Real space investigation of structural changes at the metal-insulator transition in VO2

Synchrotron X-ray total scattering studies of structural changes in rutile VO2 at the metal-insulator transition temperature of 340 K reveal that monoclinic and tetragonal phases of VO2 coexist in equilibrium, as expected for a first-order phase transition. No evidence for any distinct intermediate phase is seen. Unbiased local structure studies of the changes in V--V distances through the phase transition, using reverse Monte Carlo methods, support the idea of phase coexistence and point to the high degree of correlation in the dimerized low-temperature structure. No evidence for short range V--V correlations that would be suggestive of local dimers is found in the metallic phase.Comment: 4 pages, 5 figure

Aerosol Characteristics at a high-altitude station Nainital during the ISRO-GBP Land Campaign-II

During the second land campaign (LC-II) organised by ISRO-GBP, extensive ground-based measurements of aerosol characteristics were carried out over Manora Peak (29.4oN; 79.5oE; 1951 metres above mean sea level), Nainital (a high altitude station located in the Shivalik ranges of Central Himalayas) during the dry, winter season (December) of 2004. These measurements included the spectral aerosol optical depths (AOD), columnar water vapour content (W), Total Columnar Ozone (TCO), total number concentration (NT) of near surface aerosols, mass concentration of black carbon (MB), aerosol mass loading (MT), and Global Solar Radiation. Based on these measured parameters, we present the results on the near-surface and columnar properties of atmospheric aerosols at Nainital.Comment: Published in the Proceedings of the ISRO-GBP Land-Campaign-II meeting, Physical Research Laboratory, Ahmadabad (Inida), March 200

X-ray emission from O-type stars : DH Cep and HD 97434

We present X-ray emission characteristics of the massive O-type stars DH Cep and HD 97434 using archival XMM-Newton observations. There is no convincing evidence for short term variability in the X-ray intensity during the observations. However, the analysis of their spectra reveals X-ray structure being consistent with two-temperature plasma model. The hydrogen column densities derived from X-ray spectra of DH Cep and HD 97434 are in agreement with the reddening measurements for their corresponding host clusters NGC 7380 and Trumpler 18, indicating that the absorption by stellar wind is negligible. The X-ray emission from these hot stars is interpreted in terms of the standard instability-driven wind shock model.Comment: 13 pages ; 2 figures; 2 tables (Accepted for publication in New Astronomy

Spin-induced symmetry breaking in orbitally ordered NiCr_2O_4 and CuCr_2O_4

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$ ($t_2^4$) and Cu$^{2+}$ ($t_2^5$). Upon cooling, these compounds undergo magnetic ordering transitions; interactions being somewhat frustrated for NiCr_2O_4 but not for CuCr_2O_4. We employ variable-temperature high-resolution synchrotron X-ray powder diffraction to establish that at the magnetic ordering temperatures there are further structural changes, which result in both compounds distorting to an orthorhombic structure consistent with the Fddd space group. NiCr_2O_4 exhibits additional distortion, likely within the same space group, at a yet-lower transition temperature of $T$ = 30 K. The tetragonal to orthorhombic structural transition in these compounds appears to primarily involve changes in NiO_4 and CuO_4 tetrahedra

Mock-Gaussian Behaviour for Linear Statistics of Classical Compact Groups

We consider the scaling limit of linear statistics for eigenphases of a matrix taken from one of the classical compact groups. We compute their moments and find that the first few moments are Gaussian, whereas the limiting distribution is not. The precise number of Gaussian moments depends upon the particular statistic considered

ΔI=4\Delta I=4 and ΔI=8\Delta I=8 bifurcations in rotational bands of diatomic molecules

It is shown that the recently observed $\Delta I=4$ bifurcation seen in superdeformed nuclear bands is also occurring in rotational bands of diatomic molecules. In addition, signs of a $\Delta I=8$ bifurcation, of the same order of magnitude as the $\Delta I=4$ one, are observed both in superdeformed nuclear bands and rotational bands of diatomic molecules.Comment: LaTex twice, 10 pages and 5 PS figures provided upon demand by the Author