Vacuumless topological defects in Lyra geometry

Few years ago, Cho and Vilenkin have proposed that topological defects can arise in symmetry breaking models without having degenerate vacua. These types of defects are known as vacuumless defects. In the present work, the gravitational field of a vacuumless global string and global monopole have been investigated in the context of Lyra geometry. We find the metric of the vacuumless global string and global monopole in the weak field approximations. It has been shown that the vacuumless global string can have repulsive whereas global monopole exerts attractive gravitational effects on a test particle. It is dissimilar to the case studied in general relativity.Comment: 14 pages, 9 figures. To appear in Astrophys.Space.Sc

Cu-based metalorganic systems: an ab initio study of the electronic structure

Within a first principles framework, we study the electronic structure of the recently synthesized polymeric coordination compound Cu(II)-2,5-bis(pyrazol-1-yl)-1,4-dihydroxybenzene (CuCCP), which has been suggested to be a good realization of a Heisenberg spin-1/2 chain with antiferromagnetic coupling. By using a combination of classical with ab initio quantum mechanical methods, we design on the computer reliable modified structures of CuCCP aimed at studying effects of Cu-Cu coupling strength variations on this spin-1/2 system. For this purpose, we performed two types of modifications on CuCCP. In one case, we replaced H in the linker by i) an electron donating group (NH2) and ii) an electron withdrawing group (CN), while the other modification consisted in adding H2O and NH3 molecules in the structure which change the local coordination of the Cu(II) ions. With the NMTO-downfolding method we provide a quantitative analysis of the modified electronic structure and the nature of the Cu-Cu interaction paths in these new structures and discuss its implications for the underlying microscopic model.Comment: 18 pages, 11 figures, final versio

A new proposal for Galactic dark matter: Effect of f(T) gravity

It is still a challenging problem to the theoretical physicists to know the exact nature of the galactic dark matter which causes the galactic rotational velocity to be more or less a constant. We have proposed that the dark matter as an effect of f(T) gravity. Assuming the flat rotation curves as input we have shown that f(T) gravity can explain galactic dynamics. Here, we don' have to introduce dark matter. Spacetime metric inspired by f(T) gravity describes the region up to which the tangential velocity of the test particle is constant. This inherent property appears to be enough to produce stable circular orbits as well as attractive gravity.Comment: 7 pages and 1 figure. Minor corrections are made. Accepted for publication in Int.J.Theor.Phy

Precision mass measurements of radioactive nuclei at JYFLTRAP

The Penning trap mass spectrometer JYFLTRAP was used to measure the atomic masses of radioactive nuclei with an uncertainty better than 10 keV. The atomic masses of the neutron-deficient nuclei around the N = Z line were measured to improve the understanding of the rp-process path and the SbSnTe cycle. Furthermore, the masses of the neutron-rich gallium (Z = 31) to palladium (Z = 46) nuclei have been measured. The physics impacts on the nuclear structure and the r-process paths are reviewed. A better understanding of the nuclear deformation is presented by studying the pairing energy around A = 100.Comment: 4 pages and 4 figures, RNB7 conf. pro

Fuzzy Logic Controller Design for Intelligent Air-Conditioning System

Inefficient air cooling systems may cause of wasting energy in a great amount specially in the urban area. Being the most popular cooling system, air-conditioners have been used in domestic usage as well as in industrial applications. However, the unintelligent nature of such cooling system gives rise to excess energy consumption which causes a huge problem in the current energy hungry world. In this paper, we present design of a fuzzy logic controller for the intelligent air-conditioning system. The performance of the controller is also simulated. The proposed controller has the adaptive nature to control fan and compressor speed which leads to reducing power consumption. Also, the system controls the operation mode to retain the healthy oxygen level and humid condition of the indoor environment

Synthesis, Molecular Structures and Electrochemical Investigations of [FeFe]-Hydrogenase Biomimics [Fe₂(CO)_{6-n}(EPh₃)_{n}(mu-edt)] (E = P, As, Sb; n = 1, 2)

A series of ethane‐dithiolate (edt = S(CH_{2})_{2}S) complexes [Fe_{2}(CO)_{5}(EPh_{3})(µ‐edt)] and [Fe_{2}(CO)4(EPh_{3})_{2}(µ‐edt)] (E = P, As, Sb), biomimics of the core of [FeFe]‐hydrogenases, have been prepared and structurally characterised. The introduced ligand(s) occupies apical sites lying trans to the iron‐iron bond. NMR studies reveal that while in the mono‐substituted complexes the Fe(CO)_{3} moiety undergoes facile trigonal rotation, the Fe(CO)2(PPh3) centres do not rotate on the NMR timescale. The reductive chemistry has been examined by cyclic voltammetry both in the presence and absence of CO and the observed behavior is found to be dependent upon the nature of the substituents. With L = CO or SbPh_{3} potential inversion is seen leading to a two‐electron reduction, while for others (L = PPh_{3}, AsPh_{3}) a quasi‐reversible one‐electron reduction is observed. Protonation studies reveal that [Fe_{2}(CO)_{5}(PPh_{3})(µ‐edt)] is only partially protonated by excess HBF_{4}·Et_{2}O, thus ruling complexes [Fe_{2}(CO)_{5}(EPh3)(µ‐edt)(µ‐H)]^{+} out as a catalytic intermediates, but [Fe_{2}(CO)_{4}(PPh_{3})_{2}(µ‐edt)] reacts readily with HBF_{4}·Et_{2}O to produce [Fe_{2}(CO)_{4}(PPh3)_{2}(µ‐edt)(µ‐H)]^{+}. While all new complexes are catalysts for the reduction of protons in MeCN, their poor stability and relatively high reduction potentials does not make them attractive in this respect

Bianchi Type III Anisotropic Dark Energy Models with Constant Deceleration Parameter

The Bianchi type III dark energy models with constant deceleration parameter are investigated. The equation of state parameter $\omega$ is found to be time dependent and its existing range for this model is consistent with the recent observations of SN Ia data, SN Ia data (with CMBR anisotropy) and galaxy clustering statistics. The physical aspect of the dark energy models are discussed.Comment: 12 pages, 2 figures, Accepted version of IJT