MB and CR, respectively, while for AT, maximum adsorption capacities of 1052.6 and 86.4mg•g-1 were found for MB and CR, respectively. © Published under licence by IOP Publishing Ltd

Events in the life of a cocoon surrounding a light, collapsar jet

According to the collapsar model, gamma-ray bursts are thought to be produced in shocks that occur after the relativistic jet has broken free from the stellar envelope. If the mass density of the collimated outflow is less than that of the stellar envelope, the jet will then be surrounded by a cocoon of relativistic plasma. This material would itself be able to escape along the direction of least resistance, which is likely to be the rotation axis of the stellar progenitor, and accelerate in approximately the same way as an impulsive fireball. We discuss how the properties of the stellar envelope have a decisive effect on the appearance of a cocoon propagating through it. The relativistic material that accumulated in the cocoon would have enough kinetic energy to substantially alter the structure of the relativistic outflow, if not in fact provide much of the observed explosive power. Shock waves within this plasma can produce gamma-ray and X-ray transients, in addition to the standard afterglow emission that would arise from the deceleration shock of the cocoon fireball.Comment: 16 pages, 5 figures, slightly revised version, accepted for publication in MNRA

High-precision laser spectroscopy of the CO A1Π^1\Pi - X1Σ+^1\Sigma^+ (2,0), (3,0) and (4,0) bands

High-precision two-photon Doppler-free frequency measurements have been performed on the CO A$^1\Pi$ - X$^1\Sigma^+$ fourth-positive system (2,0), (3,0), and (4,0) bands. Absolute frequencies of forty-three transitions, for rotational quantum numbers up to $J = 5$, have been determined at an accuracy of $1.6\times10^{-3}$ cm$^{-1}$, using advanced techniques of two-color 2+1' resonance-enhanced multi-photon ionization, Sagnac interferometry, frequency-chirp analysis on the laser pulses, and correction for AC-Stark shifts. The accurate transition frequencies of the CO A$^1\Pi$ - X$^1\Sigma^+$ system are of relevance for comparison with astronomical data in the search for possible drifts of fundamental constants in the early universe. The present accuracies in laboratory wavelengths of $\Delta\lambda/\lambda = 2 \times 10^{-8}$ may be considered exact for the purpose of such comparisons.Comment: 13 pages, 6 figures, The Journal of Chemical Physics (2015) accepte

Production and characterization of activated carbon from wood wastes

Cedarwood (Cedrela Angustifolia) and teak (Tectona Grandis) woods are typically used for furniture manufacture because they have high durability, are light and easy to work. During these manufacturing process, large amount of these wastes is generated causing disposal environmental problems. In this paper, the residual wastes (sawdust) of Cedar (C) and Teak (T) are transformed into an activated material. The chemical composition of both biomass (C and T) was determinate by TGA (Thermogravimetric Analysis). Activated materials were characterized in surface area following the BET (Brunauer, Emmett and Teller) method, morphology using SEM (Scanning Electron Microscopy) and to know their functional groups a FTIR (Fourier Transform Infrared Spectroscopy) analysis was done. Their adsorption capacity was evaluated by removal of Methylene Blue (MB) and Congo Red (CR) from aqueous solutions. © Published under licence by IOP Publishing Ltd

GRB990123: Evidence that the Gamma Rays Come from a Central Engine

GRB990123 was a long complex gamma-ray burst with an optical transient that started early within the gamma-ray phase. The peak and power law decay of the early optical emission strongly indicates the presence of a decelerating relativistic shell during that phase. Prior to this burst, it was not known if the shell decelerated during the burst, so an external shock origin for the gamma rays was still possible. If the gamma-rays are produced in the external shock, then the pulse widths should reflect the observed deceleration of the shell and increase by about 2.3. We analyze the fine time structure observed in the gamma-ray data from BATSE and determine that the width of the peaks do not increase as expected for a decelerating shell; the later pulses are, at most, a factor of 1.15 longer than the earlier pulses. We also analyze the variability to determine what fraction of the shell's surface could be involved in the production of the gamma rays, the so-called surface filling factor. For GRB990123 we find a filling factor of 0.008. The lack of pulse width evolution eliminates the only remaining kinematically acceptable external shock explanation for the gamma-ray phase and, thus, the gamma rays must originate at a central engine.Comment: 14 pages, 3 embedded figues, Latex, Submitted to ApJ

Quantum Backflow States from Eigenstates of the Regularized Current Operator

We present an exhaustive class of states with quantum backflow -- the phenomenon in which a state consisting entirely of positive momenta may have negative current and the probability flows in the opposite direction to the momentum. They are characterized by a general function of momenta subject to very weak conditions. Such a family of states is of interest in the light of a recent experimental proposal to measure backflow. We find one particularly simple state which has surprisingly large backflow -- about 41 percent of the lower bound on flux derived by Bracken and Melloy. We study the eigenstates of a regularized current operator and we show how some of these states, in a certain limit, lead to our class of backflow states. This limit also clarifies the correspondence between the spectrum of the regularized current operator, which has just two non-zero eigenvalues in our chosen regularization, and the usual current operator.Comment: 16 pages, 2 figure

Can Crop Insurance Premiums Be Reliably Estimated?

This paper develops and applies a methodology to assess the accuracy of historical loss-cost rating procedures, similar to those used by the U.S. Department of Agriculture’s Risk Management Agency (RMA), versus alternative parametric premium estimation methods. It finds that the accuracy of loss-cost procedures leaves much to be desired, but can be markedly improved through the use of alternative methods and increased farm-level yield sample sizes. Evidence suggests that the high degree of inaccuracy in crop insurance premium estimations through historical loss-cost procedures identified in the paper might be a major factor behind the need for substantial government subsidies to keep the program solvent.agricultural subsidies, crop insurance premium estimation, loss-cost procedures, Risk Management Agency, Agricultural and Food Policy, Agricultural Finance, Farm Management, Risk and Uncertainty,